Handbook of Material Weathering, 5th Edition
This 5th edition of Handbook of Material Weathering contains systematic updates of knowledge generated in more than last 25 years when the 1st edition was prepared.
The information required for professional use has been growing so rapidly that additional books had to be written to accommodate essential knowledge for implementation in technological processes used to manufacture products, which deteriorate on exposure to weathering stress factors.
This edition contains 20 chapters, which can be divided into the following groups:
• Theory (photophysics and photochemistry)
• Stress factors (parameters of exposure, measurements in assessment of weathering conditions, and climatic conditions)
• Methods of weathering (laboratory degradation studies, weathering cycles, sample preparation, weathering data interpretation, lifetime prediction, and artificial weathering versus natural exposure)
• Methods of testing of weathered samples (effect of weathering on material properties and testing methods of weathered specimens)
• Weathering of polymers (data on 52 most important polymers, including mechanisms of degradation, effect of thermal history, characteristic changes in properties with graphical illustrations, and tables with numerical data)
• Weathering of products (data on 42 groups of industrial products, including their required durability, lifetime expectation, relevant degradation mechanisms, and characteristic changes with graphical illustrations)
• Effect of additives on weathering (12 groups of additives are discussed)
• Effect of environmental stress cracking (parameters controlling ESC, mechanisms, methods of testing, and effect on materials)
• Specific topics (suitability of weathered materials for recycling, interrelation between corrosion and weathering, and methods of study and prevention of deterioration of historical monuments made out of stone)
The above information is based on the thorough review of published papers, patents, and other relevant sources updated to the most recent data and information.
In addition to this book, 3 additional volumes contain supplementary information:
Handbook of Material Biodegradation, Biodeterioration, and Biostabilization by Falkiewicz-Dulik, M, Janda, K, and Wypych, G., 2010
Handbook of UV Degradation and Stabilization by Wypych, G, 2011
Atlas of Material Damage, Wypych, G, 2012
The first two books contain information relevant for protection of materials against biological and environmental stress factors. The Atlas of Material Damage has focus on structure and morphology of commercial materials and methods of damage prevention by tailoring morphology.
This set of monographic sources was prepared for research chemists in the photochemistry field, chemists and material scientists designing new materials, users of manufactured products, those who control the quality of manufactured products, and students who want to apply their knowledge to real materials. The books are invaluable for regulating agencies and patent and litigating attorneys.
Handbook of Material Weathering is now used in about 100 countries, although frequently old editions (as seen from citations) are still in use, which do not contain up-to-date information.
Preface
The first edition of this book was published by ChemTec Publishing in 1990. The book had 18 chapters and 518 pages filled with the most up-to-date information on the subject of material weathering available in 1990.
Considering the size of the book and typesetting, the present edition is at least 3 times larger, in spite of the fact that two chapters were omitted from the fourth edition: Chapter 17. Stabilization and Stabilizers and Chapter 18. Biodegradation. Even without these two chapters the present 5th edition is larger than the previous edition. The reason is quite obvious − the field is systematically growing with new data, methods, and discoveries happening every day.
The reasons for eliminating the two chapters are as follows:
• If these two chapters would still be included in the book, the book would need to have two volumes which makes a book more difficult to use (separate table of contents and indices).
• In anticipation of the need for specialized monographic sources, the two chapters mentioned above were not updated in the previous edition, so information was already lacking novelty.
• Short chapters can only present brief review of the subject, whereas in applications detailed information is needed
• Two handbooks were published by ChemTec Publishing on the subjects of the omitted chapters:
Handbook of Material Biodegradation, Biodeterioration, and Biostabilization by
Falkiewicz-Dulik, M, Janda, K, and Wypych, G., 2010
Handbook of UV Degradation and Stabilization by Wypych, G, 2011
These two books give much broader and comprehensive information, such as it is required today, especially considering rapid changes which occurred recently because of health and safety concerns (biostabilization) and new discoveries (UV stabilization).
In addition, to present volume and the above two books, there is also a new book:
Atlas of Material Damage, Wypych, G, 2012
This book was written to emphasize importance of the material structure in photodegradation and photostabilization and also to account for the morphological changes which occur when materials degrade. This addition makes narrative of material degradation more comprehensive, showing new ways to deal with unstable materials.
I hope that the information provided in these four books will help readers to advance their studies on particular subjects of their research and that the results of these studies will be implemented in the future editions of these books, since we try to report current developments to foster future discoveries.
The information required for professional use has been growing so rapidly that additional books had to be written to accommodate essential knowledge for implementation in technological processes used to manufacture products, which deteriorate on exposure to weathering stress factors.
This edition contains 20 chapters, which can be divided into the following groups:
• Theory (photophysics and photochemistry)
• Stress factors (parameters of exposure, measurements in assessment of weathering conditions, and climatic conditions)
• Methods of weathering (laboratory degradation studies, weathering cycles, sample preparation, weathering data interpretation, lifetime prediction, and artificial weathering versus natural exposure)
• Methods of testing of weathered samples (effect of weathering on material properties and testing methods of weathered specimens)
• Weathering of polymers (data on 52 most important polymers, including mechanisms of degradation, effect of thermal history, characteristic changes in properties with graphical illustrations, and tables with numerical data)
• Weathering of products (data on 42 groups of industrial products, including their required durability, lifetime expectation, relevant degradation mechanisms, and characteristic changes with graphical illustrations)
• Effect of additives on weathering (12 groups of additives are discussed)
• Effect of environmental stress cracking (parameters controlling ESC, mechanisms, methods of testing, and effect on materials)
• Specific topics (suitability of weathered materials for recycling, interrelation between corrosion and weathering, and methods of study and prevention of deterioration of historical monuments made out of stone)
The above information is based on the thorough review of published papers, patents, and other relevant sources updated to the most recent data and information.
In addition to this book, 3 additional volumes contain supplementary information:
Handbook of Material Biodegradation, Biodeterioration, and Biostabilization by Falkiewicz-Dulik, M, Janda, K, and Wypych, G., 2010
Handbook of UV Degradation and Stabilization by Wypych, G, 2011
Atlas of Material Damage, Wypych, G, 2012
The first two books contain information relevant for protection of materials against biological and environmental stress factors. The Atlas of Material Damage has focus on structure and morphology of commercial materials and methods of damage prevention by tailoring morphology.
This set of monographic sources was prepared for research chemists in the photochemistry field, chemists and material scientists designing new materials, users of manufactured products, those who control the quality of manufactured products, and students who want to apply their knowledge to real materials. The books are invaluable for regulating agencies and patent and litigating attorneys.
Handbook of Material Weathering is now used in about 100 countries, although frequently old editions (as seen from citations) are still in use, which do not contain up-to-date information.
Preface
The first edition of this book was published by ChemTec Publishing in 1990. The book had 18 chapters and 518 pages filled with the most up-to-date information on the subject of material weathering available in 1990.
Considering the size of the book and typesetting, the present edition is at least 3 times larger, in spite of the fact that two chapters were omitted from the fourth edition: Chapter 17. Stabilization and Stabilizers and Chapter 18. Biodegradation. Even without these two chapters the present 5th edition is larger than the previous edition. The reason is quite obvious − the field is systematically growing with new data, methods, and discoveries happening every day.
The reasons for eliminating the two chapters are as follows:
• If these two chapters would still be included in the book, the book would need to have two volumes which makes a book more difficult to use (separate table of contents and indices).
• In anticipation of the need for specialized monographic sources, the two chapters mentioned above were not updated in the previous edition, so information was already lacking novelty.
• Short chapters can only present brief review of the subject, whereas in applications detailed information is needed
• Two handbooks were published by ChemTec Publishing on the subjects of the omitted chapters:
Handbook of Material Biodegradation, Biodeterioration, and Biostabilization by
Falkiewicz-Dulik, M, Janda, K, and Wypych, G., 2010
Handbook of UV Degradation and Stabilization by Wypych, G, 2011
These two books give much broader and comprehensive information, such as it is required today, especially considering rapid changes which occurred recently because of health and safety concerns (biostabilization) and new discoveries (UV stabilization).
In addition, to present volume and the above two books, there is also a new book:
Atlas of Material Damage, Wypych, G, 2012
This book was written to emphasize importance of the material structure in photodegradation and photostabilization and also to account for the morphological changes which occur when materials degrade. This addition makes narrative of material degradation more comprehensive, showing new ways to deal with unstable materials.
I hope that the information provided in these four books will help readers to advance their studies on particular subjects of their research and that the results of these studies will be implemented in the future editions of these books, since we try to report current developments to foster future discoveries.
1 Photophysics
1.1 Nature of radiation
1.1.1 Radiative energy
1.1.2 Radiation intensity
1.1.3 Radiation incidence
1.2 Absorption of radiation by materials
1.2.1 General principles
1.3 Fate and utilization of absorbed energy
1.3.1 Deactivation
1.3.2 Intramolecular energy transfer
1.3.3 Intermolecular energy transfer
1.3.4 Luminescence
1.4 Radiative processes involving dimers
1.5 Modeling and photophysical data
References
2 Photochemistry
2.1 Typical routes of photochemical reactions
2.1.1 Photodissociation
2.1.2 Photooxidation
2.1.3 Peroxide and hydroperoxide conversions
2.1.4 Norrish type I and II reactions
2.1.5 Photo-Fries rearrangement
2.1.6 Photo-Fenton
2.1.7 Photosubstitution
2.1.8 Photoaddition
2.1.9 Photoelimination
2.1.10 Photodimerization
2.1.11 Photocondensation
2.1.12 Photoisomerization
2.2 Photochemical reactivity and quantum yield
2.3 Excitation of excited state
2.4 Parameters of photochemical reactions
2.6 Quenchers and photosensitizers
References
3 Parameters of Exposure
3.1 Radiation
3.1.1 The source
3.1.2 Solar radiative emission
3.1.3 Effect of orbital variations on energy supply
3.1.4 Interplanetary and near Earth space
3.1.5 Stratosphere
3.1.6 Troposphere
3.2 Temperature
3.3 Water
3.4 Atmosphere composition
3.5 Pollutants
3.5.1 Nitrogen compounds
3.5.2 Oxygen species
3.5.3 Hydrogen species
3.5.4 Carbon oxides
3.5.5 Sulfur-containing components
3.5.6 Chlorine-containing components
3.5.7 Particulate materials
3.6 Biological substances
3.7 Water pollutants
3.8 Stress
3.7 Cooperative action of different parameters
References
4 Measurements in Assessment of Weathering Conditions
4.1 Radiation
4.1.1 Measuring equipment and methods of measurement
4.1.2 Standards
4.2 Sunshine duration
4.3 Temperature
4.4 Relative humidity
4.5 Time of wetness
4.5 Rain
4.6 Pollutants
4.6.1 Carbon dioxide
4.6.2 Particulate matter
4.6.3 Sulfur dioxide
4.6.4 Nitrogen oxides
4.6.5 Carbon monoxide
4.6.6 Ozone
References
5 Climatic Conditions
5.1 Introduction
5.2 Radiation
5.3 Sunshine duration
5.4 Temperature
5.5 Precipitation
5.6 Relative humidity
5.7 Wetness time
5.8 Pollutants
5.9 Surface soiling
References
6 Methods of Outdoor Exposure
6.1 Introduction
6.2 Climatic conditions and degradation rate
6.3 Variability of weather conditions and its impact on the strategy in outdoor
exposures
6.4 Influence of specimen properties
6.5 Typical methods of outdoor exposure
6.5.1 Exposure sites
6.5.2 Exposure racks
6.5.3 Exposure of products and components
6.6 Other parameters of exposure
6.7 Relevant standards
References
7 Laboratory Degradation Studies
7.1 Introduction
7.2 Light sources
7.3 Filters
7.4 Radiation: delivery, monitoring and control
7.5 Temperature control
7.6 Humidity control
7.7 Specimen spraying
7.8 Specimen racks and holders
7.9 Weathering equipment
7.10 Correlation between different devices
7.11 Pollutants
7.12 Precision of studies
References
8 Weathering Cycles
References
9 Sample Preparation
References
10 Weathering Data Interpretation. Lifetime Prediction
References
11 Artificial Weathering Versus Natural Exposure
References
12 Effect of Weathering on Material Properties
12.1 Mass loss
12.2 Depth of degradation
12.3 Mechanical properties
12.4 Changes of color and optical properties
12.5 Surface changes
12.6 Molecular weight
12.7 Chemical composition of surface and bulk
12.8 Morphology and structure of surface layers
12.9 Glass transition temperature
12.10 Self-healing
References
13 Testing Methods of Weathered Specimen
13.1 Visual evaluation
13.2 Microscopy
13.3 Imaging techniques
13.4 Gloss
13.5 Color changes
13.6 Visible spectrophotometry
13.7 UV spectrophotometry
13.8 Infrared spectrophotometry
13.9 Near infrared spectroscopy
13.10 Raman spectroscopy
13.11 Nuclear magnetic resonance
13.12 Electron spin resonance
13.13 Mass spectrometry
13.14 Positron annihilation lifetime spectroscopy
13.15 Chemiluminescence, fluorescence, and phosphorescence
13.16 Atomic absorption spectroscopy
13.17 WAXS and SAXS
13.18 X-ray photoelectron spectroscopy, XPS
13.19 X-ray microtomography
13.20 Mass change
13.21 Density
13.22 Contact angle
13.23 Diffusion of gases and water transport in polymer
13.24 Electrical properties
13.25 Ultrasonic measurements
13.26 Thermal analysis
13.27 Rheological properties of materials
13.28 Other physical parameters
13.29 Tensile strength
13.30 Elongation
13.31 Flexural strength
13.32 Impact strength
13.33 Creep and constant strain tests
13.34 Residual stress
13.35 Scratch and mar resistance
13.36 Other mechanical properties
13.37 Surface roughness
13.38 Molecular weight
13.39 Gas and liquid chromatography
13.40 Titrimetry
13.41 Dehydrochlorination rate
13.42 Gel fraction
13.43 Oxygen uptake
13.44 Water absorption, porosity
13.45 Microorganism growth test
13.46 Environmental stress cracking resistance
References
14 Data on Specific Polymers
14.1 Acrylonitrile butadiene styrene, ABS
14.2 Acrylonitrile styrene acrylate, ASA
14.3 Alkyd resins
14.4 Acrylic resins
14.5 Cellulose
14.6 Chitosan
14.7 Epoxy resins
14.8 Ethylene propylene rubber, EPR
14.9 Ethylene vinyl acetate copolymer, EVAc
14.10 Ethylene propylene diene monomer, EPDM
14.11 Fluoropolymers
14.12 Melamine resins
14.13 Phenoxy resins
14.14 Polyacrylamide
14.15 Polyacrylonitrile
14.16 Polyamides
14.17 Polyaniline
14.18 Polycarbonates
14.19 Polyesters
14.20 Polyethylene
14.21 Polyethylene, chlorinated
14.22 Poly(ethylene glycol)
14.23 Polyfluorene
14.24 Polyimides
14.25 Poly(lactic acid)
14.26 Polymethylmethacrylate
14.27 Polyoxyethylene
14.28 Polyoxymethylene
14.29 Poly(phenylene oxide)
14.30 Poly(phenylene sulfide)
14.31 Poly(p-phenylene terephthalamide)
14.32 Poly(p-phenylene vinylene)
14.33 Polypropylene
14.34 Polystyrenes
14.35 Polysulfones
14.36 Polytetrafluoroethylene
14.37 Polythiophene
14.38 Polyurethanes
14.39 Polyvinylalcohol
14.40 Polyvinylchloride
14.41 Poly(vinylidene fluoride
14.42 Poly(vinyl methyl ether)
14.43 Styrene acrylonitrile copolymer
14.44 Silicones
14.45 Polymer blends
14.46 Rubbers
14.46.1 Natural rubber
14.46.1 Polybutadiene
14.46.2 Polychloroprene
14.46.3 Polyisoprene
14.46.4 Polyisobutylene
14.46.5 Styrene butadiene rubber
14.46.6 Styrene butadiene styrene rubber
References
15 Effect of Additives on Weathering
15.1 Fillers and reinforcing fibers
15.2 Pigments
15.3 Plasticizers
15.4 Solvents and diluents
15.5 Flame retardants
15.6 Impact modifiers
15.7 Thermal stabilizers
15.8 Antioxidants
15.9 Antimicrobial additives
15.10 Curatives, crosslinkers, initiators
15.11 Catalysts
15.12 Compatibilizer
15.12 Impurities
15.13 Summary
References
16 Weathering of Compounded Products
16.1 Adhesives
16.2 Aerospace
16.3 Agriculture
16.4 Appliances
16.5 Automotive parts
16.6 Automotive coatings
16.7 Coated fabrics
16.8 Coil coated materials
16.9 Composites
16.10 Concrete
16.11 Conservation
16.12 Construction materials
16.13 Cosmetics
16.14 Dental materials
16.15 Electronics and electrical materials
16.16 Environmental pollutants
16.17 Foams
16.18 Food
16.19 Gel coats
16.20 Geosynthetics
16.21 Glass and glazing materials
16.22 Greenhouse film
16.23 Hair
16.24 Laminates
16.25 Medical equipment and supplies
16.26 Military applications
16.27 Molded materials
16.28 Packaging materials
16.28.1 Bottles
16.28.2 Containers
16.28.3 Crates and trays
16.28.4 Films
16.29 Paints and coatings
16.30 Pavements
16.31 Pharmaceutical products
16.32 Pipes and tubing
16.33 Pulp and paper
16.34 Roofing materials
16.35 Sealants
16.36 Sheet
16.37 Siding
16.38 Solar cells and collectors
16.39 Textiles
16.40 Windows
16.41 Wire and cable
16.42 Wood
References
17 Recycling
17.1 Effect of degradation on recycling
17.2 Re-stabilization of material for recycling
17.3 Multilayer materials
17.4 Removable paint
17.5 Chemical recycling
References
18 Environmental Stress Cracking
18.1 Definitions
18.2 Parameters controlling ESC
18.2.1 Material composition
18.2.2 Morphology and dimensions
18.2.3 Processing and performance conditions
18.2.4 Solubility parameters of solvents and polymers
18.2.5 Diffusion
18.2.6 Load and internal stress
18.2.7 Time
18.2.8 Temperature
18.3 Mechanisms of environmental stress cracking
18.4 Kinetics of environmental stress cracking
18.5 Effect of ESC on material durability
18.6 Methods of testing
References
19 Interrelation Between Corrosion and Weathering
References
20 Weathering of Stones
References
Index
1.1 Nature of radiation
1.1.1 Radiative energy
1.1.2 Radiation intensity
1.1.3 Radiation incidence
1.2 Absorption of radiation by materials
1.2.1 General principles
1.3 Fate and utilization of absorbed energy
1.3.1 Deactivation
1.3.2 Intramolecular energy transfer
1.3.3 Intermolecular energy transfer
1.3.4 Luminescence
1.4 Radiative processes involving dimers
1.5 Modeling and photophysical data
References
2 Photochemistry
2.1 Typical routes of photochemical reactions
2.1.1 Photodissociation
2.1.2 Photooxidation
2.1.3 Peroxide and hydroperoxide conversions
2.1.4 Norrish type I and II reactions
2.1.5 Photo-Fries rearrangement
2.1.6 Photo-Fenton
2.1.7 Photosubstitution
2.1.8 Photoaddition
2.1.9 Photoelimination
2.1.10 Photodimerization
2.1.11 Photocondensation
2.1.12 Photoisomerization
2.2 Photochemical reactivity and quantum yield
2.3 Excitation of excited state
2.4 Parameters of photochemical reactions
2.6 Quenchers and photosensitizers
References
3 Parameters of Exposure
3.1 Radiation
3.1.1 The source
3.1.2 Solar radiative emission
3.1.3 Effect of orbital variations on energy supply
3.1.4 Interplanetary and near Earth space
3.1.5 Stratosphere
3.1.6 Troposphere
3.2 Temperature
3.3 Water
3.4 Atmosphere composition
3.5 Pollutants
3.5.1 Nitrogen compounds
3.5.2 Oxygen species
3.5.3 Hydrogen species
3.5.4 Carbon oxides
3.5.5 Sulfur-containing components
3.5.6 Chlorine-containing components
3.5.7 Particulate materials
3.6 Biological substances
3.7 Water pollutants
3.8 Stress
3.7 Cooperative action of different parameters
References
4 Measurements in Assessment of Weathering Conditions
4.1 Radiation
4.1.1 Measuring equipment and methods of measurement
4.1.2 Standards
4.2 Sunshine duration
4.3 Temperature
4.4 Relative humidity
4.5 Time of wetness
4.5 Rain
4.6 Pollutants
4.6.1 Carbon dioxide
4.6.2 Particulate matter
4.6.3 Sulfur dioxide
4.6.4 Nitrogen oxides
4.6.5 Carbon monoxide
4.6.6 Ozone
References
5 Climatic Conditions
5.1 Introduction
5.2 Radiation
5.3 Sunshine duration
5.4 Temperature
5.5 Precipitation
5.6 Relative humidity
5.7 Wetness time
5.8 Pollutants
5.9 Surface soiling
References
6 Methods of Outdoor Exposure
6.1 Introduction
6.2 Climatic conditions and degradation rate
6.3 Variability of weather conditions and its impact on the strategy in outdoor
exposures
6.4 Influence of specimen properties
6.5 Typical methods of outdoor exposure
6.5.1 Exposure sites
6.5.2 Exposure racks
6.5.3 Exposure of products and components
6.6 Other parameters of exposure
6.7 Relevant standards
References
7 Laboratory Degradation Studies
7.1 Introduction
7.2 Light sources
7.3 Filters
7.4 Radiation: delivery, monitoring and control
7.5 Temperature control
7.6 Humidity control
7.7 Specimen spraying
7.8 Specimen racks and holders
7.9 Weathering equipment
7.10 Correlation between different devices
7.11 Pollutants
7.12 Precision of studies
References
8 Weathering Cycles
References
9 Sample Preparation
References
10 Weathering Data Interpretation. Lifetime Prediction
References
11 Artificial Weathering Versus Natural Exposure
References
12 Effect of Weathering on Material Properties
12.1 Mass loss
12.2 Depth of degradation
12.3 Mechanical properties
12.4 Changes of color and optical properties
12.5 Surface changes
12.6 Molecular weight
12.7 Chemical composition of surface and bulk
12.8 Morphology and structure of surface layers
12.9 Glass transition temperature
12.10 Self-healing
References
13 Testing Methods of Weathered Specimen
13.1 Visual evaluation
13.2 Microscopy
13.3 Imaging techniques
13.4 Gloss
13.5 Color changes
13.6 Visible spectrophotometry
13.7 UV spectrophotometry
13.8 Infrared spectrophotometry
13.9 Near infrared spectroscopy
13.10 Raman spectroscopy
13.11 Nuclear magnetic resonance
13.12 Electron spin resonance
13.13 Mass spectrometry
13.14 Positron annihilation lifetime spectroscopy
13.15 Chemiluminescence, fluorescence, and phosphorescence
13.16 Atomic absorption spectroscopy
13.17 WAXS and SAXS
13.18 X-ray photoelectron spectroscopy, XPS
13.19 X-ray microtomography
13.20 Mass change
13.21 Density
13.22 Contact angle
13.23 Diffusion of gases and water transport in polymer
13.24 Electrical properties
13.25 Ultrasonic measurements
13.26 Thermal analysis
13.27 Rheological properties of materials
13.28 Other physical parameters
13.29 Tensile strength
13.30 Elongation
13.31 Flexural strength
13.32 Impact strength
13.33 Creep and constant strain tests
13.34 Residual stress
13.35 Scratch and mar resistance
13.36 Other mechanical properties
13.37 Surface roughness
13.38 Molecular weight
13.39 Gas and liquid chromatography
13.40 Titrimetry
13.41 Dehydrochlorination rate
13.42 Gel fraction
13.43 Oxygen uptake
13.44 Water absorption, porosity
13.45 Microorganism growth test
13.46 Environmental stress cracking resistance
References
14 Data on Specific Polymers
14.1 Acrylonitrile butadiene styrene, ABS
14.2 Acrylonitrile styrene acrylate, ASA
14.3 Alkyd resins
14.4 Acrylic resins
14.5 Cellulose
14.6 Chitosan
14.7 Epoxy resins
14.8 Ethylene propylene rubber, EPR
14.9 Ethylene vinyl acetate copolymer, EVAc
14.10 Ethylene propylene diene monomer, EPDM
14.11 Fluoropolymers
14.12 Melamine resins
14.13 Phenoxy resins
14.14 Polyacrylamide
14.15 Polyacrylonitrile
14.16 Polyamides
14.17 Polyaniline
14.18 Polycarbonates
14.19 Polyesters
14.20 Polyethylene
14.21 Polyethylene, chlorinated
14.22 Poly(ethylene glycol)
14.23 Polyfluorene
14.24 Polyimides
14.25 Poly(lactic acid)
14.26 Polymethylmethacrylate
14.27 Polyoxyethylene
14.28 Polyoxymethylene
14.29 Poly(phenylene oxide)
14.30 Poly(phenylene sulfide)
14.31 Poly(p-phenylene terephthalamide)
14.32 Poly(p-phenylene vinylene)
14.33 Polypropylene
14.34 Polystyrenes
14.35 Polysulfones
14.36 Polytetrafluoroethylene
14.37 Polythiophene
14.38 Polyurethanes
14.39 Polyvinylalcohol
14.40 Polyvinylchloride
14.41 Poly(vinylidene fluoride
14.42 Poly(vinyl methyl ether)
14.43 Styrene acrylonitrile copolymer
14.44 Silicones
14.45 Polymer blends
14.46 Rubbers
14.46.1 Natural rubber
14.46.1 Polybutadiene
14.46.2 Polychloroprene
14.46.3 Polyisoprene
14.46.4 Polyisobutylene
14.46.5 Styrene butadiene rubber
14.46.6 Styrene butadiene styrene rubber
References
15 Effect of Additives on Weathering
15.1 Fillers and reinforcing fibers
15.2 Pigments
15.3 Plasticizers
15.4 Solvents and diluents
15.5 Flame retardants
15.6 Impact modifiers
15.7 Thermal stabilizers
15.8 Antioxidants
15.9 Antimicrobial additives
15.10 Curatives, crosslinkers, initiators
15.11 Catalysts
15.12 Compatibilizer
15.12 Impurities
15.13 Summary
References
16 Weathering of Compounded Products
16.1 Adhesives
16.2 Aerospace
16.3 Agriculture
16.4 Appliances
16.5 Automotive parts
16.6 Automotive coatings
16.7 Coated fabrics
16.8 Coil coated materials
16.9 Composites
16.10 Concrete
16.11 Conservation
16.12 Construction materials
16.13 Cosmetics
16.14 Dental materials
16.15 Electronics and electrical materials
16.16 Environmental pollutants
16.17 Foams
16.18 Food
16.19 Gel coats
16.20 Geosynthetics
16.21 Glass and glazing materials
16.22 Greenhouse film
16.23 Hair
16.24 Laminates
16.25 Medical equipment and supplies
16.26 Military applications
16.27 Molded materials
16.28 Packaging materials
16.28.1 Bottles
16.28.2 Containers
16.28.3 Crates and trays
16.28.4 Films
16.29 Paints and coatings
16.30 Pavements
16.31 Pharmaceutical products
16.32 Pipes and tubing
16.33 Pulp and paper
16.34 Roofing materials
16.35 Sealants
16.36 Sheet
16.37 Siding
16.38 Solar cells and collectors
16.39 Textiles
16.40 Windows
16.41 Wire and cable
16.42 Wood
References
17 Recycling
17.1 Effect of degradation on recycling
17.2 Re-stabilization of material for recycling
17.3 Multilayer materials
17.4 Removable paint
17.5 Chemical recycling
References
18 Environmental Stress Cracking
18.1 Definitions
18.2 Parameters controlling ESC
18.2.1 Material composition
18.2.2 Morphology and dimensions
18.2.3 Processing and performance conditions
18.2.4 Solubility parameters of solvents and polymers
18.2.5 Diffusion
18.2.6 Load and internal stress
18.2.7 Time
18.2.8 Temperature
18.3 Mechanisms of environmental stress cracking
18.4 Kinetics of environmental stress cracking
18.5 Effect of ESC on material durability
18.6 Methods of testing
References
19 Interrelation Between Corrosion and Weathering
References
20 Weathering of Stones
References
Index
George Wypych has a Ph. D. in chemical engineering. His professional expertise includes both university teaching (full professor) and research & development. He has published 17 books: PVC Plastisols, (University Press); Polyvinylchloride Degradation, (Elsevier); Polyvinylchloride Stabilization, (Elsevier); Polymer Modified Textile Materials, (Wiley & Sons); Handbook of Material Weathering, 1st, 2nd, 3rd, and 4th Editions, (ChemTec Publishing); Handbook of Fillers, 1st, 2nd and 3rd Editions, (ChemTec Publishing); Recycling of PVC, (ChemTec Publishing); Weathering of Plastics. Testing to Mirror Real Life Performance, (Plastics Design Library), Handbook of Solvents, Handbook of Plasticizers, Handbook of Antistatics, Handbook of Antiblocking, Release, and Slip Additives (1st and 2nd Editions), PVC Degradation & Stabilization, PVC Formulary, Handbook of UV Degradation and Stabilization, Handbook of Biodeterioration, Biodegradation and Biostabilization, and Handbook of Polymers (all by ChemTec Publishing), 47 scientific papers, and he has obtained 16 patents. He specializes in polymer additives, polymer processing and formulation, material durability, and the development of sealants and coatings. He is included in the Dictionary of International Biography, Who's Who in Plastics and Polymers, Who's Who in Engineering, and was selected International Man of the Year 1996-1997 in recognition for his services to education.
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Handbook of Adhesion P...
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{"id":7703567040669,"title":"Handbook of Adhesion Promoters, 2nd Ed.","handle":"handbook-of-adhesion-promoters-2nd-ed","description":"\u003ch5\u003eDescription\u003c\/h5\u003e\nAuthor: George Wypych\u003cbr\u003eISBN 978-1-77467-018-7 \u003cbr\u003e\u003cbr\u003e \u003cmeta charset=\"utf-8\"\u003e\n\u003cp\u003ePages 322+vi\u003cbr\u003eFigures 154\u003cbr\u003ePublished Jan. 2023\u003cbr\u003e\u003c\/p\u003e\n\u003ch5\u003eSummary\u003c\/h5\u003e\n\u003cp\u003eAdhesion promoters form a significant group of additives, without, which many industrial products cannot perform according to requirements. The knowledge on this subject mostly related to silanes, which form the most widely used group of these additives, is frequently based on the book which was published at the beginning of 1980s by a scientist who developed many silanes used until today. Since then, many new additives were introduced into the market. Most of these new additives are not based on silanes but on one of over 30 chemical groups of chemical compounds needed for a variety of products in which silanes do not function, are too expensive, or better performance can be achieved with these new additives.\u003cbr\u003e\u003cbr\u003eThis book fills the existing gap in the literature, which still lacks the most recent comprehensive review of current options and knowledge. Handbook of Adhesion Promoters contains 10 chapters, each discussing essential aspects of the application of adhesion promoters. The known mechanisms which belong to one of 13 groups outline principles of use, action, and application of these additives. This chapter is followed by the discussion of mechanisms that cause adhesion loss, such as corrosion, delamination, detachment, liquid penetration, and peeling.\u003cbr\u003e\u003cbr\u003eSurface condition and its treatment are discussed regarding surface treatment by different methods (cleaning, mechanical, plasma, microwave, flame, corona discharge, laser, UV, and chemical modification), which are used in practical applications. All these are illustrated with practical examples.\u003cbr\u003e\u003cbr\u003eChapter 5 gives formulations of typical primers used in the application of adhesives and sealants, coatings, coil coatings, cosmetics, dental, leather, metal, optical devices, paper, polymers and plastics, printing, and wood. This chapter contains over 50 primer formulations.\u003cbr\u003e\u003cbr\u003eA full chapter is devoted to the subject of polymer modification which can improve adhesion – a method frequently used instead of the addition of adhesion promoters. The properties of (over 30 groups of adhesion promoters and their potential applications are discussed in the chapter devoted to this subject based on published articles, manufacturers’ information, and analysis of patents.\u003cbr\u003e\u003cbr\u003eThe last three chapters contain information on available evaluation and selection of adhesion promoters that work with different polymers (29), products (28) and help to prevent corrosion. A full list of covered polymers and products is given in the table of contents below.\u003cbr\u003e\u003cbr\u003eIn addition to the theoretical and practical knowledge required to effectively formulate products used in various applications discussed in this book, there is also available Databook of Adhesion Promoters, which contains data on many most extensively used commercial additives. Both books contain the most recent information available in literature, patents, and published by manufacturers and users of these products. \u003cbr\u003eThe Handbook of Adhesion Promoters is an important reference for chemists, engineers, and materials scientists in various industries. It is also suitable as a reference book for advanced graduate students.\u003cbr\u003eIt is recommended for readers interested in all aspects of polymers and plastics, with special attention to the development, studies, legislation, and production of adhesives, aerospace, agriculture, automotive, bitumen, ceramic tiles, coated fabrics, coatings and paints, coil coatings, composites, construction, cosmetics, dental, electrodes, electronics, flooring, food applications, inks, laminates, medical, membranes, metal coating, pharmaceutical, roofing, sealants, tires, waterproofing, and wire \u0026amp; cable.\u003cbr\u003e\u003c\/p\u003e\n\u003ch5\u003eTable of Contents\u003c\/h5\u003e\n\u003cstrong\u003e1 Introduction\u003c\/strong\u003e \u003cbr data-mce-fragment=\"1\"\u003e1.1 Definitions \u003cbr data-mce-fragment=\"1\"\u003e1.2 History \u003cbr data-mce-fragment=\"1\"\u003e\u003cstrong\u003e2 Mechanisms of Adhesion\u003c\/strong\u003e \u003cbr data-mce-fragment=\"1\"\u003e2.1 Mechanical interlocking \u003cbr data-mce-fragment=\"1\"\u003e2.2 Surface condition and shape \u003cbr data-mce-fragment=\"1\"\u003e2.3 Diffusion and entanglement \u003cbr data-mce-fragment=\"1\"\u003e2.4 Adsorption\/interaction \u003cbr data-mce-fragment=\"1\"\u003e2.5 Acid-base and electrostatic interactions\u003cbr data-mce-fragment=\"1\"\u003e2.5.1 Acid-base interactions \u003cbr data-mce-fragment=\"1\"\u003e2.5.2 Electrostatic interactions \u003cbr data-mce-fragment=\"1\"\u003e2.6 Surface free energy and wetting \u003cbr data-mce-fragment=\"1\"\u003e2.7 Crystalline properties \u003cbr data-mce-fragment=\"1\"\u003e2.8 Interphase formation \u003cbr data-mce-fragment=\"1\"\u003e2.9 Chemical bonding \u003cbr data-mce-fragment=\"1\"\u003e2.10 Hydrogen bonding \u003cbr data-mce-fragment=\"1\"\u003e2.11 Reversible hydrolysis \u003cbr data-mce-fragment=\"1\"\u003e2.12 Microbiological and biological adhesion \u003cbr data-mce-fragment=\"1\"\u003e2.13 Cellular adhesion \u003cbr data-mce-fragment=\"1\"\u003e\u003cstrong\u003e3 Mechanisms of Adhesion Loss\u003c\/strong\u003e \u003cbr data-mce-fragment=\"1\"\u003e3.1 Corrosion \u003cbr data-mce-fragment=\"1\"\u003e3.2 Delamination \u003cbr data-mce-fragment=\"1\"\u003e3.3 Detachment \u003cbr data-mce-fragment=\"1\"\u003e3.4 Debonding \u003cbr data-mce-fragment=\"1\"\u003e3.5 Liquid penetration \u003cbr data-mce-fragment=\"1\"\u003e3.6 Peeling \u003cbr data-mce-fragment=\"1\"\u003e\u003cstrong\u003e4 Substrates - Surface Condition and Treatment\u003c\/strong\u003e \u003cbr data-mce-fragment=\"1\"\u003e4.1 Surface evaluation \u003cbr data-mce-fragment=\"1\"\u003e4.2 Surface treatment \u003cbr data-mce-fragment=\"1\"\u003e4.2.1 Cleaning \u003cbr data-mce-fragment=\"1\"\u003e4.2.2 Mechanical \u003cbr data-mce-fragment=\"1\"\u003e4.2.3 Plasma \u003cbr data-mce-fragment=\"1\"\u003e4.2.4 Microwave plasma \u003cbr data-mce-fragment=\"1\"\u003e4.2.5 Flame \u003cbr data-mce-fragment=\"1\"\u003e4.2.6 Corona discharge \u003cbr data-mce-fragment=\"1\"\u003e4.2.7 Laser \u003cbr data-mce-fragment=\"1\"\u003e4.2.8 UV \u003cbr data-mce-fragment=\"1\"\u003e4.2.9 Chemical modification \u003cbr data-mce-fragment=\"1\"\u003e\u003cstrong\u003e5 Typical Primer Formulations and Applications to Different Substrates\u003c\/strong\u003e \u003cbr data-mce-fragment=\"1\"\u003e5.1 Adhesives and sealants \u003cbr data-mce-fragment=\"1\"\u003e5.2 Coatings \u003cbr data-mce-fragment=\"1\"\u003e5.3 Coil coating \u003cbr data-mce-fragment=\"1\"\u003e5.4 Cosmetics \u003cbr data-mce-fragment=\"1\"\u003e5.5 Dental \u003cbr data-mce-fragment=\"1\"\u003e5.6 Leather \u003cbr data-mce-fragment=\"1\"\u003e5.7 Metal \u003cbr data-mce-fragment=\"1\"\u003e5.8 Optical devices \u003cbr data-mce-fragment=\"1\"\u003e5.9 Paper \u003cbr data-mce-fragment=\"1\"\u003e5.10 Polymers and plastics \u003cbr data-mce-fragment=\"1\"\u003e5.11 Printing \u003cbr data-mce-fragment=\"1\"\u003e5.12 Wood \u003cbr data-mce-fragment=\"1\"\u003e\u003cstrong\u003e6 Polymer Modification to Improve Adhesion\u003c\/strong\u003e \u003cbr data-mce-fragment=\"1\"\u003e6.1 Selection of co-monomers \u003cbr data-mce-fragment=\"1\"\u003e6.2 Selection of polyols and isocyanates \u003cbr data-mce-fragment=\"1\"\u003e6.3 Modification of polymers by maleic anhydride \u003cbr data-mce-fragment=\"1\"\u003e6.4 Modification by epoxy group \u003cbr data-mce-fragment=\"1\"\u003e6.5 Silane grafting \u003cbr data-mce-fragment=\"1\"\u003e\u003cstrong\u003e7 Properties of Adhesion Promoters\u003c\/strong\u003e \u003cbr data-mce-fragment=\"1\"\u003e7.1 Acrylates \u003cbr data-mce-fragment=\"1\"\u003e7.2 Amines, amides, aminoamides \u003cbr data-mce-fragment=\"1\"\u003e7.3 Aryl diazonium salts \u003cbr data-mce-fragment=\"1\"\u003e7.4 Benzene derivatives \u003cbr data-mce-fragment=\"1\"\u003e7.5 Carbamic resin \u003cbr data-mce-fragment=\"1\"\u003e7.6 Chlorinated polyolefins \u003cbr data-mce-fragment=\"1\"\u003e7.7 Crosslinkers \u003cbr data-mce-fragment=\"1\"\u003e7.8 Epoxides \u003cbr data-mce-fragment=\"1\"\u003e7.9 Esters \u003cbr data-mce-fragment=\"1\"\u003e7.10 Inorganic compounds \u003cbr data-mce-fragment=\"1\"\u003e7.11 Ionomers \u003cbr data-mce-fragment=\"1\"\u003e7.12 Isocyanates \u003cbr data-mce-fragment=\"1\"\u003e7.13 Isocyanurates \u003cbr data-mce-fragment=\"1\"\u003e7.14 Lignin \u003cbr data-mce-fragment=\"1\"\u003e7.15 Maleic anhydride modified polymers \u003cbr data-mce-fragment=\"1\"\u003e7.16 Melamine \u003cbr data-mce-fragment=\"1\"\u003e7.17 Monomers \u003cbr data-mce-fragment=\"1\"\u003e7.18 Oligomers \u003cbr data-mce-fragment=\"1\"\u003e7.19 Phenol novolac resins \u003cbr data-mce-fragment=\"1\"\u003e7.20 Phosphoric acid esters \u003cbr data-mce-fragment=\"1\"\u003e7.21 Polymers and copolymers \u003cbr data-mce-fragment=\"1\"\u003e7.22 Polyols \u003cbr data-mce-fragment=\"1\"\u003e7.23 Resorcinol \u003cbr data-mce-fragment=\"1\"\u003e7.24 Rosin \u003cbr data-mce-fragment=\"1\"\u003e7.25 Silanes \u003cbr data-mce-fragment=\"1\"\u003e7.26 Silane+silica \u003cbr data-mce-fragment=\"1\"\u003e7.27 Silane+silicate \u003cbr data-mce-fragment=\"1\"\u003e7.28 Silane+titanate \u003cbr data-mce-fragment=\"1\"\u003e7.29 Sucrose derivatives \u003cbr data-mce-fragment=\"1\"\u003e7.30 Sulfur compounds \u003cbr data-mce-fragment=\"1\"\u003e7.31 Titanates \u003cbr data-mce-fragment=\"1\"\u003e\u003cstrong\u003e8 Selection of Adhesion Promoters for Different Substrates\u003c\/strong\u003e \u003cbr data-mce-fragment=\"1\"\u003e8.1 ABS \u003cbr data-mce-fragment=\"1\"\u003e8.2 Alkyd resins \u003cbr data-mce-fragment=\"1\"\u003e8.3 Cellulose and its derivatives \u003cbr data-mce-fragment=\"1\"\u003e8.4 Epoxy resin \u003cbr data-mce-fragment=\"1\"\u003e8.5 Glass \u003cbr data-mce-fragment=\"1\"\u003e8.6 Metal \u003cbr data-mce-fragment=\"1\"\u003e8.7 Poly(3,4-ethylenedioxythiophene) \u003cbr data-mce-fragment=\"1\"\u003e8.8 Polyamide \u003cbr data-mce-fragment=\"1\"\u003e8.9 Polyaniline \u003cbr data-mce-fragment=\"1\"\u003e8.10 Polycarbonate \u003cbr data-mce-fragment=\"1\"\u003e8.11 Polydimethylsiloxane \u003cbr data-mce-fragment=\"1\"\u003e8.12 Polyester \u003cbr data-mce-fragment=\"1\"\u003e8.13 Polyetheretherketone \u003cbr data-mce-fragment=\"1\"\u003e8.14 Polyethylene \u003cbr data-mce-fragment=\"1\"\u003e8.15 Polyimide \u003cbr data-mce-fragment=\"1\"\u003e8.16 Poly(lactic acid) \u003cbr data-mce-fragment=\"1\"\u003e8.17 Polypropylene \u003cbr data-mce-fragment=\"1\"\u003e8.18 Polystyrene \u003cbr data-mce-fragment=\"1\"\u003e8.19 Polysulfide \u003cbr data-mce-fragment=\"1\"\u003e8.20 Polysulfone \u003cbr data-mce-fragment=\"1\"\u003e8.21 Polytetrafluoroethylene \u003cbr data-mce-fragment=\"1\"\u003e8.22 Polyurethane \u003cbr data-mce-fragment=\"1\"\u003e8.23 Polyvinylalcohol \u003cbr data-mce-fragment=\"1\"\u003e8.24 Polyvinylbutyral \u003cbr data-mce-fragment=\"1\"\u003e8.25 Polyvinylchloride \u003cbr data-mce-fragment=\"1\"\u003e8.26 Poly(p-xylylene) \u003cbr data-mce-fragment=\"1\"\u003e8.27 Porcelain \u003cbr data-mce-fragment=\"1\"\u003e8.28 Rubber \u003cbr data-mce-fragment=\"1\"\u003e8.29 TPO \u003cbr data-mce-fragment=\"1\"\u003e\u003cstrong\u003e9 Selection of Adhesion Promoters for Different Products\u003c\/strong\u003e \u003cbr data-mce-fragment=\"1\"\u003e9.1 Adhesives \u003cbr data-mce-fragment=\"1\"\u003e9.2 Aerospace \u003cbr data-mce-fragment=\"1\"\u003e9.3 Agriculture \u003cbr data-mce-fragment=\"1\"\u003e9.4 Automotive \u003cbr data-mce-fragment=\"1\"\u003e9.5 Bitumen \u003cbr data-mce-fragment=\"1\"\u003e9.6 Ceramic tiles \u003cbr data-mce-fragment=\"1\"\u003e9.7 Coated fabrics \u003cbr data-mce-fragment=\"1\"\u003e9.8 Coatings and paints \u003cbr data-mce-fragment=\"1\"\u003e9.9 Coil coatings \u003cbr data-mce-fragment=\"1\"\u003e9.10 Composites \u003cbr data-mce-fragment=\"1\"\u003e9.11 Construction \u003cbr data-mce-fragment=\"1\"\u003e9.12 Cosmetics \u003cbr data-mce-fragment=\"1\"\u003e9.13 Dental \u003cbr data-mce-fragment=\"1\"\u003e9.14 Electrodes \u003cbr data-mce-fragment=\"1\"\u003e9.15 Electronics \u003cbr data-mce-fragment=\"1\"\u003e9.16 Flooring \u003cbr data-mce-fragment=\"1\"\u003e9.17 Food applications \u003cbr data-mce-fragment=\"1\"\u003e9.18 Inks \u003cbr data-mce-fragment=\"1\"\u003e9.19 Laminates \u003cbr data-mce-fragment=\"1\"\u003e9.20 Medical \u003cbr data-mce-fragment=\"1\"\u003e9.21 Membranes \u003cbr data-mce-fragment=\"1\"\u003e9.22 Metal coating \u003cbr data-mce-fragment=\"1\"\u003e9.23 Pharmaceutical \u003cbr data-mce-fragment=\"1\"\u003e9.24 Roofing \u003cbr data-mce-fragment=\"1\"\u003e9.25 Sealants \u003cbr data-mce-fragment=\"1\"\u003e9.26 Tires \u003cbr data-mce-fragment=\"1\"\u003e9.27 Waterproofing \u003cbr data-mce-fragment=\"1\"\u003e9.28 Wire \u0026amp; cable \u003cbr data-mce-fragment=\"1\"\u003e\u003cstrong\u003e10 Adhesion and Corrosion Protection \u003c\/strong\u003e\u003cbr data-mce-fragment=\"1\"\u003e\u003cstrong\u003eIndex\u003c\/strong\u003e\u003cbr data-mce-fragment=\"1\"\u003e\u003cbr\u003e\u003cbr\u003e\n\u003ch5\u003eAbout Author\u003c\/h5\u003e\nGeorge Wypych has PhD Eng. The professional expertise includes university teaching (full professor) and research \u0026amp; development (university and corporate). He has published 48 books (PVC Plastisols, Wroclaw University Press; Polyvinylchloride Degradation, Elsevier; Polyvinylchloride Stabilization, Elsevier; Polymer Modified Textile Materials, Wiley \u0026amp; Sons; Handbook of Material Weathering, 1st, 2nd, 3rd, 4th, 5th, 6th Edition, ChemTec Publishing; Handbook of Fillers, 1st, 2nd, 3rd, 4th, and 5th Edition, ChemTec Publishing; Recycling of PVC, ChemTec Publishing; Weathering of Plastics. Testing to Mirror Real Life Performance, Plastics Design Library, Handbook of Solvents, Vol. 1. Properties 1st, 2nd, and 3rd Edition, ChemTec Publishing, Handbook of Solvents, Vol. 2. Health \u0026amp; Environment 1st, 2nd, and 3rd Edition, ChemTec Publishing, Handbook of Plasticizers, 1st, 2nd, 3rd, 4th Edition, ChemTec Publishing, Handbook of Antistatics, 1st and 2nd Edition, ChemTec Publishing, Databook of Antistatics, 1st and 2nd Edition, ChemTec Publishing, Handbook of Antiblocking, Release and Slip Additives, 1st , 2nd and 3rd Edition, ChemTec Publishing, Industrial Solvents in Kirk-Othmer Encyclopedia of Chemical Technology (two editions), John Wiley \u0026amp; Sons, PVC Degradation \u0026amp; Stabilization, 1st, 2nd, 3rd, and 4th Editions, ChemTec Publishing, The PVC Formulary, 1st, 2nd, and 3rd Editions, ChemTec Publishing, Handbook of Material Biodegradation, Biodeterioration, and Biostabilization, 1st and 2nd Editions, ChemTec Publishing, Handbook of UV Degradation and Stabilization, 1st, 2nd, and 3rd Editions, ChemTec Publishing, Handbook of Polymers, 1st, 2nd, and 3rd Editions, ChemTec Publishing, Atlas of Material Damage, 1st, 2nd, and 3rd Editions, ChemTec Publishing, Handbook of Odors in Plastic Materials, 1st, 2nd, and 3rd Editions, ChemTec Publishing, Databook of Solvents (two editions), ChemTec Publishing, Databook of Blowing and Auxiliary Agents, ChemTec Publishing, Handbook of Foaming and Blowing Agents (two editions), ChemTec Publishing, Databook of Green Solvents, ChemTec Publishing (two editions), Self-healing Products (two editions), ChemTec Publishing, Handbook of Adhesion Promoters (two editions), ChemTec Publishing, Databook of Surface Modification Additives (two editions), ChemTec Publishing, Handbook of Surface Improvement and Modification (two editions), ChemTec Publishing, Graphene – Important Results and Applications, ChemTec Publishing, Handbook of Curatives and Crosslinkers, ChemTec Publishing, Chain Mobility and Progress in Medicine, Pharmaceutical, Polymer Science and Technology, Impact of Award, ChemTec Publishing, Databook of Antioxidants, ChemTec Publishing, Handbook of Antioxidants, ChemTec Publishing, Databook of UV Stabilizers (two Editions), ChemTec Publishing, Databook of Flame Retardants, ChemTec Publishing, Databook of Nucleating Agents, ChemTec Publishing, Handbook of Flame Retardants, ChemTec Publishing, Handbook of Nucleating Agents, ChemTec Publishing, Handbook of Polymers in Electronics, ChemTec Publishing, Databook of Impact Modifiers, ChemTec Publishing, Databook of Rheological Additives, ChemTec Publishing, Handbook of Impact Modifiers, ChemTec Publishing, Handbook of Rheological Additives, ChemTec Publishing, Databook of Polymer Processing Additives, ChemTec Publishing, Handbook of Polymer Processing Additives, ChemTec Publishing, Functional Fillers (two editions), 2 databases (Solvents Database, 1st, 2nd, 3rd Edition and Database of Antistatics 1st and 2nd Edition, both by ChemTec Publishing), and 42 scientific papers and obtained 16 patents. He specializes in PVC, polymer additives, material durability, and the development of sealants and coatings. He was included in the Dictionary of International Biography, Who's Who in Plastics and Polymers, and Who's Who in Engineering, and was selected International Man of the Year 1996-1997 in recognition of services to education.","published_at":"2023-02-24T14:28:53-05:00","created_at":"2023-02-24T14:15:19-05:00","vendor":"Chemtec Publishing","type":"Book","tags":["2023","additive","additives","adhesion","book","filler","fillers","new","polymer","polymers","properties","surface"],"price":33500,"price_min":33500,"price_max":33500,"available":true,"price_varies":false,"compare_at_price":null,"compare_at_price_min":0,"compare_at_price_max":0,"compare_at_price_varies":false,"variants":[{"id":43394020933789,"title":"Default Title","option1":"Default Title","option2":null,"option3":null,"sku":"","requires_shipping":true,"taxable":true,"featured_image":null,"available":true,"name":"Handbook of Adhesion Promoters, 2nd Ed.","public_title":null,"options":["Default Title"],"price":33500,"weight":1000,"compare_at_price":null,"inventory_quantity":0,"inventory_management":null,"inventory_policy":"continue","barcode":"978-1-77467-018-7","requires_selling_plan":false,"selling_plan_allocations":[]}],"images":["\/\/chemtec.org\/cdn\/shop\/products\/9781774670187-Case.png?v=1677266905"],"featured_image":"\/\/chemtec.org\/cdn\/shop\/products\/9781774670187-Case.png?v=1677266905","options":["Title"],"media":[{"alt":null,"id":27340098863261,"position":1,"preview_image":{"aspect_ratio":0.658,"height":450,"width":296,"src":"\/\/chemtec.org\/cdn\/shop\/products\/9781774670187-Case.png?v=1677266905"},"aspect_ratio":0.658,"height":450,"media_type":"image","src":"\/\/chemtec.org\/cdn\/shop\/products\/9781774670187-Case.png?v=1677266905","width":296}],"requires_selling_plan":false,"selling_plan_groups":[],"content":"\u003ch5\u003eDescription\u003c\/h5\u003e\nAuthor: George Wypych\u003cbr\u003eISBN 978-1-77467-018-7 \u003cbr\u003e\u003cbr\u003e \u003cmeta charset=\"utf-8\"\u003e\n\u003cp\u003ePages 322+vi\u003cbr\u003eFigures 154\u003cbr\u003ePublished Jan. 2023\u003cbr\u003e\u003c\/p\u003e\n\u003ch5\u003eSummary\u003c\/h5\u003e\n\u003cp\u003eAdhesion promoters form a significant group of additives, without, which many industrial products cannot perform according to requirements. The knowledge on this subject mostly related to silanes, which form the most widely used group of these additives, is frequently based on the book which was published at the beginning of 1980s by a scientist who developed many silanes used until today. Since then, many new additives were introduced into the market. Most of these new additives are not based on silanes but on one of over 30 chemical groups of chemical compounds needed for a variety of products in which silanes do not function, are too expensive, or better performance can be achieved with these new additives.\u003cbr\u003e\u003cbr\u003eThis book fills the existing gap in the literature, which still lacks the most recent comprehensive review of current options and knowledge. Handbook of Adhesion Promoters contains 10 chapters, each discussing essential aspects of the application of adhesion promoters. The known mechanisms which belong to one of 13 groups outline principles of use, action, and application of these additives. This chapter is followed by the discussion of mechanisms that cause adhesion loss, such as corrosion, delamination, detachment, liquid penetration, and peeling.\u003cbr\u003e\u003cbr\u003eSurface condition and its treatment are discussed regarding surface treatment by different methods (cleaning, mechanical, plasma, microwave, flame, corona discharge, laser, UV, and chemical modification), which are used in practical applications. All these are illustrated with practical examples.\u003cbr\u003e\u003cbr\u003eChapter 5 gives formulations of typical primers used in the application of adhesives and sealants, coatings, coil coatings, cosmetics, dental, leather, metal, optical devices, paper, polymers and plastics, printing, and wood. This chapter contains over 50 primer formulations.\u003cbr\u003e\u003cbr\u003eA full chapter is devoted to the subject of polymer modification which can improve adhesion – a method frequently used instead of the addition of adhesion promoters. The properties of (over 30 groups of adhesion promoters and their potential applications are discussed in the chapter devoted to this subject based on published articles, manufacturers’ information, and analysis of patents.\u003cbr\u003e\u003cbr\u003eThe last three chapters contain information on available evaluation and selection of adhesion promoters that work with different polymers (29), products (28) and help to prevent corrosion. A full list of covered polymers and products is given in the table of contents below.\u003cbr\u003e\u003cbr\u003eIn addition to the theoretical and practical knowledge required to effectively formulate products used in various applications discussed in this book, there is also available Databook of Adhesion Promoters, which contains data on many most extensively used commercial additives. Both books contain the most recent information available in literature, patents, and published by manufacturers and users of these products. \u003cbr\u003eThe Handbook of Adhesion Promoters is an important reference for chemists, engineers, and materials scientists in various industries. It is also suitable as a reference book for advanced graduate students.\u003cbr\u003eIt is recommended for readers interested in all aspects of polymers and plastics, with special attention to the development, studies, legislation, and production of adhesives, aerospace, agriculture, automotive, bitumen, ceramic tiles, coated fabrics, coatings and paints, coil coatings, composites, construction, cosmetics, dental, electrodes, electronics, flooring, food applications, inks, laminates, medical, membranes, metal coating, pharmaceutical, roofing, sealants, tires, waterproofing, and wire \u0026amp; cable.\u003cbr\u003e\u003c\/p\u003e\n\u003ch5\u003eTable of Contents\u003c\/h5\u003e\n\u003cstrong\u003e1 Introduction\u003c\/strong\u003e \u003cbr data-mce-fragment=\"1\"\u003e1.1 Definitions \u003cbr data-mce-fragment=\"1\"\u003e1.2 History \u003cbr data-mce-fragment=\"1\"\u003e\u003cstrong\u003e2 Mechanisms of Adhesion\u003c\/strong\u003e \u003cbr data-mce-fragment=\"1\"\u003e2.1 Mechanical interlocking \u003cbr data-mce-fragment=\"1\"\u003e2.2 Surface condition and shape \u003cbr data-mce-fragment=\"1\"\u003e2.3 Diffusion and entanglement \u003cbr data-mce-fragment=\"1\"\u003e2.4 Adsorption\/interaction \u003cbr data-mce-fragment=\"1\"\u003e2.5 Acid-base and electrostatic interactions\u003cbr data-mce-fragment=\"1\"\u003e2.5.1 Acid-base interactions \u003cbr data-mce-fragment=\"1\"\u003e2.5.2 Electrostatic interactions \u003cbr data-mce-fragment=\"1\"\u003e2.6 Surface free energy and wetting \u003cbr data-mce-fragment=\"1\"\u003e2.7 Crystalline properties \u003cbr data-mce-fragment=\"1\"\u003e2.8 Interphase formation \u003cbr data-mce-fragment=\"1\"\u003e2.9 Chemical bonding \u003cbr data-mce-fragment=\"1\"\u003e2.10 Hydrogen bonding \u003cbr data-mce-fragment=\"1\"\u003e2.11 Reversible hydrolysis \u003cbr data-mce-fragment=\"1\"\u003e2.12 Microbiological and biological adhesion \u003cbr data-mce-fragment=\"1\"\u003e2.13 Cellular adhesion \u003cbr data-mce-fragment=\"1\"\u003e\u003cstrong\u003e3 Mechanisms of Adhesion Loss\u003c\/strong\u003e \u003cbr data-mce-fragment=\"1\"\u003e3.1 Corrosion \u003cbr data-mce-fragment=\"1\"\u003e3.2 Delamination \u003cbr data-mce-fragment=\"1\"\u003e3.3 Detachment \u003cbr data-mce-fragment=\"1\"\u003e3.4 Debonding \u003cbr data-mce-fragment=\"1\"\u003e3.5 Liquid penetration \u003cbr data-mce-fragment=\"1\"\u003e3.6 Peeling \u003cbr data-mce-fragment=\"1\"\u003e\u003cstrong\u003e4 Substrates - Surface Condition and Treatment\u003c\/strong\u003e \u003cbr data-mce-fragment=\"1\"\u003e4.1 Surface evaluation \u003cbr data-mce-fragment=\"1\"\u003e4.2 Surface treatment \u003cbr data-mce-fragment=\"1\"\u003e4.2.1 Cleaning \u003cbr data-mce-fragment=\"1\"\u003e4.2.2 Mechanical \u003cbr data-mce-fragment=\"1\"\u003e4.2.3 Plasma \u003cbr data-mce-fragment=\"1\"\u003e4.2.4 Microwave plasma \u003cbr data-mce-fragment=\"1\"\u003e4.2.5 Flame \u003cbr data-mce-fragment=\"1\"\u003e4.2.6 Corona discharge \u003cbr data-mce-fragment=\"1\"\u003e4.2.7 Laser \u003cbr data-mce-fragment=\"1\"\u003e4.2.8 UV \u003cbr data-mce-fragment=\"1\"\u003e4.2.9 Chemical modification \u003cbr data-mce-fragment=\"1\"\u003e\u003cstrong\u003e5 Typical Primer Formulations and Applications to Different Substrates\u003c\/strong\u003e \u003cbr data-mce-fragment=\"1\"\u003e5.1 Adhesives and sealants \u003cbr data-mce-fragment=\"1\"\u003e5.2 Coatings \u003cbr data-mce-fragment=\"1\"\u003e5.3 Coil coating \u003cbr data-mce-fragment=\"1\"\u003e5.4 Cosmetics \u003cbr data-mce-fragment=\"1\"\u003e5.5 Dental \u003cbr data-mce-fragment=\"1\"\u003e5.6 Leather \u003cbr data-mce-fragment=\"1\"\u003e5.7 Metal \u003cbr data-mce-fragment=\"1\"\u003e5.8 Optical devices \u003cbr data-mce-fragment=\"1\"\u003e5.9 Paper \u003cbr data-mce-fragment=\"1\"\u003e5.10 Polymers and plastics \u003cbr data-mce-fragment=\"1\"\u003e5.11 Printing \u003cbr data-mce-fragment=\"1\"\u003e5.12 Wood \u003cbr data-mce-fragment=\"1\"\u003e\u003cstrong\u003e6 Polymer Modification to Improve Adhesion\u003c\/strong\u003e \u003cbr data-mce-fragment=\"1\"\u003e6.1 Selection of co-monomers \u003cbr data-mce-fragment=\"1\"\u003e6.2 Selection of polyols and isocyanates \u003cbr data-mce-fragment=\"1\"\u003e6.3 Modification of polymers by maleic anhydride \u003cbr data-mce-fragment=\"1\"\u003e6.4 Modification by epoxy group \u003cbr data-mce-fragment=\"1\"\u003e6.5 Silane grafting \u003cbr data-mce-fragment=\"1\"\u003e\u003cstrong\u003e7 Properties of Adhesion Promoters\u003c\/strong\u003e \u003cbr data-mce-fragment=\"1\"\u003e7.1 Acrylates \u003cbr data-mce-fragment=\"1\"\u003e7.2 Amines, amides, aminoamides \u003cbr data-mce-fragment=\"1\"\u003e7.3 Aryl diazonium salts \u003cbr data-mce-fragment=\"1\"\u003e7.4 Benzene derivatives \u003cbr data-mce-fragment=\"1\"\u003e7.5 Carbamic resin \u003cbr data-mce-fragment=\"1\"\u003e7.6 Chlorinated polyolefins \u003cbr data-mce-fragment=\"1\"\u003e7.7 Crosslinkers \u003cbr data-mce-fragment=\"1\"\u003e7.8 Epoxides \u003cbr data-mce-fragment=\"1\"\u003e7.9 Esters \u003cbr data-mce-fragment=\"1\"\u003e7.10 Inorganic compounds \u003cbr data-mce-fragment=\"1\"\u003e7.11 Ionomers \u003cbr data-mce-fragment=\"1\"\u003e7.12 Isocyanates \u003cbr data-mce-fragment=\"1\"\u003e7.13 Isocyanurates \u003cbr data-mce-fragment=\"1\"\u003e7.14 Lignin \u003cbr data-mce-fragment=\"1\"\u003e7.15 Maleic anhydride modified polymers \u003cbr data-mce-fragment=\"1\"\u003e7.16 Melamine \u003cbr data-mce-fragment=\"1\"\u003e7.17 Monomers \u003cbr data-mce-fragment=\"1\"\u003e7.18 Oligomers \u003cbr data-mce-fragment=\"1\"\u003e7.19 Phenol novolac resins \u003cbr data-mce-fragment=\"1\"\u003e7.20 Phosphoric acid esters \u003cbr data-mce-fragment=\"1\"\u003e7.21 Polymers and copolymers \u003cbr data-mce-fragment=\"1\"\u003e7.22 Polyols \u003cbr data-mce-fragment=\"1\"\u003e7.23 Resorcinol \u003cbr data-mce-fragment=\"1\"\u003e7.24 Rosin \u003cbr data-mce-fragment=\"1\"\u003e7.25 Silanes \u003cbr data-mce-fragment=\"1\"\u003e7.26 Silane+silica \u003cbr data-mce-fragment=\"1\"\u003e7.27 Silane+silicate \u003cbr data-mce-fragment=\"1\"\u003e7.28 Silane+titanate \u003cbr data-mce-fragment=\"1\"\u003e7.29 Sucrose derivatives \u003cbr data-mce-fragment=\"1\"\u003e7.30 Sulfur compounds \u003cbr data-mce-fragment=\"1\"\u003e7.31 Titanates \u003cbr data-mce-fragment=\"1\"\u003e\u003cstrong\u003e8 Selection of Adhesion Promoters for Different Substrates\u003c\/strong\u003e \u003cbr data-mce-fragment=\"1\"\u003e8.1 ABS \u003cbr data-mce-fragment=\"1\"\u003e8.2 Alkyd resins \u003cbr data-mce-fragment=\"1\"\u003e8.3 Cellulose and its derivatives \u003cbr data-mce-fragment=\"1\"\u003e8.4 Epoxy resin \u003cbr data-mce-fragment=\"1\"\u003e8.5 Glass \u003cbr data-mce-fragment=\"1\"\u003e8.6 Metal \u003cbr data-mce-fragment=\"1\"\u003e8.7 Poly(3,4-ethylenedioxythiophene) \u003cbr data-mce-fragment=\"1\"\u003e8.8 Polyamide \u003cbr data-mce-fragment=\"1\"\u003e8.9 Polyaniline \u003cbr data-mce-fragment=\"1\"\u003e8.10 Polycarbonate \u003cbr data-mce-fragment=\"1\"\u003e8.11 Polydimethylsiloxane \u003cbr data-mce-fragment=\"1\"\u003e8.12 Polyester \u003cbr data-mce-fragment=\"1\"\u003e8.13 Polyetheretherketone \u003cbr data-mce-fragment=\"1\"\u003e8.14 Polyethylene \u003cbr data-mce-fragment=\"1\"\u003e8.15 Polyimide \u003cbr data-mce-fragment=\"1\"\u003e8.16 Poly(lactic acid) \u003cbr data-mce-fragment=\"1\"\u003e8.17 Polypropylene \u003cbr data-mce-fragment=\"1\"\u003e8.18 Polystyrene \u003cbr data-mce-fragment=\"1\"\u003e8.19 Polysulfide \u003cbr data-mce-fragment=\"1\"\u003e8.20 Polysulfone \u003cbr data-mce-fragment=\"1\"\u003e8.21 Polytetrafluoroethylene \u003cbr data-mce-fragment=\"1\"\u003e8.22 Polyurethane \u003cbr data-mce-fragment=\"1\"\u003e8.23 Polyvinylalcohol \u003cbr data-mce-fragment=\"1\"\u003e8.24 Polyvinylbutyral \u003cbr data-mce-fragment=\"1\"\u003e8.25 Polyvinylchloride \u003cbr data-mce-fragment=\"1\"\u003e8.26 Poly(p-xylylene) \u003cbr data-mce-fragment=\"1\"\u003e8.27 Porcelain \u003cbr data-mce-fragment=\"1\"\u003e8.28 Rubber \u003cbr data-mce-fragment=\"1\"\u003e8.29 TPO \u003cbr data-mce-fragment=\"1\"\u003e\u003cstrong\u003e9 Selection of Adhesion Promoters for Different Products\u003c\/strong\u003e \u003cbr data-mce-fragment=\"1\"\u003e9.1 Adhesives \u003cbr data-mce-fragment=\"1\"\u003e9.2 Aerospace \u003cbr data-mce-fragment=\"1\"\u003e9.3 Agriculture \u003cbr data-mce-fragment=\"1\"\u003e9.4 Automotive \u003cbr data-mce-fragment=\"1\"\u003e9.5 Bitumen \u003cbr data-mce-fragment=\"1\"\u003e9.6 Ceramic tiles \u003cbr data-mce-fragment=\"1\"\u003e9.7 Coated fabrics \u003cbr data-mce-fragment=\"1\"\u003e9.8 Coatings and paints \u003cbr data-mce-fragment=\"1\"\u003e9.9 Coil coatings \u003cbr data-mce-fragment=\"1\"\u003e9.10 Composites \u003cbr data-mce-fragment=\"1\"\u003e9.11 Construction \u003cbr data-mce-fragment=\"1\"\u003e9.12 Cosmetics \u003cbr data-mce-fragment=\"1\"\u003e9.13 Dental \u003cbr data-mce-fragment=\"1\"\u003e9.14 Electrodes \u003cbr data-mce-fragment=\"1\"\u003e9.15 Electronics \u003cbr data-mce-fragment=\"1\"\u003e9.16 Flooring \u003cbr data-mce-fragment=\"1\"\u003e9.17 Food applications \u003cbr data-mce-fragment=\"1\"\u003e9.18 Inks \u003cbr data-mce-fragment=\"1\"\u003e9.19 Laminates \u003cbr data-mce-fragment=\"1\"\u003e9.20 Medical \u003cbr data-mce-fragment=\"1\"\u003e9.21 Membranes \u003cbr data-mce-fragment=\"1\"\u003e9.22 Metal coating \u003cbr data-mce-fragment=\"1\"\u003e9.23 Pharmaceutical \u003cbr data-mce-fragment=\"1\"\u003e9.24 Roofing \u003cbr data-mce-fragment=\"1\"\u003e9.25 Sealants \u003cbr data-mce-fragment=\"1\"\u003e9.26 Tires \u003cbr data-mce-fragment=\"1\"\u003e9.27 Waterproofing \u003cbr data-mce-fragment=\"1\"\u003e9.28 Wire \u0026amp; cable \u003cbr data-mce-fragment=\"1\"\u003e\u003cstrong\u003e10 Adhesion and Corrosion Protection \u003c\/strong\u003e\u003cbr data-mce-fragment=\"1\"\u003e\u003cstrong\u003eIndex\u003c\/strong\u003e\u003cbr data-mce-fragment=\"1\"\u003e\u003cbr\u003e\u003cbr\u003e\n\u003ch5\u003eAbout Author\u003c\/h5\u003e\nGeorge Wypych has PhD Eng. The professional expertise includes university teaching (full professor) and research \u0026amp; development (university and corporate). He has published 48 books (PVC Plastisols, Wroclaw University Press; Polyvinylchloride Degradation, Elsevier; Polyvinylchloride Stabilization, Elsevier; Polymer Modified Textile Materials, Wiley \u0026amp; Sons; Handbook of Material Weathering, 1st, 2nd, 3rd, 4th, 5th, 6th Edition, ChemTec Publishing; Handbook of Fillers, 1st, 2nd, 3rd, 4th, and 5th Edition, ChemTec Publishing; Recycling of PVC, ChemTec Publishing; Weathering of Plastics. Testing to Mirror Real Life Performance, Plastics Design Library, Handbook of Solvents, Vol. 1. Properties 1st, 2nd, and 3rd Edition, ChemTec Publishing, Handbook of Solvents, Vol. 2. Health \u0026amp; Environment 1st, 2nd, and 3rd Edition, ChemTec Publishing, Handbook of Plasticizers, 1st, 2nd, 3rd, 4th Edition, ChemTec Publishing, Handbook of Antistatics, 1st and 2nd Edition, ChemTec Publishing, Databook of Antistatics, 1st and 2nd Edition, ChemTec Publishing, Handbook of Antiblocking, Release and Slip Additives, 1st , 2nd and 3rd Edition, ChemTec Publishing, Industrial Solvents in Kirk-Othmer Encyclopedia of Chemical Technology (two editions), John Wiley \u0026amp; Sons, PVC Degradation \u0026amp; Stabilization, 1st, 2nd, 3rd, and 4th Editions, ChemTec Publishing, The PVC Formulary, 1st, 2nd, and 3rd Editions, ChemTec Publishing, Handbook of Material Biodegradation, Biodeterioration, and Biostabilization, 1st and 2nd Editions, ChemTec Publishing, Handbook of UV Degradation and Stabilization, 1st, 2nd, and 3rd Editions, ChemTec Publishing, Handbook of Polymers, 1st, 2nd, and 3rd Editions, ChemTec Publishing, Atlas of Material Damage, 1st, 2nd, and 3rd Editions, ChemTec Publishing, Handbook of Odors in Plastic Materials, 1st, 2nd, and 3rd Editions, ChemTec Publishing, Databook of Solvents (two editions), ChemTec Publishing, Databook of Blowing and Auxiliary Agents, ChemTec Publishing, Handbook of Foaming and Blowing Agents (two editions), ChemTec Publishing, Databook of Green Solvents, ChemTec Publishing (two editions), Self-healing Products (two editions), ChemTec Publishing, Handbook of Adhesion Promoters (two editions), ChemTec Publishing, Databook of Surface Modification Additives (two editions), ChemTec Publishing, Handbook of Surface Improvement and Modification (two editions), ChemTec Publishing, Graphene – Important Results and Applications, ChemTec Publishing, Handbook of Curatives and Crosslinkers, ChemTec Publishing, Chain Mobility and Progress in Medicine, Pharmaceutical, Polymer Science and Technology, Impact of Award, ChemTec Publishing, Databook of Antioxidants, ChemTec Publishing, Handbook of Antioxidants, ChemTec Publishing, Databook of UV Stabilizers (two Editions), ChemTec Publishing, Databook of Flame Retardants, ChemTec Publishing, Databook of Nucleating Agents, ChemTec Publishing, Handbook of Flame Retardants, ChemTec Publishing, Handbook of Nucleating Agents, ChemTec Publishing, Handbook of Polymers in Electronics, ChemTec Publishing, Databook of Impact Modifiers, ChemTec Publishing, Databook of Rheological Additives, ChemTec Publishing, Handbook of Impact Modifiers, ChemTec Publishing, Handbook of Rheological Additives, ChemTec Publishing, Databook of Polymer Processing Additives, ChemTec Publishing, Handbook of Polymer Processing Additives, ChemTec Publishing, Functional Fillers (two editions), 2 databases (Solvents Database, 1st, 2nd, 3rd Edition and Database of Antistatics 1st and 2nd Edition, both by ChemTec Publishing), and 42 scientific papers and obtained 16 patents. He specializes in PVC, polymer additives, material durability, and the development of sealants and coatings. He was included in the Dictionary of International Biography, Who's Who in Plastics and Polymers, and Who's Who in Engineering, and was selected International Man of the Year 1996-1997 in recognition of services to education."}
Handbook of Odors in P...
$350.00
{"id":7703563108509,"title":"Handbook of Odors in Plastic Materials, 3rd Ed.","handle":"handbook-of-odors-in-plastic-materials-3rd-ed","description":"\u003ch5\u003eDescription\u003c\/h5\u003e\n\u003cp\u003e\u003cbr\u003eAuthor: George Wypych \u003cbr\u003eISBN 978-1-77467-020-0 (hard copy) \u003cbr\u003e\u003cbr\u003ePublished: Jan. 2023 \u003cbr data-mce-fragment=\"1\"\u003ePages: 390 + viii\u003cbr data-mce-fragment=\"1\"\u003eFigures: 77\u003cbr data-mce-fragment=\"1\"\u003eTables: 33\u003cbr data-mce-fragment=\"1\"\u003e\u003cbr\u003e\u003c\/p\u003e\n\u003cp\u003e \u003c\/p\u003e\n\u003ch5\u003eSummary\u003c\/h5\u003e\n\u003cp\u003eThis handbook will be of value to a wide range of people involved in the plastics industry, including plastic manufacturing engineers, material scientists and production personnel, quality assurance managers, and laboratory technicians.\u003cbr\u003e\u003cbr\u003eIt is the first book ever written on this crucial subject. The third edition contains a thorough review of the most recent data, achievements, and information in this less-known but very significant field of polymer modification. The odor of the product may decide whether a product is purchased by a customer or not. Odor is also an important reason for customer complaints, legislative work, legal disputes, and product returns. In scented products, the retention of volatile components is of particular interest. Many leading companies have recognized this as an opportunity, and they actively study and modify odors typical of their products.\u003cbr\u003e\u003cbr\u003eSeveral reasons are behind the formation of odors in plastic materials, including \u003cbr\u003e1. Properties of polymer\u003cbr\u003e2. Use of other materials than polymer, especially materials required in processing (additives)\u003cbr\u003e3. Process parameters and their effect on the severity of degradation of components of the formulation\u003cbr\u003e4. Exposure to different forms of radiation and oxygen\u003cbr\u003e5. Recycling of polymeric materials\u003cbr\u003e6. Contact with other products\u003cbr\u003e7. Storage\u003cbr\u003ea. Diffusion-related properties\u003cbr\u003eb. Migration-evaporation\u003cbr\u003ec. Storage in the same space\u003cbr\u003e\u003cbr\u003eThe above reasons are analyzed for different materials to find out the best methods to prevent unwanted odor formation. Three chapters are devoted to the analysis of odor-related matters in different polymers, products, and methods of processing. Almost forty polymers and forty-two product groups are analyzed based on research publications and patents.\u003cbr\u003e\u003cbr\u003eOther important chapters discuss the mechanism of odor formation and its transport within a material, distinctive odors found in plastic materials, taste, and fogging.\u003cbr\u003e\u003cbr\u003eThe book also contains information on testing odor changes, the relationship between odor and toxicity, as well as a selection of raw materials for fog-free products.\u003cbr\u003e\u003cbr\u003eHandbook of Odors in Plastic Materials presents a comprehensive treatise of the state-of-the-art in all aspects of plastic odor. It covers general techniques for testing, evaluation, and control of plastic odors; identification techniques for plastics derived from renewable feedstocks; deodorants and antiozonants; waste management and its impact on the environment; legislation affecting plastic odor-related products; and future trends toward environmental sustainability.\u003cbr\u003e\u003cbr\u003eThe Handbook of Odors in Plastic Materials is needed by anyone interested in plastic materials. The book contains complete information based on hard-to-find source publications and numerous patents.\u003cbr\u003e\u003c\/p\u003e\n\u003cbr\u003e\u003cbr\u003e\n\u003ch5\u003eTable of Contents\u003c\/h5\u003e\n\u003cp\u003e \u003c\/p\u003e\n\u003cp\u003e1 Introduction \u003cbr data-mce-fragment=\"1\"\u003e2 Mechanisms of odor formation and its transport\u003cbr data-mce-fragment=\"1\"\u003e3 Distinctive odors\u003cbr data-mce-fragment=\"1\"\u003e4 Taste \u003cbr data-mce-fragment=\"1\"\u003e5 Fogging \u003cbr data-mce-fragment=\"1\"\u003e6 Reasons for odor formation in plastic materials\u003cbr data-mce-fragment=\"1\"\u003e7 Methods of testing in odor analysis\u003cbr data-mce-fragment=\"1\"\u003e8 Odor in relation to different polymers\u003cbr data-mce-fragment=\"1\"\u003e9 Odor in various products\u003cbr data-mce-fragment=\"1\"\u003e10 Effect of processing method\u003cbr data-mce-fragment=\"1\"\u003e11 Methods of odor removal\u003cbr data-mce-fragment=\"1\"\u003e12 Regulations \u003cbr data-mce-fragment=\"1\"\u003e13 Health and safety \u003cbr data-mce-fragment=\"1\"\u003e14 Indoor air quality\u003cbr data-mce-fragment=\"1\"\u003eIndex\u003cbr data-mce-fragment=\"1\"\u003e\u003c\/p\u003e\n\u003ch5\u003eAbout Author\u003c\/h5\u003e\nGeorge Wypych has PhD Eng. The professional expertise includes university teaching (full professor) and research \u0026amp; development (university and corporate). He has published 48 books (PVC Plastisols, Wroclaw University Press; Polyvinylchloride Degradation, Elsevier; Polyvinylchloride Stabilization, Elsevier; Polymer Modified Textile Materials, Wiley \u0026amp; Sons; Handbook of Material Weathering, 1st, 2nd, 3rd, 4th, 5th, 6th Edition, ChemTec Publishing; Handbook of Fillers, 1st, 2nd, 3rd, 4th, and 5th Edition, ChemTec Publishing; Recycling of PVC, ChemTec Publishing; Weathering of Plastics. Testing to Mirror Real Life Performance, Plastics Design Library, Handbook of Solvents, Vol. 1. Properties 1st, 2nd, and 3rd Edition, ChemTec Publishing, Handbook of Solvents, Vol. 2. Health \u0026amp; Environment 1st, 2nd, and 3rd Edition, ChemTec Publishing, Handbook of Plasticizers, 1st, 2nd, 3rd, 4th Edition, ChemTec Publishing, Handbook of Antistatics, 1st and 2nd Edition, ChemTec Publishing, Databook of Antistatics, 1st and 2nd Edition, ChemTec Publishing, Handbook of Antiblocking, Release and Slip Additives, 1st , 2nd and 3rd Edition, ChemTec Publishing, Industrial Solvents in Kirk-Othmer Encyclopedia of Chemical Technology (two editions), John Wiley \u0026amp; Sons, PVC Degradation \u0026amp; Stabilization, 1st, 2nd, 3rd, and 4th Editions, ChemTec Publishing, The PVC Formulary, 1st, 2nd, and 3rd Editions, ChemTec Publishing, Handbook of Material Biodegradation, Biodeterioration, and Biostabilization, 1st and 2nd Editions, ChemTec Publishing, Handbook of UV Degradation and Stabilization, 1st, 2nd, and 3rd Editions, ChemTec Publishing, Handbook of Polymers, 1st, 2nd, and 3rd Editions, ChemTec Publishing, Atlas of Material Damage, 1st, 2nd, and 3rd Editions, ChemTec Publishing, Handbook of Odors in Plastic Materials, 1st, 2nd, and 3rd Editions, ChemTec Publishing, Databook of Solvents (two editions), ChemTec Publishing, Databook of Blowing and Auxiliary Agents, ChemTec Publishing, Handbook of Foaming and Blowing Agents (two editions), ChemTec Publishing, Databook of Green Solvents, ChemTec Publishing (two editions), Self-healing Products (two editions), ChemTec Publishing, Handbook of Adhesion Promoters (two editions), ChemTec Publishing, Databook of Surface Modification Additives (two editions), ChemTec Publishing, Handbook of Surface Improvement and Modification (two editions), ChemTec Publishing, Graphene – Important Results and Applications, ChemTec Publishing, Handbook of Curatives and Crosslinkers, ChemTec Publishing, Chain Mobility and Progress in Medicine, Pharmaceutical, Polymer Science and Technology, Impact of Award, ChemTec Publishing, Databook of Antioxidants, ChemTec Publishing, Handbook of Antioxidants, ChemTec Publishing, Databook of UV Stabilizers (two Editions), ChemTec Publishing, Databook of Flame Retardants, ChemTec Publishing, Databook of Nucleating Agents, ChemTec Publishing, Handbook of Flame Retardants, ChemTec Publishing, Handbook of Nucleating Agents, ChemTec Publishing, Handbook of Polymers in Electronics, ChemTec Publishing, Databook of Impact Modifiers, ChemTec Publishing, Databook of Rheological Additives, ChemTec Publishing, Handbook of Impact Modifiers, ChemTec Publishing, Handbook of Rheological Additives, ChemTec Publishing, Databook of Polymer Processing Additives, ChemTec Publishing, Handbook of Polymer Processing Additives, ChemTec Publishing, Functional Fillers (two editions), 2 databases (Solvents Database, 1st, 2nd, 3rd Edition and Database of Antistatics 1st and 2nd Edition, both by ChemTec Publishing), and 42 scientific papers and obtained 16 patents. He specializes in PVC, polymer additives, material durability, and the development of sealants and coatings. He was included in the Dictionary of International Biography, Who's Who in Plastics and Polymers, and Who's Who in Engineering, and was selected International Man of the Year 1996-1997 in recognition of services to education.","published_at":"2023-02-24T14:14:51-05:00","created_at":"2023-02-24T14:07:49-05:00","vendor":"Chemtec Publishing","type":"Book","tags":["2023","book","environment","formation odor","general","new","plastic odor","plastics","storage","testning methods"],"price":35000,"price_min":35000,"price_max":35000,"available":true,"price_varies":false,"compare_at_price":null,"compare_at_price_min":0,"compare_at_price_max":0,"compare_at_price_varies":false,"variants":[{"id":43394004549789,"title":"Default Title","option1":"Default Title","option2":null,"option3":null,"sku":"","requires_shipping":true,"taxable":true,"featured_image":null,"available":true,"name":"Handbook of Odors in Plastic Materials, 3rd Ed.","public_title":null,"options":["Default Title"],"price":35000,"weight":1000,"compare_at_price":null,"inventory_quantity":0,"inventory_management":null,"inventory_policy":"deny","barcode":"978-1-77467-020-0","requires_selling_plan":false,"selling_plan_allocations":[]}],"images":["\/\/chemtec.org\/cdn\/shop\/products\/9781774670200-Case.png?v=1677265986"],"featured_image":"\/\/chemtec.org\/cdn\/shop\/products\/9781774670200-Case.png?v=1677265986","options":["Title"],"media":[{"alt":null,"id":27340037882013,"position":1,"preview_image":{"aspect_ratio":0.658,"height":450,"width":296,"src":"\/\/chemtec.org\/cdn\/shop\/products\/9781774670200-Case.png?v=1677265986"},"aspect_ratio":0.658,"height":450,"media_type":"image","src":"\/\/chemtec.org\/cdn\/shop\/products\/9781774670200-Case.png?v=1677265986","width":296}],"requires_selling_plan":false,"selling_plan_groups":[],"content":"\u003ch5\u003eDescription\u003c\/h5\u003e\n\u003cp\u003e\u003cbr\u003eAuthor: George Wypych \u003cbr\u003eISBN 978-1-77467-020-0 (hard copy) \u003cbr\u003e\u003cbr\u003ePublished: Jan. 2023 \u003cbr data-mce-fragment=\"1\"\u003ePages: 390 + viii\u003cbr data-mce-fragment=\"1\"\u003eFigures: 77\u003cbr data-mce-fragment=\"1\"\u003eTables: 33\u003cbr data-mce-fragment=\"1\"\u003e\u003cbr\u003e\u003c\/p\u003e\n\u003cp\u003e \u003c\/p\u003e\n\u003ch5\u003eSummary\u003c\/h5\u003e\n\u003cp\u003eThis handbook will be of value to a wide range of people involved in the plastics industry, including plastic manufacturing engineers, material scientists and production personnel, quality assurance managers, and laboratory technicians.\u003cbr\u003e\u003cbr\u003eIt is the first book ever written on this crucial subject. The third edition contains a thorough review of the most recent data, achievements, and information in this less-known but very significant field of polymer modification. The odor of the product may decide whether a product is purchased by a customer or not. Odor is also an important reason for customer complaints, legislative work, legal disputes, and product returns. In scented products, the retention of volatile components is of particular interest. Many leading companies have recognized this as an opportunity, and they actively study and modify odors typical of their products.\u003cbr\u003e\u003cbr\u003eSeveral reasons are behind the formation of odors in plastic materials, including \u003cbr\u003e1. Properties of polymer\u003cbr\u003e2. Use of other materials than polymer, especially materials required in processing (additives)\u003cbr\u003e3. Process parameters and their effect on the severity of degradation of components of the formulation\u003cbr\u003e4. Exposure to different forms of radiation and oxygen\u003cbr\u003e5. Recycling of polymeric materials\u003cbr\u003e6. Contact with other products\u003cbr\u003e7. Storage\u003cbr\u003ea. Diffusion-related properties\u003cbr\u003eb. Migration-evaporation\u003cbr\u003ec. Storage in the same space\u003cbr\u003e\u003cbr\u003eThe above reasons are analyzed for different materials to find out the best methods to prevent unwanted odor formation. Three chapters are devoted to the analysis of odor-related matters in different polymers, products, and methods of processing. Almost forty polymers and forty-two product groups are analyzed based on research publications and patents.\u003cbr\u003e\u003cbr\u003eOther important chapters discuss the mechanism of odor formation and its transport within a material, distinctive odors found in plastic materials, taste, and fogging.\u003cbr\u003e\u003cbr\u003eThe book also contains information on testing odor changes, the relationship between odor and toxicity, as well as a selection of raw materials for fog-free products.\u003cbr\u003e\u003cbr\u003eHandbook of Odors in Plastic Materials presents a comprehensive treatise of the state-of-the-art in all aspects of plastic odor. It covers general techniques for testing, evaluation, and control of plastic odors; identification techniques for plastics derived from renewable feedstocks; deodorants and antiozonants; waste management and its impact on the environment; legislation affecting plastic odor-related products; and future trends toward environmental sustainability.\u003cbr\u003e\u003cbr\u003eThe Handbook of Odors in Plastic Materials is needed by anyone interested in plastic materials. The book contains complete information based on hard-to-find source publications and numerous patents.\u003cbr\u003e\u003c\/p\u003e\n\u003cbr\u003e\u003cbr\u003e\n\u003ch5\u003eTable of Contents\u003c\/h5\u003e\n\u003cp\u003e \u003c\/p\u003e\n\u003cp\u003e1 Introduction \u003cbr data-mce-fragment=\"1\"\u003e2 Mechanisms of odor formation and its transport\u003cbr data-mce-fragment=\"1\"\u003e3 Distinctive odors\u003cbr data-mce-fragment=\"1\"\u003e4 Taste \u003cbr data-mce-fragment=\"1\"\u003e5 Fogging \u003cbr data-mce-fragment=\"1\"\u003e6 Reasons for odor formation in plastic materials\u003cbr data-mce-fragment=\"1\"\u003e7 Methods of testing in odor analysis\u003cbr data-mce-fragment=\"1\"\u003e8 Odor in relation to different polymers\u003cbr data-mce-fragment=\"1\"\u003e9 Odor in various products\u003cbr data-mce-fragment=\"1\"\u003e10 Effect of processing method\u003cbr data-mce-fragment=\"1\"\u003e11 Methods of odor removal\u003cbr data-mce-fragment=\"1\"\u003e12 Regulations \u003cbr data-mce-fragment=\"1\"\u003e13 Health and safety \u003cbr data-mce-fragment=\"1\"\u003e14 Indoor air quality\u003cbr data-mce-fragment=\"1\"\u003eIndex\u003cbr data-mce-fragment=\"1\"\u003e\u003c\/p\u003e\n\u003ch5\u003eAbout Author\u003c\/h5\u003e\nGeorge Wypych has PhD Eng. The professional expertise includes university teaching (full professor) and research \u0026amp; development (university and corporate). He has published 48 books (PVC Plastisols, Wroclaw University Press; Polyvinylchloride Degradation, Elsevier; Polyvinylchloride Stabilization, Elsevier; Polymer Modified Textile Materials, Wiley \u0026amp; Sons; Handbook of Material Weathering, 1st, 2nd, 3rd, 4th, 5th, 6th Edition, ChemTec Publishing; Handbook of Fillers, 1st, 2nd, 3rd, 4th, and 5th Edition, ChemTec Publishing; Recycling of PVC, ChemTec Publishing; Weathering of Plastics. Testing to Mirror Real Life Performance, Plastics Design Library, Handbook of Solvents, Vol. 1. Properties 1st, 2nd, and 3rd Edition, ChemTec Publishing, Handbook of Solvents, Vol. 2. Health \u0026amp; Environment 1st, 2nd, and 3rd Edition, ChemTec Publishing, Handbook of Plasticizers, 1st, 2nd, 3rd, 4th Edition, ChemTec Publishing, Handbook of Antistatics, 1st and 2nd Edition, ChemTec Publishing, Databook of Antistatics, 1st and 2nd Edition, ChemTec Publishing, Handbook of Antiblocking, Release and Slip Additives, 1st , 2nd and 3rd Edition, ChemTec Publishing, Industrial Solvents in Kirk-Othmer Encyclopedia of Chemical Technology (two editions), John Wiley \u0026amp; Sons, PVC Degradation \u0026amp; Stabilization, 1st, 2nd, 3rd, and 4th Editions, ChemTec Publishing, The PVC Formulary, 1st, 2nd, and 3rd Editions, ChemTec Publishing, Handbook of Material Biodegradation, Biodeterioration, and Biostabilization, 1st and 2nd Editions, ChemTec Publishing, Handbook of UV Degradation and Stabilization, 1st, 2nd, and 3rd Editions, ChemTec Publishing, Handbook of Polymers, 1st, 2nd, and 3rd Editions, ChemTec Publishing, Atlas of Material Damage, 1st, 2nd, and 3rd Editions, ChemTec Publishing, Handbook of Odors in Plastic Materials, 1st, 2nd, and 3rd Editions, ChemTec Publishing, Databook of Solvents (two editions), ChemTec Publishing, Databook of Blowing and Auxiliary Agents, ChemTec Publishing, Handbook of Foaming and Blowing Agents (two editions), ChemTec Publishing, Databook of Green Solvents, ChemTec Publishing (two editions), Self-healing Products (two editions), ChemTec Publishing, Handbook of Adhesion Promoters (two editions), ChemTec Publishing, Databook of Surface Modification Additives (two editions), ChemTec Publishing, Handbook of Surface Improvement and Modification (two editions), ChemTec Publishing, Graphene – Important Results and Applications, ChemTec Publishing, Handbook of Curatives and Crosslinkers, ChemTec Publishing, Chain Mobility and Progress in Medicine, Pharmaceutical, Polymer Science and Technology, Impact of Award, ChemTec Publishing, Databook of Antioxidants, ChemTec Publishing, Handbook of Antioxidants, ChemTec Publishing, Databook of UV Stabilizers (two Editions), ChemTec Publishing, Databook of Flame Retardants, ChemTec Publishing, Databook of Nucleating Agents, ChemTec Publishing, Handbook of Flame Retardants, ChemTec Publishing, Handbook of Nucleating Agents, ChemTec Publishing, Handbook of Polymers in Electronics, ChemTec Publishing, Databook of Impact Modifiers, ChemTec Publishing, Databook of Rheological Additives, ChemTec Publishing, Handbook of Impact Modifiers, ChemTec Publishing, Handbook of Rheological Additives, ChemTec Publishing, Databook of Polymer Processing Additives, ChemTec Publishing, Handbook of Polymer Processing Additives, ChemTec Publishing, Functional Fillers (two editions), 2 databases (Solvents Database, 1st, 2nd, 3rd Edition and Database of Antistatics 1st and 2nd Edition, both by ChemTec Publishing), and 42 scientific papers and obtained 16 patents. He specializes in PVC, polymer additives, material durability, and the development of sealants and coatings. He was included in the Dictionary of International Biography, Who's Who in Plastics and Polymers, and Who's Who in Engineering, and was selected International Man of the Year 1996-1997 in recognition of services to education."}
Handbook of Plasticize...
$390.00
{"id":7703557439645,"title":"Handbook of Plasticizers, 4th Edition","handle":"handbook-of-plasticizers-4th-edition","description":"\u003ch5\u003eDescription\u003c\/h5\u003e\n\u003cp\u003eEditor: George Wypych \u003cbr\u003eISBN 978-1- 77467-022-4 (hard copy)\u003cbr\u003e\u003cbr\u003ePublished: Jan. 2023 \u003cbr data-mce-fragment=\"1\"\u003ePages 894+xxii\u003cbr data-mce-fragment=\"1\"\u003eTables 115, Figures 360\u003cbr data-mce-fragment=\"1\"\u003e\u003cbr\u003e\u003c\/p\u003e\n\u003cp\u003e \u003c\/p\u003e\n\u003ch5\u003eSummary\u003c\/h5\u003e\n\u003cp\u003eHandbook of Plasticizers brings together in one place all that is known about this vital and rapidly expanding field. The book serves both as a basic reference source for researchers, engineers, and others involved in plastics processing, research and development as well as a source of ideas regarding future developments.\u003cbr\u003e\u003cbr\u003eThis book contains a comprehensive review of information available in the open literature, such as published scientific papers, information from plasticizer manufacturers, and patent literature. The information from the most recent sources was used to update information from previous editions. \u003cbr\u003eThe information available today permits the use of plasticizers more effectively and helps to avoid certain plasticizers in applications where they may cause health or material durability problems. The source of raw materials used to produce plasticizers is becoming one of the issues in their selection. The book contains information on plasticizers obtained from renewable resources. Plasticizer incorporation demands a broad background of information because plasticizers are now added to complex mixtures containing a variety of materials that may have different reactions to the presence of plasticizers. Plasticizer choice is also not simple because there is a large selection of commercial plasticizers and various environmental issues dictating preferred solutions.\u003cbr\u003e\u003cbr\u003eBoth aspects considered indicate the need for a comprehensive source which, using currently available means of the computerized database, should provide data and a broad background of theoretical information in a condensed form easy to search. \u003cbr\u003e\u003cbr\u003eNumerical data on the most important plasticizers are provided in the tabular form of the printed book entitled Databook of Plasticizers. \u003cbr\u003eTwenty-one chapters are included in the Handbook of Plasticizers. The full Table of Contents is given below. Only some chapters are discussed here to add more information that may not be obvious from the table of contents.\u003cbr\u003e\u003cbr\u003eData are available for a large number of commercial plasticizers. This data is used in Chapter 2 to specify typical properties of plasticizers that belong to one of the thirty-one groups. The ranges of expected properties for a given group are also given.\u003cbr\u003e\u003cbr\u003eChapters 5, 6, and 7 contain new and historical approaches, which explain the mechanisms of plasticizers’ action and their behavior in plasticized systems. This theoretical background helps to understand practical observations and provides guidance to the methods of material improvement. Chapter 9 shows plasticization steps and results of various analytical studies, which help in understanding these steps and the parameters which may control them.\u003cbr\u003e\u003cbr\u003eTwenty-nine sections of Chapter 10 discuss plasticizers’ effect on the physical and mechanical properties of plasticized materials. These sections are essential for understanding the behavior of materials and the principles of their formulation. \u003cbr\u003e\u003cbr\u003e\u003cbr\u003e\u003cbr\u003e\u003cbr\u003eChapter 11 contains data on the use of plasticizers in 61 groups of polymers. The information is grouped under the following sections – Frequently used plasticizers, Practical concentrations, Main functions performed by plasticizers, Mechanism of plasticizer action, Effect of plasticizers on polymer and other additives, and Typical formulations. The use of such a consistent method of data presentation helps to find information quickly and to compare data from various sources and applications. \u003cbr\u003e\u003cbr\u003eSimilarly, Chapter 13 discusses the use of plasticizers in 33 groups of products according to a similar breakdown, including Plasticizer types, Plasticizer concentration, Reasons for plasticizer use, Advantages and disadvantages of plasticizer use, Effect of plasticizers on product properties, and Examples of formulations. Both chapters make use of a large number of patents and information in open literature discussing the most current findings and trends.\u003cbr\u003e\u003cbr\u003eIn Chapter 14, attempts are being made to discuss the following topics: The effect of plasticizers on process conditions, Processing defects formation and elimination with the use of plasticizers, In the fluence of rheological changes on the process, Equipment maintenance, and energy consumption. This chapter discusses 15 methods of polymer and rubber processing.\u003cbr\u003eSeveral chapters which follow discuss various aspects of plasticizer’s effect on health, safety, and the environment. Chapter 17 contains opinions of renowned experts on various aspects of plasticizers’ effect on health and safety. Chapter 18 contains information on plasticizers’ persistence in soil and water. Plasticizers releases and their presence in the environment are discussed for many important commercial plasticizers.\u003cbr\u003e\u003cbr\u003eThis short review and the Table of Contents show that this book is the most comprehensive source of current information on plasticizers. Plasticizers are used in so many products that every library should have this reference source of information on plasticizers readily available for its readers, especially considering that so many aspects of application plasticizers have recently changed that older books cannot provide the right answers. This book is best used in conjunction with the Plasticizer Database and\/or Databook of Plasticizers which give information on the present status and properties of industrial and research plasticizers.\u003cbr\u003e\u003c\/p\u003e\n\u003cbr\u003e \u003cbr\u003e\u003cbr\u003e\n\u003ch5\u003eTable of Contents\u003c\/h5\u003e\n\u003cp\u003e\u003cstrong\u003e1 INTRODUCTION\u003c\/strong\u003e \u003cbr\u003e George Wypych\u003cbr\u003e1.1 Historical developments \u003cbr\u003e1.2 Expectations from plasticizers \u003cbr\u003e1.3 Definitions \u003cbr\u003e1.4 Classification \u003cbr\u003e\u003cbr\u003e\u003cstrong\u003e2 PLASTICIZER TYPES\u003c\/strong\u003e \u003cbr\u003e George Wypych\u003cbr\u003e2.1 Introduction \u003cbr\u003e2.2 Characteristic properties of industrial plasticizers \u003cbr\u003e2.2.1 Abietates \u003cbr\u003e2.2.2 Adipates \u003cbr\u003e2.2.3 Alkyl sulfonates \u003cbr\u003e2.2.4 Amides and amines \u003cbr\u003e2.2.5 Azelates \u003cbr\u003e2.2.6 Benzoates \u003cbr\u003e2.2.7 Bioplasticizers \u003cbr\u003e2.2.8 Biodegradable plasticizers \u003cbr\u003e2.2.9 Chlorinated paraffins, \u003cbr\u003e2.2.10 Citrates \u003cbr\u003e2.2.11 Cyclohexane dicarboxylic acid, diisononyl ester \u003cbr\u003e2.2.12 Energetic plasticizers \u003cbr\u003e2.2.13 Epoxides \u003cbr\u003e2.2.14 Esters of C10-30 dicarboxylic acids \u003cbr\u003e2.2.15 Ether-ester plasticizers \u003cbr\u003e2.2.16 Glutarates \u003cbr\u003e2.2.17 Hydrocarbon oils \u003cbr\u003e2.2.18 Hydrocarbon resins \u003cbr\u003e2.2.19 Isobutyrates \u003cbr\u003e2.2.20 Maleates \u003cbr\u003e2.2.21 Oleates \u003cbr\u003e2.2.22 Pentaerythritol derivatives \u003cbr\u003e2.2.23 Phosphates \u003cbr\u003e2.2.24 Phthalate-free plasticizers \u003cbr\u003e2.2.25 Phthalates \u003cbr\u003e2.2.26 Polymeric plasticizers \u003cbr\u003e2.2.26.1 Esters \u003cbr\u003e2.2.26.2 Polybutenes \u003cbr\u003e2.26.3 Others \u003cbr\u003e2.2.27 Ricinoleates \u003cbr\u003e2.2.28 Sebacates \u003cbr\u003e2.2.29 Succinates \u003cbr\u003e2.2.30 Sulfonamides \u003cbr\u003e2.2.31 Superplasticizers and plasticizers for concrete \u003cbr\u003e2.2.32 Tri- and pyromellitates \u003cbr\u003e2.3 Methods of synthesis and their effect on properties of plasticizers \u003cbr\u003e2.4 Reactive plasticizers and internal plasticization \u003cbr\u003e\u003cbr\u003e\u003cstrong\u003e3 TYPICAL METHODS OF QUALITY CONTROL OF PLASTICIZERS\u003c\/strong\u003e \u003cbr\u003e George Wypych\u003cbr\u003e3.1 Abbreviations, terminology, and vocabulary \u003cbr\u003e3.2 Acid number \u003cbr\u003e3.3 Aging studies \u003cbr\u003e3.4 Ash \u003cbr\u003e3.5 Brittleness temperature \u003cbr\u003e3.6 Brookfield viscosity \u003cbr\u003e3.7 Chemical resistance \u003cbr\u003e3.8 Color \u003cbr\u003e3.9 Compatibility \u003cbr\u003e3.10 Compression set \u003cbr\u003e3.11 Concrete additives \u003cbr\u003e3.12 Electrical properties \u003cbr\u003e3.13 Extractable matter \u003cbr\u003e3.14 Flash and fire point \u003cbr\u003e3.15 Fogging \u003cbr\u003e3.16 Fusion \u003cbr\u003e3.17 Gas chromatography \u003cbr\u003e3.18 Hardness \u003cbr\u003e3.19 Infrared analysis of plasticizers \u003cbr\u003e3.20 Kinematic viscosity \u003cbr\u003e3.21 Marking (classification) \u003cbr\u003e3.22 Melt rheology \u003cbr\u003e3.23 Migration \u003cbr\u003e3.24 Polyvinylchloride standard specification \u003cbr\u003e3.25 Powder-mix time \u003cbr\u003e3.26 Purity \u003cbr\u003e3.27 Refractive index \u003cbr\u003e3.28 Residual contamination \u003cbr\u003e3.29 Sampling \u003cbr\u003e3.30 Saponification value \u003cbr\u003e3.31 Saybolt viscosity \u003cbr\u003e3.32 Sorption of plasticizer \u003cbr\u003e3.33 Specific gravity \u003cbr\u003e3.34 Specification \u003cbr\u003e3.35 Staining \u003cbr\u003e3.36 Stiffness \u003cbr\u003e3.37 Tensile properties \u003cbr\u003e3.38 Thermal expansion coefficient \u003cbr\u003e3.39 Unsaponifiable contents \u003cbr\u003e3.40 Viscosity of plastisols and organosols \u003cbr\u003e3.41 Water concentration \u003cbr\u003e3.42 Weight loss \u003cbr\u003e\u003cbr\u003e\u003cstrong\u003e4 TRANSPORTATION AND STORAGE\u003c\/strong\u003e \u003cbr\u003e George Wypych\u003cbr\u003e4.1 Transportation \u003cbr\u003e4.2 Storage \u003cbr\u003e\u003cbr\u003e\u003cstrong\u003e5 MECHANISMS OF PLASTICIZERS ACTION\u003c\/strong\u003e \u003cbr\u003e A. Marcilla and M. Beltrán\u003cbr\u003e5.1 Classical theories \u003cbr\u003e5.1.1 The lubricity theory \u003cbr\u003e5.1.2 The gel theory \u003cbr\u003e5.1.3 Moorshead's empirical approach \u003cbr\u003e5.2 The free volume theory \u003cbr\u003e5.2.1 Mathematical models \u003cbr\u003e\u003cbr\u003e\u003cstrong\u003e6 COMPATIBILITY OF PLASTICIZERS 159\u003c\/strong\u003e\u003cbr\u003e George Wypych\u003cbr\u003e6.1 Prediction methods of plasticizer compatibility \u003cbr\u003e6.1.1 Flory-Huggins interaction parameter \u003cbr\u003e6.1.2 Prediction of Gibbs free energy of mixing UNIFAC-FV \u003cbr\u003e6.1.3 Molar volume \u003cbr\u003e6.1.4 Polarity \u003cbr\u003e6.1.5 Hansen solubility parameters \u003cbr\u003e6.1.6 Hoy solubility parameters and other methods based on solubility\u003cbr\u003e parameters \u003cbr\u003e6.1.7 Hildebrand solubility parameter \u003cbr\u003e6.1.8 Molecule charge density using COSMO \u003cbr\u003e6.1.9 Mesoscale simulation using DPD \u003cbr\u003e6.1.10 Ap\/Po ratio \u003cbr\u003e6.2 Validation methods \u003cbr\u003e6.2.1 DSC analysis \u003cbr\u003e6.2.2 Inverse gas chromatography \u003cbr\u003e6.2.3 Solid-gel transition temperature \u003cbr\u003e6.3 Effect of plasticizer structure and conditions of incorporation on\u003cbr\u003e compatibility \u003cbr\u003e6.3.1 Effect of plasticizer structure \u003cbr\u003e6.3.1.1 Aromaticity \u003cbr\u003e6.3.1.2 Branching \u003cbr\u003e6.3.1.3 Chain length \u003cbr\u003e6.3.1.4 Molecular weight \u003cbr\u003e6.3.1.5 Polarity \u003cbr\u003e6.3.2 Conditions of incorporation \u003cbr\u003e6.3.2.1 Amount (concentration) \u003cbr\u003e6.3.2.2 Method of processing \u003cbr\u003e6.3.2.3 Temperature \u003cbr\u003e6.4 Effect of plasticizer type on properties of plasticized material \u003cbr\u003e6.4.1 Crystallinity \u003cbr\u003e6.4.2 Exudation \u003cbr\u003e6.4.3 Permanence \u003cbr\u003e6.4.4 Thermal degradation \u003cbr\u003e6.4.5 Volatility \u003cbr\u003e\u003cbr\u003e\u003cstrong\u003e7 PLASTICIZER MOTION AND DIFFUSION\u003c\/strong\u003e \u003cbr\u003e George Wypych\u003cbr\u003e7.1 Plasticizer diffusion rate and the methods of study \u003cbr\u003e7.2 Plasticizer motion and distribution in the matrix \u003cbr\u003e7.3 Plasticizer migration \u003cbr\u003e7.4 Antiplasticization \u003cbr\u003e7.5 Effect of diffusion and mobility of plasticizers on their suitability \u003cbr\u003e\u003cbr\u003e\u003cstrong\u003e8 EFFECT OF PLASTICIZERS ON OTHER COMPONENTS OF FORMULATION\u003c\/strong\u003e \u003cbr\u003e George Wypych\u003cbr\u003e8.1 Plasticizer consumption by fillers \u003cbr\u003e8.2 Solubility of additives in plasticizers \u003cbr\u003e8.3 Additive molecular mobility and transport in the presence of\u003cbr\u003e plasticizers \u003cbr\u003e8.4 Effect of plasticizers on polymerization and curing reactions \u003cbr\u003e\u003cbr\u003e\u003cstrong\u003e9 PLASTICIZATION STEPS\u003c\/strong\u003e \u003cbr\u003e A. Marcilla, J.C. García and M. Beltrán\u003cbr\u003e9.1 Plasticization steps \u003cbr\u003e9.2 Studies of plastisol's behavior during gelation and fusion \u003cbr\u003e9.2.1 Rheological characterization \u003cbr\u003e9.2.2 Studies by Scanning Electron Microscopy \u003cbr\u003e9.2.3 Study of polymer-plasticizer interactions by DSC \u003cbr\u003e9.2.4 Study of polymer-plasticizer interactions by SALS \u003cbr\u003e9.2.5 Study of polymer-plasticizer interactions by FTIR \u003cbr\u003e9.2.6 Study of polymer-plasticizer interactions by TG \u003cbr\u003e\u003cbr\u003e\u003cstrong\u003e10 EFFECT OF PLASTICIZERS ON PROPERTIES OF PLASTICIZED MATERIALS\u003c\/strong\u003e\u003cbr\u003e George Wypych\u003cbr\u003e10.1 Mechanical properties \u003cbr\u003e10.1.1 Tensile strength \u003cbr\u003e10.1.2 Elongation \u003cbr\u003e10.1.3 Hardness \u003cbr\u003e10.1.4 Toughness, stiffness, ductility, modulus \u003cbr\u003e10.1.5 Other mechanical properties \u003cbr\u003e10.2 Optical properties \u003cbr\u003e10.3 Spectral properties \u003cbr\u003e10.4 Gloss \u003cbr\u003e10.5 Sound \u003cbr\u003e10.6 Rheological properties \u003cbr\u003e10.7 Magnetorheological properties \u003cbr\u003e10.8 Electrical properties \u003cbr\u003e10.9 Glass transition temperature \u003cbr\u003e10.10 Flammability and smoke formation in the presence of plasticizers \u003cbr\u003e10.11 Thermal degradation \u003cbr\u003e10.11.1 Thermal degradation of plasticizers \u003cbr\u003e10.11.2 Effect of polymer degradation products on plasticizers \u003cbr\u003e10.11.3 Effect of plasticizer degradation products on polymer degradation \u003cbr\u003e10.11.4 Loss of plasticizer from the material due to chemical decomposition\u003cbr\u003e reactions and evaporation \u003cbr\u003e10.11.5 Effect of plasticizers on the thermal degradation of materials \u003cbr\u003e10.12 Effect of UV and ionizing radiation on plasticized materials \u003cbr\u003e10.13 Hydrolysis \u003cbr\u003e10.14 Biodegradation in the presence of plasticizers \u003cbr\u003e10.15 Crystallization, structure, and orientation of macromolecules \u003cbr\u003e10.16 Morphology \u003cbr\u003e10.17 Plasticizer effect on contact with other materials \u003cbr\u003e10.18 Influence of plasticizers on swelling \u003cbr\u003e10.19 Fogging \u003cbr\u003e10.20 Hydrophobic\/hydrophilic properties \u003cbr\u003e10.21 Osmotic pressure of plasticizer in polymer \u003cbr\u003e10.22 Self-healing \u003cbr\u003e10.23 Shrinkage \u003cbr\u003e10.24 Soiling \u003cbr\u003e10.25 Free volume \u003cbr\u003e10.26 Dissolution \u003cbr\u003e10.27 Foaming \u003cbr\u003e10.28 Permeability \u003cbr\u003e10.29 Sorption \u003cbr\u003e\u003cbr\u003e\u003cstrong\u003e11 PLASTICIZERS USE AND SELECTION FOR SPECIFIC POLYMERS\u003c\/strong\u003e \u003cbr\u003e George Wypych\u003cbr\u003e11.1 ABS \u003cbr\u003e11.1.1 Frequently used plasticizers \u003cbr\u003e11.1.2 Practical concentrations \u003cbr\u003e11.1.3 Main functions performed by plasticizers \u003cbr\u003e11.1.4 Mechanism of plasticizer action \u003cbr\u003e11.1.5 Effect of plasticizers on polymer and other additives \u003cbr\u003e11.1.6 Typical formulations \u003cbr\u003e11.2 Acrylics \u003cbr\u003e11.2.1 Frequently used plasticizers \u003cbr\u003e11.2.2 Practical concentrations \u003cbr\u003e11.2.3 Main functions performed by plasticizers \u003cbr\u003e11.2.4 Mechanism of plasticizer action \u003cbr\u003e11.2.5 Typical formulations \u003cbr\u003e11.3 Bromobutyl rubber \u003cbr\u003e11.3.1 Frequently used plasticizers \u003cbr\u003e11.3.2 Practical concentrations \u003cbr\u003e11.3.3 Main functions performed by plasticizers \u003cbr\u003e11.3.4 Effect of plasticizers on polymer and other additives \u003cbr\u003e11.4 Butyl terpolymer \u003cbr\u003e11.4.1 Frequently used plasticizers \u003cbr\u003e11.4.2 Practical concentrations \u003cbr\u003e11.5 Cellulose acetate \u003cbr\u003e11.5.1 Frequently used plasticizers \u003cbr\u003e11.5.2 Practical concentrations \u003cbr\u003e11.5.3 Main functions performed by plasticizers \u003cbr\u003e11.5.4 Mechanism of plasticizer action \u003cbr\u003e11.5.5 Effect of plasticizers on polymer and other additives \u003cbr\u003e11.6 Cellulose butyrate and propionate \u003cbr\u003e11.6.1 Frequently used plasticizers \u003cbr\u003e11.6.2 Practical concentrations \u003cbr\u003e11.6.3 Main functions performed by plasticizers \u003cbr\u003e11.6.4 Effect of plasticizers on polymer and other additives \u003cbr\u003e11.7 Cellulose nitrate \u003cbr\u003e11.7.1 Frequently used plasticizers \u003cbr\u003e11.7.2 Practical concentrations \u003cbr\u003e11.7.3 Main functions performed by plasticizers \u003cbr\u003e11.7.4 Effect of plasticizers on polymer and other additives \u003cbr\u003e11.7.5 Typical formulations \u003cbr\u003e11.8 Chitosan \u003cbr\u003e11.8.1 Frequently used plasticizers \u003cbr\u003e11.8.2 Practical concentrations \u003cbr\u003e11.8.3 Main functions performed by plasticizers \u003cbr\u003e11.8.4 Effect of plasticizers on polymer and other additives \u003cbr\u003e11.9 Chlorinated polyvinylchloride \u003cbr\u003e11.9.1 Frequently used plasticizers \u003cbr\u003e11.9.2 Effect of plasticizers on polymer and other additives \u003cbr\u003e11.10 Chlorosulfonated polyethylene \u003cbr\u003e11.10.1 Frequently used plasticizers \u003cbr\u003e11.10.2 Effect of plasticizers on polymer and other additives \u003cbr\u003e11.11 Copolymers \u003cbr\u003e11.11.1 Frequently used plasticizers \u003cbr\u003e11.11.2 Practical concentrations \u003cbr\u003e11.11.3 Main functions performed by plasticizers \u003cbr\u003e11.11.4 Mechanism of plasticizer action \u003cbr\u003e11.12 Cyanoacrylates \u003cbr\u003e11.12.1 Frequently used plasticizers \u003cbr\u003e11.12.2 Practical concentrations \u003cbr\u003e11.12.3 Main functions performed by plasticizers \u003cbr\u003e11.12.4 Effect of plasticizer on polymer and other additives \u003cbr\u003e11.13 Ethylcellulose \u003cbr\u003e11.13.1 Frequently used plasticizers \u003cbr\u003e11.13.2 Practical concentrations \u003cbr\u003e11.13.3 Effect of plasticizers on polymer and other additives \u003cbr\u003e11.14 Epoxy resin \u003cbr\u003e11.14.1 Frequently used plasticizers \u003cbr\u003e11.14.2 Practical concentrations \u003cbr\u003e11.14.3 Main functions performed by plasticizers \u003cbr\u003e11.14.4 Effect of plasticizers on polymer and other additives \u003cbr\u003e11.15 Ethylene-propylene-diene copolymer \u003cbr\u003e11.15.1 Frequently used plasticizers \u003cbr\u003e11.15.2 Practical concentrations \u003cbr\u003e11.15.3 Main functions performed by plasticizers \u003cbr\u003e11.15.4 Effect of plasticizers on polymer and other additives \u003cbr\u003e11.15.5 Typical formulations \u003cbr\u003e11.16 Ethylene-vinyl acetate copolymer \u003cbr\u003e11.17 Ionomers \u003cbr\u003e11.17.1 Frequently used plasticizers \u003cbr\u003e11.17.2 Practical concentrations \u003cbr\u003e11.17.3 Main functions performed by plasticizers \u003cbr\u003e11.17.4 Mechanism of plasticizer action \u003cbr\u003e11.17.5 Effect of plasticizers on polymer and other additives \u003cbr\u003e11.18 Nitrile rubber \u003cbr\u003e11.18.1 Frequently used plasticizers \u003cbr\u003e11.18.2 Practical concentrations \u003cbr\u003e11.18.3 Main functions performed by plasticizers \u003cbr\u003e11.18.4 Effect of plasticizers on polymer and other additives \u003cbr\u003e11.18.5 Typical formulations \u003cbr\u003e11.19 Perfluoropolymers \u003cbr\u003e11.20 Polyacrylonitrile \u003cbr\u003e11.20.1 Frequently used plasticizers \u003cbr\u003e11.20.2 Practical concentrations \u003cbr\u003e11.20.3 Main functions performed by plasticizers \u003cbr\u003e11.20.4 Effect of plasticizers on polymer and other additives \u003cbr\u003e11.21 Polyamide \u003cbr\u003e11.21.1 Frequently used plasticizers \u003cbr\u003e11.21.2 Practical concentrations \u003cbr\u003e11.21.3 Main functions performed by plasticizers \u003cbr\u003e11.21.4 Effect of plasticizers on polymer and other additives \u003cbr\u003e11.22 Polyamine \u003cbr\u003e11.23 Polyaniline \u003cbr\u003e11.24 Polybutadiene \u003cbr\u003e11.24.1 Frequently used plasticizers \u003cbr\u003e11.24.2 Practical concentrations \u003cbr\u003e11.24.3 Main functions performed by plasticizers \u003cbr\u003e11.25 Polybutylene \u003cbr\u003e11.25.1 Frequently used plasticizers \u003cbr\u003e11.25.2 Practical concentrations \u003cbr\u003e11.25.3 Main functions performed by plasticizers \u003cbr\u003e11.26 Poly(butyl methacrylate) \u003cbr\u003e11.26.1 Frequently used plasticizers \u003cbr\u003e11.26.2 Practical concentrations \u003cbr\u003e11.26.3 Main functions performed by plasticizers \u003cbr\u003e11.27 Polycarbonate \u003cbr\u003e11.27.1 Frequently used plasticizers \u003cbr\u003e11.27.2 Practical concentrations \u003cbr\u003e11.27.3 Main functions performed by plasticizers \u003cbr\u003e11.27.4 Effect of plasticizers on polymer and other additives \u003cbr\u003e11.28 Polyester \u003cbr\u003e11.28.1 Frequently used plasticizers \u003cbr\u003e11.28.2 Practical concentrations \u003cbr\u003e11.28.3 Main functions performed by plasticizers \u003cbr\u003e11.28.4 Effect of plasticizers on polymer and other additives \u003cbr\u003e11.28.5 Typical formulations \u003cbr\u003e11.29 Polyetherimide \u003cbr\u003e11.30 Polyethylacrylate \u003cbr\u003e11.31 Polyethylene \u003cbr\u003e11.31.1 Frequently used plasticizers \u003cbr\u003e11.31.2 Practical concentrations \u003cbr\u003e11.31.3 Main functions performed by plasticizers \u003cbr\u003e11.31.4 Mechanism of plasticizer action \u003cbr\u003e11.31.5 Typical formulations \u003cbr\u003e11.32 Poly(ethylene oxide) \u003cbr\u003e11.32.1 Frequently used plasticizers \u003cbr\u003e11.32.2 Practical concentrations \u003cbr\u003e11.32.3 Main functions performed by plasticizers \u003cbr\u003e11.32.4 Effect of plasticizers on polymer and other additives \u003cbr\u003e11.33 Poly(3-hydroxybutyrate) \u003cbr\u003e11.33.1 Frequently used plasticizers \u003cbr\u003e11.33.2 Practical concentrations \u003cbr\u003e11.33.3 Main functions performed by plasticizers \u003cbr\u003e11.34 Polyisobutylene \u003cbr\u003e11.35 Polyisoprene \u003cbr\u003e11.35.1 Frequently used plasticizers \u003cbr\u003e11.35.2 Practical concentrations \u003cbr\u003e11.35.3 Main functions performed by plasticizers \u003cbr\u003e11.35.4 Typical formulations \u003cbr\u003e11.36 Polyimide \u003cbr\u003e11.36.1 Frequently used plasticizers \u003cbr\u003e11.36.2 Practical concentrations \u003cbr\u003e11.36.3 Main functions performed by plasticizers \u003cbr\u003e11.36.4 Effect of plasticizers on polymer and other additives \u003cbr\u003e11.37 Polylactide \u003cbr\u003e11.37.1 Frequently used plasticizers \u003cbr\u003e11.37.2 Practical concentrations \u003cbr\u003e11.37.3 Main functions performed by plasticizers \u003cbr\u003e11.37.4 Effect of plasticizers on polymer and other additives \u003cbr\u003e11.38 Polymethylmethacrylate \u003cbr\u003e11.38.1 Frequently used plasticizers \u003cbr\u003e11.38.2 Practical concentrations \u003cbr\u003e11.38.3 Main functions performed by plasticizers \u003cbr\u003e11.38.4 Mechanism of plasticizer action \u003cbr\u003e11.38.5 Typical formulations \u003cbr\u003e11.39 Polypropylene \u003cbr\u003e11.39.1 Frequently used plasticizers \u003cbr\u003e11.39.2 Practical concentrations \u003cbr\u003e11.39.3 Main functions performed by plasticizers \u003cbr\u003e11.39.4 Effect of plasticizers on polymer and other additives \u003cbr\u003e11.40 Poly(propylene carbonate) \u003cbr\u003e11.40.1 Frequently used plasticizers \u003cbr\u003e11.40.2 Practical concentrations \u003cbr\u003e11.40.3 Main functions performed by plasticizers \u003cbr\u003e11.40.4 Effect of plasticizers on polymer and other additives \u003cbr\u003e11.41 Poly(N-vinylcarbazole) \u003cbr\u003e11.42 Poly(N-vinylpyrrolidone) \u003cbr\u003e11.42.1 Frequently used plasticizers \u003cbr\u003e11.42.2 Practical concentrations \u003cbr\u003e11.42.3 Main functions performed by plasticizers \u003cbr\u003e11.42.4 Mechanism of plasticizer action \u003cbr\u003e11.42.5 Typical formulations \u003cbr\u003e11.43 Poly(phenylene ether) \u003cbr\u003e11.43.1 Frequently used plasticizers \u003cbr\u003e11.43.2 Practical concentrations \u003cbr\u003e11.43.3 Main functions performed by plasticizers \u003cbr\u003e11.44 Poly(phenylene sulfide) \u003cbr\u003e11.45 Polystyrene \u003cbr\u003e11.45.1 Frequently used plasticizers \u003cbr\u003e11.45.2 Practical concentrations \u003cbr\u003e11.45.3 Main functions performed by plasticizers \u003cbr\u003e11.46 Polysulfide \u003cbr\u003e11.46.1 Frequently used plasticizers \u003cbr\u003e11.46.2 Practical concentrations \u003cbr\u003e11.46.3 Main functions performed by plasticizers \u003cbr\u003e11.47 Polysulfone \u003cbr\u003e11.48 Polyurethanes \u003cbr\u003e11.48.1 Frequently used plasticizers \u003cbr\u003e11.48.2 Practical concentrations \u003cbr\u003e11.48.3 Main functions performed by plasticizers \u003cbr\u003e11.48.4 Mechanism of plasticizers action \u003cbr\u003e11.48.5 Effect of plasticizers on polymers and other additives \u003cbr\u003e11.48.6 Typical formulations \u003cbr\u003e11.49 Polyvinylacetate \u003cbr\u003e11.49.1 Frequently used plasticizers \u003cbr\u003e11.49.2 Practical concentrations \u003cbr\u003e11.49.3 Main functions performed by plasticizers \u003cbr\u003e11.49.4 Effect of plasticizers on polymer and other additives \u003cbr\u003e11.50 Polyvinylalcohol \u003cbr\u003e11.50.1 Frequently used plasticizers \u003cbr\u003e11.50.2 Practical concentrations \u003cbr\u003e11.50.3 Main functions performed by plasticizers \u003cbr\u003e11.50.4 Mechanism of plasticizer action \u003cbr\u003e11.50.5 Effect of plasticizers on polymer and other additives \u003cbr\u003e11.50.6 Typical formulations \u003cbr\u003e11.51 Polyvinylbutyral \u003cbr\u003e11.51.1 Frequently used plasticizers \u003cbr\u003e11.51.2 Practical concentrations \u003cbr\u003e11.51.3 Main functions performed by plasticizers \u003cbr\u003e11.51.4 Effect of plasticizers on polymer and other additives \u003cbr\u003e11.52 Polyvinylchloride \u003cbr\u003e11.52.1 Frequently used plasticizers \u003cbr\u003e11.52.2 Practical concentrations \u003cbr\u003e11.52.3 Main functions performed by plasticizers \u003cbr\u003e11.52.4 Mechanism of plasticizer action \u003cbr\u003e11.52.5 Effect of plasticizers on polymer and other additives \u003cbr\u003e11.52.6 Typical formulations \u003cbr\u003e11.53 Polyvinylfluoride \u003cbr\u003e11.54 Polyvinylidenefluoride \u003cbr\u003e11.54.1 Frequently used plasticizers \u003cbr\u003e11.54.2 Practical concentrations \u003cbr\u003e11.54.3 Main functions performed by plasticizers \u003cbr\u003e11.54.4 Effect of plasticizers on polymer and other additives \u003cbr\u003e11.55 Polyvinylidenechloride \u003cbr\u003e11.56 Proteins \u003cbr\u003e11.56.1 Frequently used plasticizers \u003cbr\u003e11.56.2 Practical concentrations \u003cbr\u003e11.56.3 Main functions performed by plasticizers \u003cbr\u003e11.56.4 Mechanism of plasticizer action \u003cbr\u003e11.56.5 Effect of plasticizers on polymer and other additives \u003cbr\u003e11.57 Rubber, natural \u003cbr\u003e11.57.1 Frequently used plasticizers \u003cbr\u003e11.57.2 Practical concentrations \u003cbr\u003e11.57.3 Main functions performed by plasticizers \u003cbr\u003e11.57.4 Effect of plasticizers on polymer and other additives \u003cbr\u003e11.57.5 Typical formulations \u003cbr\u003e11.58 Silicone \u003cbr\u003e11.58.1 Frequently used plasticizers \u003cbr\u003e11.58.2 Practical concentrations \u003cbr\u003e11.58.3 Main functions performed by plasticizers \u003cbr\u003e11.58.4 Effect of plasticizers on polymer and other additives \u003cbr\u003e11.58.5 Typical formulations \u003cbr\u003e11.59 Styrene-butadiene rubber \u003cbr\u003e11.59.1 Frequently used plasticizers \u003cbr\u003e11.59.2 Practical concentrations \u003cbr\u003e11.59.3 Effect of plasticizers on polymer and other additives \u003cbr\u003e11.59.4 Typical formulations \u003cbr\u003e11.60 Styrene-butadiene-styrene rubber \u003cbr\u003e11.60.1 Frequently used plasticizers \u003cbr\u003e11.60.2 Practical concentrations \u003cbr\u003e11.60.3 Main functions performed by plasticizers \u003cbr\u003e11.60.4 Effect of plasticizer on polymer and other additives \u003cbr\u003e11.61 Starch \u003cbr\u003e11.61.1 Frequently used plasticizers \u003cbr\u003e11.61.2 Practical concentrations \u003cbr\u003e11.61.3 Main functions performed by plasticizers \u003cbr\u003e11.61.4 Effect of plasticizers on polymer and other additives \u003cbr\u003e11.61.5 Typical formulations\u003cbr\u003e \u003cbr\u003e\u003cstrong\u003e12 PLASTICIZERS IN POLYMER BLENDS\u003c\/strong\u003e \u003cbr\u003e George Wypych\u003cbr\u003e12.1 Plasticizer partition between component polymers \u003cbr\u003e12.2 Interaction of plasticizers with blend components \u003cbr\u003e12.3 Effect of plasticizers on blend properties \u003cbr\u003e12.4 Blending to reduce or to replace plasticizers \u003cbr\u003e\u003cbr\u003e\u003cbr\u003e\u003cstrong\u003e13 PLASTICIZERS IN VARIOUS INDUSTRIAL PRODUCTS\u003c\/strong\u003e \u003cbr\u003e George Wypych\u003cbr\u003e13.1 Adhesives and sealants \u003cbr\u003e13.1.1 Plasticizer types \u003cbr\u003e13.1.2 Plasticizer concentration \u003cbr\u003e13.1.3 Reasons for plasticizer use \u003cbr\u003e13.1.4 Advantages and disadvantages of plasticizers use \u003cbr\u003e13.1.5 Effect of plasticizers on product properties \u003cbr\u003e13.1.6 Examples of formulations \u003cbr\u003e13.2 Aerospace \u003cbr\u003e13.3 Agriculture \u003cbr\u003e13.4 Automotive \u003cbr\u003e13.4.1 Plasticizer types \u003cbr\u003e13.4.2 Plasticizer concentration \u003cbr\u003e13.4.3 Reasons for plasticizer use \u003cbr\u003e13.4.4 Advantages and disadvantages of plasticizers use \u003cbr\u003e13.4.5 Effect of plasticizers on product properties \u003cbr\u003e13.5 Cementitious materials \u003cbr\u003e13.5.1 Plasticizer types \u003cbr\u003e13.5.2 Plasticizer concentration \u003cbr\u003e13.5.3 Reasons for plasticizer use \u003cbr\u003e13.5.4 Advantages and disadvantages of plasticizers use \u003cbr\u003e13.5.5 Effect of plasticizers on product properties \u003cbr\u003e13.5.6 Examples of formulations \u003cbr\u003e13.6 Coated fabrics \u003cbr\u003e13.6.1 Plasticizer types \u003cbr\u003e13.6.2 Plasticizer concentration \u003cbr\u003e13.6.3 Reasons for plasticizer use \u003cbr\u003e13.6.4 Advantages and disadvantages of plasticizers use \u003cbr\u003e13.6.5 Effect of plasticizers on product properties \u003cbr\u003e13.6.6 Examples of formulations \u003cbr\u003e13.7 Composites \u003cbr\u003e13.7.1 Plasticizer types \u003cbr\u003e13.7.2 Plasticizer concentrations \u003cbr\u003e13.7.3 Reasons for addition \u003cbr\u003e13.7.4 Effect of plasticizers on product properties \u003cbr\u003e13.8 Cosmetics \u003cbr\u003e13.8.1 Plasticizer types \u003cbr\u003e13.8.2 Plasticizer concentration \u003cbr\u003e13.8.3 Reasons for plasticizer use \u003cbr\u003e13.8.4 Advantages and disadvantages of plasticizers use \u003cbr\u003e13.8.5 Effect of plasticizers on product properties \u003cbr\u003e13.8.6 Examples of formulations \u003cbr\u003e13.9 Cultural heritage \u003cbr\u003e13.10 Dental materials \u003cbr\u003e13.10.1 Plasticizer types \u003cbr\u003e13.10.2 Plasticizer concentration \u003cbr\u003e13.10.3 Reasons for plasticizer use \u003cbr\u003e13.10.4 Advantages and disadvantages of plasticizers use \u003cbr\u003e13.11 Electrical and electronics \u003cbr\u003e13.11.1 Plasticizer types \u003cbr\u003e13.11.2 Plasticizer concentration \u003cbr\u003e13.11.3 Reasons for plasticizer use \u003cbr\u003e13.11.4 Advantages and disadvantages of plasticizers use \u003cbr\u003e13.11.5 Effect of plasticizers on product properties \u003cbr\u003e13.12 Fibers \u003cbr\u003e13.12.1 Plasticizer types \u003cbr\u003e13.12.2 Plasticizer concentration \u003cbr\u003e13.12.3 Reasons for plasticizer use \u003cbr\u003e13.12.4 Effect of plasticizers on product properties \u003cbr\u003e13.13 Film \u003cbr\u003e13.13.1 Plasticizer types \u003cbr\u003e13.13.2 Plasticizer concentration \u003cbr\u003e13.13.3 Reasons for plasticizer use \u003cbr\u003e13.13.4 Advantages and disadvantages of plasticizers use \u003cbr\u003e13.13.5 Effect of plasticizers on product properties \u003cbr\u003e13.14 Food \u003cbr\u003e13.14.1 Plasticizer types \u003cbr\u003e13.14.2 Plasticizer concentration \u003cbr\u003e13.14.3 Reasons for plasticizer use \u003cbr\u003e13.14.4 Advantages and disadvantages of plasticizers use \u003cbr\u003e13.14.5 Effect of plasticizers on product properties \u003cbr\u003e13.15 Flooring \u003cbr\u003e13.15.1 Plasticizer types \u003cbr\u003e13.15.2 Plasticizer concentration \u003cbr\u003e13.15.3 Reasons for plasticizer use \u003cbr\u003e13.15.4 Advantages and disadvantages of plasticizers use \u003cbr\u003e13.15.5 Effect of plasticizers on product properties \u003cbr\u003e13.15.6 Examples of formulations \u003cbr\u003e13.16 Foams \u003cbr\u003e13.16.1 Plasticizer types \u003cbr\u003e13.16.2 Plasticizer concentration \u003cbr\u003e13.16.3 Reasons for plasticizer use \u003cbr\u003e13.16.4 Advantages and disadvantages of plasticizers use \u003cbr\u003e13.16.5 Effect of plasticizers on product properties \u003cbr\u003e13.16.6 Examples of formulations \u003cbr\u003e13.17 Footwear \u003cbr\u003e13.17.1 Plasticizer types \u003cbr\u003e13.17.2 Plasticizer concentration \u003cbr\u003e13.17.3 Reasons for plasticizer use \u003cbr\u003e13.17.4 Advantages and disadvantages of plasticizers use \u003cbr\u003e13.17.5 Example of formulation \u003cbr\u003e13.18 Fuel cells \u003cbr\u003e13.18.1 Plasticizer types \u003cbr\u003e13.18.2 Plasticizer concentration \u003cbr\u003e13.18.3 Reasons for plasticizer use \u003cbr\u003e13.19 Gaskets \u003cbr\u003e13.19.1 Plasticizer types \u003cbr\u003e13.19.2 Plasticizer concentration \u003cbr\u003e13.19.3 Reasons for plasticizer use \u003cbr\u003e13.19.4 Advantages and disadvantages of plasticizers use \u003cbr\u003e13.19.5 Examples of formulations \u003cbr\u003e13.20 Household products \u003cbr\u003e13.21 Inks, varnishes, and lacquers \u003cbr\u003e13.21.1 Plasticizer types \u003cbr\u003e13.21.2 Plasticizer concentration \u003cbr\u003e13.21.3 Reasons for plasticizer use \u003cbr\u003e13.21.4 Advantages and disadvantages of plasticizers use \u003cbr\u003e13.21.5 Effect of plasticizers on product properties \u003cbr\u003e13.21.6 Examples of formulations \u003cbr\u003e13.22 Medical applications \u003cbr\u003e13.22.1 Plasticizer types \u003cbr\u003e13.22.2 Plasticizer concentration \u003cbr\u003e13.22.3 Reasons for plasticizer use \u003cbr\u003e13.22.4 Advantages and disadvantages of plasticizers use \u003cbr\u003e13.22.5 Effect of plasticizers on product properties \u003cbr\u003e13.22.6 Examples of formulations \u003cbr\u003e13.23 Membranes \u003cbr\u003e13.23.1 Plasticizer types \u003cbr\u003e13.23.2 Plasticizer concentration \u003cbr\u003e13.23.3 Reasons for plasticizer use \u003cbr\u003e13.23.4 Advantages and disadvantages of plasticizers use \u003cbr\u003e13.24 Microspheres \u003cbr\u003e13.24.1 Plasticizer types \u003cbr\u003e13.24.2 Plasticizer concentration \u003cbr\u003e13.24.3 Reasons for plasticizer use \u003cbr\u003e13.25 Paints and coatings \u003cbr\u003e13.25.1 Plasticizer types \u003cbr\u003e13.25.2 Plasticizer concentration \u003cbr\u003e13.25.3 Reasons for plasticizer use \u003cbr\u003e13.25.4 Advantages and disadvantages of plasticizers use \u003cbr\u003e13.25.5 Effect of plasticizers on product properties \u003cbr\u003e13.25.6 Examples of formulations \u003cbr\u003e13.26 Pharmaceutical products \u003cbr\u003e13.26.1 Plasticizer types \u003cbr\u003e13.26.2 Plasticizer concentration \u003cbr\u003e13.26.3 Reasons for plasticizer use \u003cbr\u003e13.26.4 Advantages and disadvantages of plasticizers use \u003cbr\u003e13.26.5 Effect of plasticizers on product properties \u003cbr\u003e13.26.6 Examples of formulations \u003cbr\u003e13.27 Photographic materials \u003cbr\u003e13.27.1 Plasticizer types \u003cbr\u003e13.27.2 Plasticizer concentration \u003cbr\u003e13.27.3 Reasons for plasticizer use \u003cbr\u003e13.27.4 Effect of plasticizers on product properties \u003cbr\u003e13.28 Pipes \u003cbr\u003e13.28.1 Plasticizer types \u003cbr\u003e13.28.2 Plasticizer concentration \u003cbr\u003e13.28.3 Reasons for plasticizer use \u003cbr\u003e13.28.4 Advantages and disadvantages of plasticizers use \u003cbr\u003e13.28.5 Effect of plasticizers on product properties \u003cbr\u003e13.28.6 Examples of formulations \u003cbr\u003e13.29 Roofing materials \u003cbr\u003e13.29.1 Plasticizer types \u003cbr\u003e13.29.2 Plasticizer concentration \u003cbr\u003e13.29.3 Reasons for plasticizer use \u003cbr\u003e13.29.4 Advantages and disadvantages of plasticizers use \u003cbr\u003e13.29.5 Effect of plasticizers on product properties \u003cbr\u003e13.29.6 Examples of formulations \u003cbr\u003e13.30 Tires \u003cbr\u003e13.30.1 Plasticizer types \u003cbr\u003e13.30.2 Plasticizer concentration \u003cbr\u003e13.30.3 Reasons for plasticizer use \u003cbr\u003e13.30.4 Advantages and disadvantages of plasticizers use \u003cbr\u003e13.30.5 Effect of plasticizers on product properties \u003cbr\u003e13.30.6 Examples of formulations \u003cbr\u003e13.31 Toys \u003cbr\u003e13.31.1 Plasticizer types \u003cbr\u003e13.31.2 Plasticizer concentration \u003cbr\u003e13.31.3 Reasons for plasticizer use \u003cbr\u003e13.31.4 Effect of plasticizers on product properties \u003cbr\u003e13.32 Tubing \u003cbr\u003e13.32.1 Plasticizer types \u003cbr\u003e13.32.2 Plasticizer concentration \u003cbr\u003e13.32.3 Reasons for plasticizer use \u003cbr\u003e13.32.4 Advantages and disadvantages of plasticizers use \u003cbr\u003e13.32.5 Effect of plasticizers on product properties \u003cbr\u003e13.32.6 Examples of formulations \u003cbr\u003e13.33 Wire and cable \u003cbr\u003e13.33.1 Plasticizer types \u003cbr\u003e13.33.2 Plasticizer concentration \u003cbr\u003e13.33.3 Reasons for plasticizer use \u003cbr\u003e13.33.4 Advantages and disadvantages of plasticizers use \u003cbr\u003e13.33.5 Effect of plasticizers on product properties \u003cbr\u003e13.33.6 Examples of formulations \u003cbr\u003e\u003cbr\u003e\u003cstrong\u003e14 PLASTICIZERS IN VARIOUS PROCESSING METHODS\u003c\/strong\u003e \u003cbr\u003e George Wypych\u003cbr\u003e14.1 Blow molding \u003cbr\u003e14.2 Calendering \u003cbr\u003e14.3 Coil coating \u003cbr\u003e14.4 Compression molding \u003cbr\u003e14.5 Compounding (mixing) \u003cbr\u003e14.6 Dip coating \u003cbr\u003e14.7 Dry blending \u003cbr\u003e14.8 Extrusion \u003cbr\u003e14.9 Injection molding \u003cbr\u003e14.10 Polymer synthesis \u003cbr\u003e14.11 Rotational molding \u003cbr\u003e14.12 Rubber processing \u003cbr\u003e14.13 Thermoforming \u003cbr\u003e14.14 Web coating \u003cbr\u003e14.15 Wire coating \u003cbr\u003e\u003cbr\u003e\u003cstrong\u003e15 SPECIALIZED ANALYTICAL METHODS IN PLASTICIZER TESTING\u003c\/strong\u003e \u003cbr\u003e George Wypych\u003cbr\u003e15.1 Plasticizer identification \u003cbr\u003e15.2 Methods of determination of plasticizer concentration \u003cbr\u003e15.3 Determination of volatility, molecular motion, diffusion, and migration \u003cbr\u003e15.4 Methods of study of plasticized materials \u003cbr\u003e\u003cbr\u003e\u003cstrong\u003e16 MATHEMATICAL MODELING IN APPLICATION TO PLASTICIZERS\u003c\/strong\u003e \u003cbr\u003e George Wypych\u003cbr\u003e16.1 PVC-plasticizer interaction model \u003cbr\u003e16.2 Gas permeation \u003cbr\u003e16.3 Migration \u003cbr\u003e16.4 Dry-blending time \u003cbr\u003e16.5 Gelation and fusion \u003cbr\u003e16.6 Thermal decomposition \u003cbr\u003e16.7 Potential health risk of exposure to DEHP from glove \u003cbr\u003e\u003cbr\u003e\u003cstrong\u003e17 HEALTH AND SAFETY ISSUES WITH PLASTICIZERS AND PLASTICIZED\u003c\/strong\u003e\u003cbr\u003e\u003cstrong\u003e MATERIALS\u003c\/strong\u003e \u003cbr\u003e17.1 Adjuvant effect of plasticizers \u003cbr\u003e Søren Thor Larsen \u003cbr\u003e17.1.1 Introduction \u003cbr\u003e17.1.2 Airway allergy \u003cbr\u003e17.1.3 Adjuvant effect \u003cbr\u003e17.1.4 Adjuvant effect of phthalate plasticizers \u003cbr\u003e 17.1.4.1 Epidemiological studies \u003cbr\u003e17.1.4.2 In vivo (animal) studies \u003cbr\u003e17.1.5 Conclusions \u003cbr\u003e17.2 The rodent hepatocarcinogenic response to phthalate plasticizers\u003cbr\u003e : basic biology and human extrapolation \u003cbr\u003e Abigail L Walker and Ruth A Roberts\u003cbr\u003e17.2.1 Introduction \u003cbr\u003e17.2.2 Gene expression and cancer toxicology \u003cbr\u003e17.2.2.1 Gene expression \u003cbr\u003e17.2.2.2 Cancer biology: some basic considerations \u003cbr\u003e17.2.2.3 Developing areas of interest in hepatocarcinogenesis \u003cbr\u003e17.2.2.4 Chemical carcinogenesis \u003cbr\u003e17.2.3 Peroxisome proliferators and rodent nongenotoxic\u003cbr\u003e hepatocarcinogenesis \u003cbr\u003e17.2.3.1 The peroxisome proliferators \u003cbr\u003e17.2.3.2 PPAR \u003cbr\u003e17.2.4 Species differences in response to peroxisome proliferators \u003cbr\u003e17.2.5 Chemical regulation \u003cbr\u003e17.2.5.1 Challenges in alternative models \u003cbr\u003e17.2.6 Summary \u003cbr\u003e17.3 The influence of maternal nutrition on phthalate teratogenicity \u003cbr\u003e Janet Y. Uriu-Adams1 and Carl L. Keen\u003cbr\u003e17.3.1 Introduction \u003cbr\u003e17.3.2 Reproductive toxicity of BBP and DEHP \u003cbr\u003e17.3.3 Acute phase response-induced alterations in maternal \u003cbr\u003e17.3.4 Concluding comments \u003cbr\u003e17.3.5 Recent findings \u003cbr\u003e17.3.6 Acknowledgments \u003cbr\u003e17.4 Public health implications of phthalates: A review of U.S. actions\u003cbr\u003e to protect those most vulnerable \u003cbr\u003e Stephanie R. Miles-Richardson and Dhara Richardson\u003cbr\u003e17.4.1 Introduction \u003cbr\u003e17.4.2 Implications of the COVID-19 pandemic on phthalate exposure \u003cbr\u003e17.4.3 The U.S. response to phthalate exposure \u003cbr\u003e17.4.3 Some U.S. State-level actions \u003cbr\u003e17.4.4 2008 Consumer Product Safety Improvement Act \u003cbr\u003e17.4.5 Food and Drug Administration (FDA) petition, lawsuit, and final ruling \u003cbr\u003e17.4.6 Preventing Harmful Exposure to Phthalates Act 117th Congress\u003cbr\u003e (2021-2022) \u003cbr\u003e17.4.7 Other U.S. Federal Agencies \u003cbr\u003e17.4.8 Conclusion \u003cbr\u003e17.5 Plasticizers in the indoor environment \u003cbr\u003e Werner Butte\u003cbr\u003e17.5.1 Introduction \u003cbr\u003e17.5.2 Sources of indoor plasticizers \u003cbr\u003e17.5.3 Occurrence of plasticizers indoors \u003cbr\u003e17.5.3.1 Indoor air \u003cbr\u003e17.5.3.2 House dust \u003cbr\u003e17.5.4 Impact of plasticizers in the indoor environment \u003cbr\u003e17.5.4.1 Indoor plasticizers and health \u003cbr\u003e17.5.4.2 Human exposure assessment for plasticizers in the indoor\u003cbr\u003e environment \u003cbr\u003e17.5.4.3 Reference and guideline values of plasticizers to assess indoor\u003cbr\u003e quality \u003cbr\u003e17.5.5 Summary \u003cbr\u003e\u003cbr\u003e\u003cstrong\u003e18 THE ENVIRONMENTAL FATE OF PLASTICIZERS\u003c\/strong\u003e \u003cbr\u003e William R. Roy\u003cbr\u003e18.1 Introduction \u003cbr\u003e18.1.1 Releases to the environment \u003cbr\u003e18.1.2 Levels in the environment \u003cbr\u003e18.2 Plasticizers in water \u003cbr\u003e18.2.1 Solubility \u003cbr\u003e18.2.2 Volatilization from water. \u003cbr\u003e18.2.3 Abiotic degradation in water \u003cbr\u003e18.2.4 Biodegradation in water \u003cbr\u003e18.2.5 Adsorption from water \u003cbr\u003e18.3 Soil and sediment \u003cbr\u003e18.3.1 Volatilization \u003cbr\u003e18.3.2 Biodegradation in soil \u003cbr\u003e18.4 Organisms \u003cbr\u003e18.5 Air \u003cbr\u003e Summary and concluding remarks \u003cbr\u003e\u003cbr\u003e\u003cstrong\u003e19 REGULATIONS AND DATA\u003c\/strong\u003e \u003cbr\u003e George Wypych\u003cbr\u003e19.1 Toxic substance control \u003cbr\u003e19.2. Carcinogenic effect \u003cbr\u003e19.3 Teratogenic and mutagenic effect \u003cbr\u003e19.4 Workplace exposure limits \u003cbr\u003e19.5 Exposure from consumer products \u003cbr\u003e19.6 Plasticizers in drinking water \u003cbr\u003e19.7 Food regulatory acts \u003cbr\u003e19.8 Medical and other applications \u003cbr\u003e\u003cbr\u003e\u003cbr\u003e\u003cstrong\u003e20 PERSONAL PROTECTION\u003c\/strong\u003e \u003cbr\u003e George Wypych\u003cbr\u003e20.1 Clothing \u003cbr\u003e20.2 Gloves \u003cbr\u003e20.3 Eye protection \u003cbr\u003e20.4 Respiratory protection \u003cbr\u003e\u003cbr\u003e\u003cstrong\u003e21 PLASTICIZER RECOVERY \u0026amp; RECYCLING\u003c\/strong\u003e \u003cbr\u003e George Wypych\u003cbr\u003e\u003cbr\u003e \u003cstrong\u003eINDEX\u003c\/strong\u003e\u003cbr\u003e\u003c\/p\u003e\n\u003cp\u003e \u003c\/p\u003e\n\u003ch5\u003eAbout Author\u003c\/h5\u003e\nGeorge Wypych has PhD Eng. The professional expertise includes university teaching (full professor) and research \u0026amp; development (university and corporate). He has published 48 books (PVC Plastisols, Wroclaw University Press; Polyvinylchloride Degradation, Elsevier; Polyvinylchloride Stabilization, Elsevier; Polymer Modified Textile Materials, Wiley \u0026amp; Sons; Handbook of Material Weathering, 1st, 2nd, 3rd, 4th, 5th, 6th Edition, ChemTec Publishing; Handbook of Fillers, 1st, 2nd, 3rd, 4th, and 5th Edition, ChemTec Publishing; Recycling of PVC, ChemTec Publishing; Weathering of Plastics. Testing to Mirror Real Life Performance, Plastics Design Library, Handbook of Solvents, Vol. 1. Properties 1st, 2nd, and 3rd Edition, ChemTec Publishing, Handbook of Solvents, Vol. 2. Health \u0026amp; Environment 1st, 2nd, and 3rd Edition, ChemTec Publishing, Handbook of Plasticizers, 1st, 2nd, 3rd, 4th Edition, ChemTec Publishing, Handbook of Antistatics, 1st and 2nd Edition, ChemTec Publishing, Databook of Antistatics, 1st and 2nd Edition, ChemTec Publishing, Handbook of Antiblocking, Release and Slip Additives, 1st , 2nd and 3rd Edition, ChemTec Publishing, Industrial Solvents in Kirk-Othmer Encyclopedia of Chemical Technology (two editions), John Wiley \u0026amp; Sons, PVC Degradation \u0026amp; Stabilization, 1st, 2nd, 3rd, and 4th Editions, ChemTec Publishing, The PVC Formulary, 1st, 2nd, and 3rd Editions, ChemTec Publishing, Handbook of Material Biodegradation, Biodeterioration, and Biostabilization, 1st and 2nd Editions, ChemTec Publishing, Handbook of UV Degradation and Stabilization, 1st, 2nd, and 3rd Editions, ChemTec Publishing, Handbook of Polymers, 1st, 2nd, and 3rd Editions, ChemTec Publishing, Atlas of Material Damage, 1st, 2nd, and 3rd Editions, ChemTec Publishing, Handbook of Odors in Plastic Materials, 1st, 2nd, and 3rd Editions, ChemTec Publishing, Databook of Solvents (two editions), ChemTec Publishing, Databook of Blowing and Auxiliary Agents, ChemTec Publishing, Handbook of Foaming and Blowing Agents (two editions), ChemTec Publishing, Databook of Green Solvents, ChemTec Publishing (two editions), Self-healing Products (two editions), ChemTec Publishing, Handbook of Adhesion Promoters (two editions), ChemTec Publishing, Databook of Surface Modification Additives (two editions), ChemTec Publishing, Handbook of Surface Improvement and Modification (two editions), ChemTec Publishing, Graphene – Important Results and Applications, ChemTec Publishing, Handbook of Curatives and Crosslinkers, ChemTec Publishing, Chain Mobility and Progress in Medicine, Pharmaceutical, Polymer Science and Technology, Impact of Award, ChemTec Publishing, Databook of Antioxidants, ChemTec Publishing, Handbook of Antioxidants, ChemTec Publishing, Databook of UV Stabilizers (two Editions), ChemTec Publishing, Databook of Flame Retardants, ChemTec Publishing, Databook of Nucleating Agents, ChemTec Publishing, Handbook of Flame Retardants, ChemTec Publishing, Handbook of Nucleating Agents, ChemTec Publishing, Handbook of Polymers in Electronics, ChemTec Publishing, Databook of Impact Modifiers, ChemTec Publishing, Databook of Rheological Additives, ChemTec Publishing, Handbook of Impact Modifiers, ChemTec Publishing, Handbook of Rheological Additives, ChemTec Publishing, Databook of Polymer Processing Additives, ChemTec Publishing, Handbook of Polymer Processing Additives, ChemTec Publishing, Functional Fillers (two editions), 2 databases (Solvents Database, 1st, 2nd, 3rd Edition and Database of Antistatics 1st and 2nd Edition, both by ChemTec Publishing), and 42 scientific papers and obtained 16 patents. He specializes in PVC, polymer additives, material durability, and the development of sealants and coatings. He was included in the Dictionary of International Biography, Who's Who in Plastics and Polymers, and Who's Who in Engineering, and was selected International Man of the Year 1996-1997 in recognition of services to education.","published_at":"2023-02-24T14:06:20-05:00","created_at":"2023-02-24T13:56:07-05:00","vendor":"Chemtec Publishing","type":"Book","tags":["abiotic","adipates","adsorption","alkyl sulfonates","azelates","benzoates","biodegradation","book","chlorinated paraffins","citrates","coated fabrics","cosmetics","database","degradation","dental materials","electrical","electronics","energetic plasticizers","environment","epoxides","eye protection","fibers","film","flooring","foams","food","footwear","gaskets","gloves","inks","medical applications","membranes","p-additives","paints","pharmaceutical products","plasticisers","plasticizers additives","polymer","releases","solubility","varnishes","volatilization","water"],"price":39000,"price_min":39000,"price_max":39000,"available":true,"price_varies":false,"compare_at_price":null,"compare_at_price_min":0,"compare_at_price_max":0,"compare_at_price_varies":false,"variants":[{"id":43393978663069,"title":"Default Title","option1":"Default Title","option2":null,"option3":null,"sku":"","requires_shipping":true,"taxable":true,"featured_image":null,"available":true,"name":"Handbook of Plasticizers, 4th Edition","public_title":null,"options":["Default Title"],"price":39000,"weight":1000,"compare_at_price":null,"inventory_quantity":0,"inventory_management":null,"inventory_policy":"deny","barcode":"978-1-77467-022-4","requires_selling_plan":false,"selling_plan_allocations":[]}],"images":["\/\/chemtec.org\/cdn\/shop\/products\/9781774670224-Case.png?v=1677265546"],"featured_image":"\/\/chemtec.org\/cdn\/shop\/products\/9781774670224-Case.png?v=1677265546","options":["Title"],"media":[{"alt":null,"id":27340016779421,"position":1,"preview_image":{"aspect_ratio":0.658,"height":450,"width":296,"src":"\/\/chemtec.org\/cdn\/shop\/products\/9781774670224-Case.png?v=1677265546"},"aspect_ratio":0.658,"height":450,"media_type":"image","src":"\/\/chemtec.org\/cdn\/shop\/products\/9781774670224-Case.png?v=1677265546","width":296}],"requires_selling_plan":false,"selling_plan_groups":[],"content":"\u003ch5\u003eDescription\u003c\/h5\u003e\n\u003cp\u003eEditor: George Wypych \u003cbr\u003eISBN 978-1- 77467-022-4 (hard copy)\u003cbr\u003e\u003cbr\u003ePublished: Jan. 2023 \u003cbr data-mce-fragment=\"1\"\u003ePages 894+xxii\u003cbr data-mce-fragment=\"1\"\u003eTables 115, Figures 360\u003cbr data-mce-fragment=\"1\"\u003e\u003cbr\u003e\u003c\/p\u003e\n\u003cp\u003e \u003c\/p\u003e\n\u003ch5\u003eSummary\u003c\/h5\u003e\n\u003cp\u003eHandbook of Plasticizers brings together in one place all that is known about this vital and rapidly expanding field. The book serves both as a basic reference source for researchers, engineers, and others involved in plastics processing, research and development as well as a source of ideas regarding future developments.\u003cbr\u003e\u003cbr\u003eThis book contains a comprehensive review of information available in the open literature, such as published scientific papers, information from plasticizer manufacturers, and patent literature. The information from the most recent sources was used to update information from previous editions. \u003cbr\u003eThe information available today permits the use of plasticizers more effectively and helps to avoid certain plasticizers in applications where they may cause health or material durability problems. The source of raw materials used to produce plasticizers is becoming one of the issues in their selection. The book contains information on plasticizers obtained from renewable resources. Plasticizer incorporation demands a broad background of information because plasticizers are now added to complex mixtures containing a variety of materials that may have different reactions to the presence of plasticizers. Plasticizer choice is also not simple because there is a large selection of commercial plasticizers and various environmental issues dictating preferred solutions.\u003cbr\u003e\u003cbr\u003eBoth aspects considered indicate the need for a comprehensive source which, using currently available means of the computerized database, should provide data and a broad background of theoretical information in a condensed form easy to search. \u003cbr\u003e\u003cbr\u003eNumerical data on the most important plasticizers are provided in the tabular form of the printed book entitled Databook of Plasticizers. \u003cbr\u003eTwenty-one chapters are included in the Handbook of Plasticizers. The full Table of Contents is given below. Only some chapters are discussed here to add more information that may not be obvious from the table of contents.\u003cbr\u003e\u003cbr\u003eData are available for a large number of commercial plasticizers. This data is used in Chapter 2 to specify typical properties of plasticizers that belong to one of the thirty-one groups. The ranges of expected properties for a given group are also given.\u003cbr\u003e\u003cbr\u003eChapters 5, 6, and 7 contain new and historical approaches, which explain the mechanisms of plasticizers’ action and their behavior in plasticized systems. This theoretical background helps to understand practical observations and provides guidance to the methods of material improvement. Chapter 9 shows plasticization steps and results of various analytical studies, which help in understanding these steps and the parameters which may control them.\u003cbr\u003e\u003cbr\u003eTwenty-nine sections of Chapter 10 discuss plasticizers’ effect on the physical and mechanical properties of plasticized materials. These sections are essential for understanding the behavior of materials and the principles of their formulation. \u003cbr\u003e\u003cbr\u003e\u003cbr\u003e\u003cbr\u003e\u003cbr\u003eChapter 11 contains data on the use of plasticizers in 61 groups of polymers. The information is grouped under the following sections – Frequently used plasticizers, Practical concentrations, Main functions performed by plasticizers, Mechanism of plasticizer action, Effect of plasticizers on polymer and other additives, and Typical formulations. The use of such a consistent method of data presentation helps to find information quickly and to compare data from various sources and applications. \u003cbr\u003e\u003cbr\u003eSimilarly, Chapter 13 discusses the use of plasticizers in 33 groups of products according to a similar breakdown, including Plasticizer types, Plasticizer concentration, Reasons for plasticizer use, Advantages and disadvantages of plasticizer use, Effect of plasticizers on product properties, and Examples of formulations. Both chapters make use of a large number of patents and information in open literature discussing the most current findings and trends.\u003cbr\u003e\u003cbr\u003eIn Chapter 14, attempts are being made to discuss the following topics: The effect of plasticizers on process conditions, Processing defects formation and elimination with the use of plasticizers, In the fluence of rheological changes on the process, Equipment maintenance, and energy consumption. This chapter discusses 15 methods of polymer and rubber processing.\u003cbr\u003eSeveral chapters which follow discuss various aspects of plasticizer’s effect on health, safety, and the environment. Chapter 17 contains opinions of renowned experts on various aspects of plasticizers’ effect on health and safety. Chapter 18 contains information on plasticizers’ persistence in soil and water. Plasticizers releases and their presence in the environment are discussed for many important commercial plasticizers.\u003cbr\u003e\u003cbr\u003eThis short review and the Table of Contents show that this book is the most comprehensive source of current information on plasticizers. Plasticizers are used in so many products that every library should have this reference source of information on plasticizers readily available for its readers, especially considering that so many aspects of application plasticizers have recently changed that older books cannot provide the right answers. This book is best used in conjunction with the Plasticizer Database and\/or Databook of Plasticizers which give information on the present status and properties of industrial and research plasticizers.\u003cbr\u003e\u003c\/p\u003e\n\u003cbr\u003e \u003cbr\u003e\u003cbr\u003e\n\u003ch5\u003eTable of Contents\u003c\/h5\u003e\n\u003cp\u003e\u003cstrong\u003e1 INTRODUCTION\u003c\/strong\u003e \u003cbr\u003e George Wypych\u003cbr\u003e1.1 Historical developments \u003cbr\u003e1.2 Expectations from plasticizers \u003cbr\u003e1.3 Definitions \u003cbr\u003e1.4 Classification \u003cbr\u003e\u003cbr\u003e\u003cstrong\u003e2 PLASTICIZER TYPES\u003c\/strong\u003e \u003cbr\u003e George Wypych\u003cbr\u003e2.1 Introduction \u003cbr\u003e2.2 Characteristic properties of industrial plasticizers \u003cbr\u003e2.2.1 Abietates \u003cbr\u003e2.2.2 Adipates \u003cbr\u003e2.2.3 Alkyl sulfonates \u003cbr\u003e2.2.4 Amides and amines \u003cbr\u003e2.2.5 Azelates \u003cbr\u003e2.2.6 Benzoates \u003cbr\u003e2.2.7 Bioplasticizers \u003cbr\u003e2.2.8 Biodegradable plasticizers \u003cbr\u003e2.2.9 Chlorinated paraffins, \u003cbr\u003e2.2.10 Citrates \u003cbr\u003e2.2.11 Cyclohexane dicarboxylic acid, diisononyl ester \u003cbr\u003e2.2.12 Energetic plasticizers \u003cbr\u003e2.2.13 Epoxides \u003cbr\u003e2.2.14 Esters of C10-30 dicarboxylic acids \u003cbr\u003e2.2.15 Ether-ester plasticizers \u003cbr\u003e2.2.16 Glutarates \u003cbr\u003e2.2.17 Hydrocarbon oils \u003cbr\u003e2.2.18 Hydrocarbon resins \u003cbr\u003e2.2.19 Isobutyrates \u003cbr\u003e2.2.20 Maleates \u003cbr\u003e2.2.21 Oleates \u003cbr\u003e2.2.22 Pentaerythritol derivatives \u003cbr\u003e2.2.23 Phosphates \u003cbr\u003e2.2.24 Phthalate-free plasticizers \u003cbr\u003e2.2.25 Phthalates \u003cbr\u003e2.2.26 Polymeric plasticizers \u003cbr\u003e2.2.26.1 Esters \u003cbr\u003e2.2.26.2 Polybutenes \u003cbr\u003e2.26.3 Others \u003cbr\u003e2.2.27 Ricinoleates \u003cbr\u003e2.2.28 Sebacates \u003cbr\u003e2.2.29 Succinates \u003cbr\u003e2.2.30 Sulfonamides \u003cbr\u003e2.2.31 Superplasticizers and plasticizers for concrete \u003cbr\u003e2.2.32 Tri- and pyromellitates \u003cbr\u003e2.3 Methods of synthesis and their effect on properties of plasticizers \u003cbr\u003e2.4 Reactive plasticizers and internal plasticization \u003cbr\u003e\u003cbr\u003e\u003cstrong\u003e3 TYPICAL METHODS OF QUALITY CONTROL OF PLASTICIZERS\u003c\/strong\u003e \u003cbr\u003e George Wypych\u003cbr\u003e3.1 Abbreviations, terminology, and vocabulary \u003cbr\u003e3.2 Acid number \u003cbr\u003e3.3 Aging studies \u003cbr\u003e3.4 Ash \u003cbr\u003e3.5 Brittleness temperature \u003cbr\u003e3.6 Brookfield viscosity \u003cbr\u003e3.7 Chemical resistance \u003cbr\u003e3.8 Color \u003cbr\u003e3.9 Compatibility \u003cbr\u003e3.10 Compression set \u003cbr\u003e3.11 Concrete additives \u003cbr\u003e3.12 Electrical properties \u003cbr\u003e3.13 Extractable matter \u003cbr\u003e3.14 Flash and fire point \u003cbr\u003e3.15 Fogging \u003cbr\u003e3.16 Fusion \u003cbr\u003e3.17 Gas chromatography \u003cbr\u003e3.18 Hardness \u003cbr\u003e3.19 Infrared analysis of plasticizers \u003cbr\u003e3.20 Kinematic viscosity \u003cbr\u003e3.21 Marking (classification) \u003cbr\u003e3.22 Melt rheology \u003cbr\u003e3.23 Migration \u003cbr\u003e3.24 Polyvinylchloride standard specification \u003cbr\u003e3.25 Powder-mix time \u003cbr\u003e3.26 Purity \u003cbr\u003e3.27 Refractive index \u003cbr\u003e3.28 Residual contamination \u003cbr\u003e3.29 Sampling \u003cbr\u003e3.30 Saponification value \u003cbr\u003e3.31 Saybolt viscosity \u003cbr\u003e3.32 Sorption of plasticizer \u003cbr\u003e3.33 Specific gravity \u003cbr\u003e3.34 Specification \u003cbr\u003e3.35 Staining \u003cbr\u003e3.36 Stiffness \u003cbr\u003e3.37 Tensile properties \u003cbr\u003e3.38 Thermal expansion coefficient \u003cbr\u003e3.39 Unsaponifiable contents \u003cbr\u003e3.40 Viscosity of plastisols and organosols \u003cbr\u003e3.41 Water concentration \u003cbr\u003e3.42 Weight loss \u003cbr\u003e\u003cbr\u003e\u003cstrong\u003e4 TRANSPORTATION AND STORAGE\u003c\/strong\u003e \u003cbr\u003e George Wypych\u003cbr\u003e4.1 Transportation \u003cbr\u003e4.2 Storage \u003cbr\u003e\u003cbr\u003e\u003cstrong\u003e5 MECHANISMS OF PLASTICIZERS ACTION\u003c\/strong\u003e \u003cbr\u003e A. Marcilla and M. Beltrán\u003cbr\u003e5.1 Classical theories \u003cbr\u003e5.1.1 The lubricity theory \u003cbr\u003e5.1.2 The gel theory \u003cbr\u003e5.1.3 Moorshead's empirical approach \u003cbr\u003e5.2 The free volume theory \u003cbr\u003e5.2.1 Mathematical models \u003cbr\u003e\u003cbr\u003e\u003cstrong\u003e6 COMPATIBILITY OF PLASTICIZERS 159\u003c\/strong\u003e\u003cbr\u003e George Wypych\u003cbr\u003e6.1 Prediction methods of plasticizer compatibility \u003cbr\u003e6.1.1 Flory-Huggins interaction parameter \u003cbr\u003e6.1.2 Prediction of Gibbs free energy of mixing UNIFAC-FV \u003cbr\u003e6.1.3 Molar volume \u003cbr\u003e6.1.4 Polarity \u003cbr\u003e6.1.5 Hansen solubility parameters \u003cbr\u003e6.1.6 Hoy solubility parameters and other methods based on solubility\u003cbr\u003e parameters \u003cbr\u003e6.1.7 Hildebrand solubility parameter \u003cbr\u003e6.1.8 Molecule charge density using COSMO \u003cbr\u003e6.1.9 Mesoscale simulation using DPD \u003cbr\u003e6.1.10 Ap\/Po ratio \u003cbr\u003e6.2 Validation methods \u003cbr\u003e6.2.1 DSC analysis \u003cbr\u003e6.2.2 Inverse gas chromatography \u003cbr\u003e6.2.3 Solid-gel transition temperature \u003cbr\u003e6.3 Effect of plasticizer structure and conditions of incorporation on\u003cbr\u003e compatibility \u003cbr\u003e6.3.1 Effect of plasticizer structure \u003cbr\u003e6.3.1.1 Aromaticity \u003cbr\u003e6.3.1.2 Branching \u003cbr\u003e6.3.1.3 Chain length \u003cbr\u003e6.3.1.4 Molecular weight \u003cbr\u003e6.3.1.5 Polarity \u003cbr\u003e6.3.2 Conditions of incorporation \u003cbr\u003e6.3.2.1 Amount (concentration) \u003cbr\u003e6.3.2.2 Method of processing \u003cbr\u003e6.3.2.3 Temperature \u003cbr\u003e6.4 Effect of plasticizer type on properties of plasticized material \u003cbr\u003e6.4.1 Crystallinity \u003cbr\u003e6.4.2 Exudation \u003cbr\u003e6.4.3 Permanence \u003cbr\u003e6.4.4 Thermal degradation \u003cbr\u003e6.4.5 Volatility \u003cbr\u003e\u003cbr\u003e\u003cstrong\u003e7 PLASTICIZER MOTION AND DIFFUSION\u003c\/strong\u003e \u003cbr\u003e George Wypych\u003cbr\u003e7.1 Plasticizer diffusion rate and the methods of study \u003cbr\u003e7.2 Plasticizer motion and distribution in the matrix \u003cbr\u003e7.3 Plasticizer migration \u003cbr\u003e7.4 Antiplasticization \u003cbr\u003e7.5 Effect of diffusion and mobility of plasticizers on their suitability \u003cbr\u003e\u003cbr\u003e\u003cstrong\u003e8 EFFECT OF PLASTICIZERS ON OTHER COMPONENTS OF FORMULATION\u003c\/strong\u003e \u003cbr\u003e George Wypych\u003cbr\u003e8.1 Plasticizer consumption by fillers \u003cbr\u003e8.2 Solubility of additives in plasticizers \u003cbr\u003e8.3 Additive molecular mobility and transport in the presence of\u003cbr\u003e plasticizers \u003cbr\u003e8.4 Effect of plasticizers on polymerization and curing reactions \u003cbr\u003e\u003cbr\u003e\u003cstrong\u003e9 PLASTICIZATION STEPS\u003c\/strong\u003e \u003cbr\u003e A. Marcilla, J.C. García and M. Beltrán\u003cbr\u003e9.1 Plasticization steps \u003cbr\u003e9.2 Studies of plastisol's behavior during gelation and fusion \u003cbr\u003e9.2.1 Rheological characterization \u003cbr\u003e9.2.2 Studies by Scanning Electron Microscopy \u003cbr\u003e9.2.3 Study of polymer-plasticizer interactions by DSC \u003cbr\u003e9.2.4 Study of polymer-plasticizer interactions by SALS \u003cbr\u003e9.2.5 Study of polymer-plasticizer interactions by FTIR \u003cbr\u003e9.2.6 Study of polymer-plasticizer interactions by TG \u003cbr\u003e\u003cbr\u003e\u003cstrong\u003e10 EFFECT OF PLASTICIZERS ON PROPERTIES OF PLASTICIZED MATERIALS\u003c\/strong\u003e\u003cbr\u003e George Wypych\u003cbr\u003e10.1 Mechanical properties \u003cbr\u003e10.1.1 Tensile strength \u003cbr\u003e10.1.2 Elongation \u003cbr\u003e10.1.3 Hardness \u003cbr\u003e10.1.4 Toughness, stiffness, ductility, modulus \u003cbr\u003e10.1.5 Other mechanical properties \u003cbr\u003e10.2 Optical properties \u003cbr\u003e10.3 Spectral properties \u003cbr\u003e10.4 Gloss \u003cbr\u003e10.5 Sound \u003cbr\u003e10.6 Rheological properties \u003cbr\u003e10.7 Magnetorheological properties \u003cbr\u003e10.8 Electrical properties \u003cbr\u003e10.9 Glass transition temperature \u003cbr\u003e10.10 Flammability and smoke formation in the presence of plasticizers \u003cbr\u003e10.11 Thermal degradation \u003cbr\u003e10.11.1 Thermal degradation of plasticizers \u003cbr\u003e10.11.2 Effect of polymer degradation products on plasticizers \u003cbr\u003e10.11.3 Effect of plasticizer degradation products on polymer degradation \u003cbr\u003e10.11.4 Loss of plasticizer from the material due to chemical decomposition\u003cbr\u003e reactions and evaporation \u003cbr\u003e10.11.5 Effect of plasticizers on the thermal degradation of materials \u003cbr\u003e10.12 Effect of UV and ionizing radiation on plasticized materials \u003cbr\u003e10.13 Hydrolysis \u003cbr\u003e10.14 Biodegradation in the presence of plasticizers \u003cbr\u003e10.15 Crystallization, structure, and orientation of macromolecules \u003cbr\u003e10.16 Morphology \u003cbr\u003e10.17 Plasticizer effect on contact with other materials \u003cbr\u003e10.18 Influence of plasticizers on swelling \u003cbr\u003e10.19 Fogging \u003cbr\u003e10.20 Hydrophobic\/hydrophilic properties \u003cbr\u003e10.21 Osmotic pressure of plasticizer in polymer \u003cbr\u003e10.22 Self-healing \u003cbr\u003e10.23 Shrinkage \u003cbr\u003e10.24 Soiling \u003cbr\u003e10.25 Free volume \u003cbr\u003e10.26 Dissolution \u003cbr\u003e10.27 Foaming \u003cbr\u003e10.28 Permeability \u003cbr\u003e10.29 Sorption \u003cbr\u003e\u003cbr\u003e\u003cstrong\u003e11 PLASTICIZERS USE AND SELECTION FOR SPECIFIC POLYMERS\u003c\/strong\u003e \u003cbr\u003e George Wypych\u003cbr\u003e11.1 ABS \u003cbr\u003e11.1.1 Frequently used plasticizers \u003cbr\u003e11.1.2 Practical concentrations \u003cbr\u003e11.1.3 Main functions performed by plasticizers \u003cbr\u003e11.1.4 Mechanism of plasticizer action \u003cbr\u003e11.1.5 Effect of plasticizers on polymer and other additives \u003cbr\u003e11.1.6 Typical formulations \u003cbr\u003e11.2 Acrylics \u003cbr\u003e11.2.1 Frequently used plasticizers \u003cbr\u003e11.2.2 Practical concentrations \u003cbr\u003e11.2.3 Main functions performed by plasticizers \u003cbr\u003e11.2.4 Mechanism of plasticizer action \u003cbr\u003e11.2.5 Typical formulations \u003cbr\u003e11.3 Bromobutyl rubber \u003cbr\u003e11.3.1 Frequently used plasticizers \u003cbr\u003e11.3.2 Practical concentrations \u003cbr\u003e11.3.3 Main functions performed by plasticizers \u003cbr\u003e11.3.4 Effect of plasticizers on polymer and other additives \u003cbr\u003e11.4 Butyl terpolymer \u003cbr\u003e11.4.1 Frequently used plasticizers \u003cbr\u003e11.4.2 Practical concentrations \u003cbr\u003e11.5 Cellulose acetate \u003cbr\u003e11.5.1 Frequently used plasticizers \u003cbr\u003e11.5.2 Practical concentrations \u003cbr\u003e11.5.3 Main functions performed by plasticizers \u003cbr\u003e11.5.4 Mechanism of plasticizer action \u003cbr\u003e11.5.5 Effect of plasticizers on polymer and other additives \u003cbr\u003e11.6 Cellulose butyrate and propionate \u003cbr\u003e11.6.1 Frequently used plasticizers \u003cbr\u003e11.6.2 Practical concentrations \u003cbr\u003e11.6.3 Main functions performed by plasticizers \u003cbr\u003e11.6.4 Effect of plasticizers on polymer and other additives \u003cbr\u003e11.7 Cellulose nitrate \u003cbr\u003e11.7.1 Frequently used plasticizers \u003cbr\u003e11.7.2 Practical concentrations \u003cbr\u003e11.7.3 Main functions performed by plasticizers \u003cbr\u003e11.7.4 Effect of plasticizers on polymer and other additives \u003cbr\u003e11.7.5 Typical formulations \u003cbr\u003e11.8 Chitosan \u003cbr\u003e11.8.1 Frequently used plasticizers \u003cbr\u003e11.8.2 Practical concentrations \u003cbr\u003e11.8.3 Main functions performed by plasticizers \u003cbr\u003e11.8.4 Effect of plasticizers on polymer and other additives \u003cbr\u003e11.9 Chlorinated polyvinylchloride \u003cbr\u003e11.9.1 Frequently used plasticizers \u003cbr\u003e11.9.2 Effect of plasticizers on polymer and other additives \u003cbr\u003e11.10 Chlorosulfonated polyethylene \u003cbr\u003e11.10.1 Frequently used plasticizers \u003cbr\u003e11.10.2 Effect of plasticizers on polymer and other additives \u003cbr\u003e11.11 Copolymers \u003cbr\u003e11.11.1 Frequently used plasticizers \u003cbr\u003e11.11.2 Practical concentrations \u003cbr\u003e11.11.3 Main functions performed by plasticizers \u003cbr\u003e11.11.4 Mechanism of plasticizer action \u003cbr\u003e11.12 Cyanoacrylates \u003cbr\u003e11.12.1 Frequently used plasticizers \u003cbr\u003e11.12.2 Practical concentrations \u003cbr\u003e11.12.3 Main functions performed by plasticizers \u003cbr\u003e11.12.4 Effect of plasticizer on polymer and other additives \u003cbr\u003e11.13 Ethylcellulose \u003cbr\u003e11.13.1 Frequently used plasticizers \u003cbr\u003e11.13.2 Practical concentrations \u003cbr\u003e11.13.3 Effect of plasticizers on polymer and other additives \u003cbr\u003e11.14 Epoxy resin \u003cbr\u003e11.14.1 Frequently used plasticizers \u003cbr\u003e11.14.2 Practical concentrations \u003cbr\u003e11.14.3 Main functions performed by plasticizers \u003cbr\u003e11.14.4 Effect of plasticizers on polymer and other additives \u003cbr\u003e11.15 Ethylene-propylene-diene copolymer \u003cbr\u003e11.15.1 Frequently used plasticizers \u003cbr\u003e11.15.2 Practical concentrations \u003cbr\u003e11.15.3 Main functions performed by plasticizers \u003cbr\u003e11.15.4 Effect of plasticizers on polymer and other additives \u003cbr\u003e11.15.5 Typical formulations \u003cbr\u003e11.16 Ethylene-vinyl acetate copolymer \u003cbr\u003e11.17 Ionomers \u003cbr\u003e11.17.1 Frequently used plasticizers \u003cbr\u003e11.17.2 Practical concentrations \u003cbr\u003e11.17.3 Main functions performed by plasticizers \u003cbr\u003e11.17.4 Mechanism of plasticizer action \u003cbr\u003e11.17.5 Effect of plasticizers on polymer and other additives \u003cbr\u003e11.18 Nitrile rubber \u003cbr\u003e11.18.1 Frequently used plasticizers \u003cbr\u003e11.18.2 Practical concentrations \u003cbr\u003e11.18.3 Main functions performed by plasticizers \u003cbr\u003e11.18.4 Effect of plasticizers on polymer and other additives \u003cbr\u003e11.18.5 Typical formulations \u003cbr\u003e11.19 Perfluoropolymers \u003cbr\u003e11.20 Polyacrylonitrile \u003cbr\u003e11.20.1 Frequently used plasticizers \u003cbr\u003e11.20.2 Practical concentrations \u003cbr\u003e11.20.3 Main functions performed by plasticizers \u003cbr\u003e11.20.4 Effect of plasticizers on polymer and other additives \u003cbr\u003e11.21 Polyamide \u003cbr\u003e11.21.1 Frequently used plasticizers \u003cbr\u003e11.21.2 Practical concentrations \u003cbr\u003e11.21.3 Main functions performed by plasticizers \u003cbr\u003e11.21.4 Effect of plasticizers on polymer and other additives \u003cbr\u003e11.22 Polyamine \u003cbr\u003e11.23 Polyaniline \u003cbr\u003e11.24 Polybutadiene \u003cbr\u003e11.24.1 Frequently used plasticizers \u003cbr\u003e11.24.2 Practical concentrations \u003cbr\u003e11.24.3 Main functions performed by plasticizers \u003cbr\u003e11.25 Polybutylene \u003cbr\u003e11.25.1 Frequently used plasticizers \u003cbr\u003e11.25.2 Practical concentrations \u003cbr\u003e11.25.3 Main functions performed by plasticizers \u003cbr\u003e11.26 Poly(butyl methacrylate) \u003cbr\u003e11.26.1 Frequently used plasticizers \u003cbr\u003e11.26.2 Practical concentrations \u003cbr\u003e11.26.3 Main functions performed by plasticizers \u003cbr\u003e11.27 Polycarbonate \u003cbr\u003e11.27.1 Frequently used plasticizers \u003cbr\u003e11.27.2 Practical concentrations \u003cbr\u003e11.27.3 Main functions performed by plasticizers \u003cbr\u003e11.27.4 Effect of plasticizers on polymer and other additives \u003cbr\u003e11.28 Polyester \u003cbr\u003e11.28.1 Frequently used plasticizers \u003cbr\u003e11.28.2 Practical concentrations \u003cbr\u003e11.28.3 Main functions performed by plasticizers \u003cbr\u003e11.28.4 Effect of plasticizers on polymer and other additives \u003cbr\u003e11.28.5 Typical formulations \u003cbr\u003e11.29 Polyetherimide \u003cbr\u003e11.30 Polyethylacrylate \u003cbr\u003e11.31 Polyethylene \u003cbr\u003e11.31.1 Frequently used plasticizers \u003cbr\u003e11.31.2 Practical concentrations \u003cbr\u003e11.31.3 Main functions performed by plasticizers \u003cbr\u003e11.31.4 Mechanism of plasticizer action \u003cbr\u003e11.31.5 Typical formulations \u003cbr\u003e11.32 Poly(ethylene oxide) \u003cbr\u003e11.32.1 Frequently used plasticizers \u003cbr\u003e11.32.2 Practical concentrations \u003cbr\u003e11.32.3 Main functions performed by plasticizers \u003cbr\u003e11.32.4 Effect of plasticizers on polymer and other additives \u003cbr\u003e11.33 Poly(3-hydroxybutyrate) \u003cbr\u003e11.33.1 Frequently used plasticizers \u003cbr\u003e11.33.2 Practical concentrations \u003cbr\u003e11.33.3 Main functions performed by plasticizers \u003cbr\u003e11.34 Polyisobutylene \u003cbr\u003e11.35 Polyisoprene \u003cbr\u003e11.35.1 Frequently used plasticizers \u003cbr\u003e11.35.2 Practical concentrations \u003cbr\u003e11.35.3 Main functions performed by plasticizers \u003cbr\u003e11.35.4 Typical formulations \u003cbr\u003e11.36 Polyimide \u003cbr\u003e11.36.1 Frequently used plasticizers \u003cbr\u003e11.36.2 Practical concentrations \u003cbr\u003e11.36.3 Main functions performed by plasticizers \u003cbr\u003e11.36.4 Effect of plasticizers on polymer and other additives \u003cbr\u003e11.37 Polylactide \u003cbr\u003e11.37.1 Frequently used plasticizers \u003cbr\u003e11.37.2 Practical concentrations \u003cbr\u003e11.37.3 Main functions performed by plasticizers \u003cbr\u003e11.37.4 Effect of plasticizers on polymer and other additives \u003cbr\u003e11.38 Polymethylmethacrylate \u003cbr\u003e11.38.1 Frequently used plasticizers \u003cbr\u003e11.38.2 Practical concentrations \u003cbr\u003e11.38.3 Main functions performed by plasticizers \u003cbr\u003e11.38.4 Mechanism of plasticizer action \u003cbr\u003e11.38.5 Typical formulations \u003cbr\u003e11.39 Polypropylene \u003cbr\u003e11.39.1 Frequently used plasticizers \u003cbr\u003e11.39.2 Practical concentrations \u003cbr\u003e11.39.3 Main functions performed by plasticizers \u003cbr\u003e11.39.4 Effect of plasticizers on polymer and other additives \u003cbr\u003e11.40 Poly(propylene carbonate) \u003cbr\u003e11.40.1 Frequently used plasticizers \u003cbr\u003e11.40.2 Practical concentrations \u003cbr\u003e11.40.3 Main functions performed by plasticizers \u003cbr\u003e11.40.4 Effect of plasticizers on polymer and other additives \u003cbr\u003e11.41 Poly(N-vinylcarbazole) \u003cbr\u003e11.42 Poly(N-vinylpyrrolidone) \u003cbr\u003e11.42.1 Frequently used plasticizers \u003cbr\u003e11.42.2 Practical concentrations \u003cbr\u003e11.42.3 Main functions performed by plasticizers \u003cbr\u003e11.42.4 Mechanism of plasticizer action \u003cbr\u003e11.42.5 Typical formulations \u003cbr\u003e11.43 Poly(phenylene ether) \u003cbr\u003e11.43.1 Frequently used plasticizers \u003cbr\u003e11.43.2 Practical concentrations \u003cbr\u003e11.43.3 Main functions performed by plasticizers \u003cbr\u003e11.44 Poly(phenylene sulfide) \u003cbr\u003e11.45 Polystyrene \u003cbr\u003e11.45.1 Frequently used plasticizers \u003cbr\u003e11.45.2 Practical concentrations \u003cbr\u003e11.45.3 Main functions performed by plasticizers \u003cbr\u003e11.46 Polysulfide \u003cbr\u003e11.46.1 Frequently used plasticizers \u003cbr\u003e11.46.2 Practical concentrations \u003cbr\u003e11.46.3 Main functions performed by plasticizers \u003cbr\u003e11.47 Polysulfone \u003cbr\u003e11.48 Polyurethanes \u003cbr\u003e11.48.1 Frequently used plasticizers \u003cbr\u003e11.48.2 Practical concentrations \u003cbr\u003e11.48.3 Main functions performed by plasticizers \u003cbr\u003e11.48.4 Mechanism of plasticizers action \u003cbr\u003e11.48.5 Effect of plasticizers on polymers and other additives \u003cbr\u003e11.48.6 Typical formulations \u003cbr\u003e11.49 Polyvinylacetate \u003cbr\u003e11.49.1 Frequently used plasticizers \u003cbr\u003e11.49.2 Practical concentrations \u003cbr\u003e11.49.3 Main functions performed by plasticizers \u003cbr\u003e11.49.4 Effect of plasticizers on polymer and other additives \u003cbr\u003e11.50 Polyvinylalcohol \u003cbr\u003e11.50.1 Frequently used plasticizers \u003cbr\u003e11.50.2 Practical concentrations \u003cbr\u003e11.50.3 Main functions performed by plasticizers \u003cbr\u003e11.50.4 Mechanism of plasticizer action \u003cbr\u003e11.50.5 Effect of plasticizers on polymer and other additives \u003cbr\u003e11.50.6 Typical formulations \u003cbr\u003e11.51 Polyvinylbutyral \u003cbr\u003e11.51.1 Frequently used plasticizers \u003cbr\u003e11.51.2 Practical concentrations \u003cbr\u003e11.51.3 Main functions performed by plasticizers \u003cbr\u003e11.51.4 Effect of plasticizers on polymer and other additives \u003cbr\u003e11.52 Polyvinylchloride \u003cbr\u003e11.52.1 Frequently used plasticizers \u003cbr\u003e11.52.2 Practical concentrations \u003cbr\u003e11.52.3 Main functions performed by plasticizers \u003cbr\u003e11.52.4 Mechanism of plasticizer action \u003cbr\u003e11.52.5 Effect of plasticizers on polymer and other additives \u003cbr\u003e11.52.6 Typical formulations \u003cbr\u003e11.53 Polyvinylfluoride \u003cbr\u003e11.54 Polyvinylidenefluoride \u003cbr\u003e11.54.1 Frequently used plasticizers \u003cbr\u003e11.54.2 Practical concentrations \u003cbr\u003e11.54.3 Main functions performed by plasticizers \u003cbr\u003e11.54.4 Effect of plasticizers on polymer and other additives \u003cbr\u003e11.55 Polyvinylidenechloride \u003cbr\u003e11.56 Proteins \u003cbr\u003e11.56.1 Frequently used plasticizers \u003cbr\u003e11.56.2 Practical concentrations \u003cbr\u003e11.56.3 Main functions performed by plasticizers \u003cbr\u003e11.56.4 Mechanism of plasticizer action \u003cbr\u003e11.56.5 Effect of plasticizers on polymer and other additives \u003cbr\u003e11.57 Rubber, natural \u003cbr\u003e11.57.1 Frequently used plasticizers \u003cbr\u003e11.57.2 Practical concentrations \u003cbr\u003e11.57.3 Main functions performed by plasticizers \u003cbr\u003e11.57.4 Effect of plasticizers on polymer and other additives \u003cbr\u003e11.57.5 Typical formulations \u003cbr\u003e11.58 Silicone \u003cbr\u003e11.58.1 Frequently used plasticizers \u003cbr\u003e11.58.2 Practical concentrations \u003cbr\u003e11.58.3 Main functions performed by plasticizers \u003cbr\u003e11.58.4 Effect of plasticizers on polymer and other additives \u003cbr\u003e11.58.5 Typical formulations \u003cbr\u003e11.59 Styrene-butadiene rubber \u003cbr\u003e11.59.1 Frequently used plasticizers \u003cbr\u003e11.59.2 Practical concentrations \u003cbr\u003e11.59.3 Effect of plasticizers on polymer and other additives \u003cbr\u003e11.59.4 Typical formulations \u003cbr\u003e11.60 Styrene-butadiene-styrene rubber \u003cbr\u003e11.60.1 Frequently used plasticizers \u003cbr\u003e11.60.2 Practical concentrations \u003cbr\u003e11.60.3 Main functions performed by plasticizers \u003cbr\u003e11.60.4 Effect of plasticizer on polymer and other additives \u003cbr\u003e11.61 Starch \u003cbr\u003e11.61.1 Frequently used plasticizers \u003cbr\u003e11.61.2 Practical concentrations \u003cbr\u003e11.61.3 Main functions performed by plasticizers \u003cbr\u003e11.61.4 Effect of plasticizers on polymer and other additives \u003cbr\u003e11.61.5 Typical formulations\u003cbr\u003e \u003cbr\u003e\u003cstrong\u003e12 PLASTICIZERS IN POLYMER BLENDS\u003c\/strong\u003e \u003cbr\u003e George Wypych\u003cbr\u003e12.1 Plasticizer partition between component polymers \u003cbr\u003e12.2 Interaction of plasticizers with blend components \u003cbr\u003e12.3 Effect of plasticizers on blend properties \u003cbr\u003e12.4 Blending to reduce or to replace plasticizers \u003cbr\u003e\u003cbr\u003e\u003cbr\u003e\u003cstrong\u003e13 PLASTICIZERS IN VARIOUS INDUSTRIAL PRODUCTS\u003c\/strong\u003e \u003cbr\u003e George Wypych\u003cbr\u003e13.1 Adhesives and sealants \u003cbr\u003e13.1.1 Plasticizer types \u003cbr\u003e13.1.2 Plasticizer concentration \u003cbr\u003e13.1.3 Reasons for plasticizer use \u003cbr\u003e13.1.4 Advantages and disadvantages of plasticizers use \u003cbr\u003e13.1.5 Effect of plasticizers on product properties \u003cbr\u003e13.1.6 Examples of formulations \u003cbr\u003e13.2 Aerospace \u003cbr\u003e13.3 Agriculture \u003cbr\u003e13.4 Automotive \u003cbr\u003e13.4.1 Plasticizer types \u003cbr\u003e13.4.2 Plasticizer concentration \u003cbr\u003e13.4.3 Reasons for plasticizer use \u003cbr\u003e13.4.4 Advantages and disadvantages of plasticizers use \u003cbr\u003e13.4.5 Effect of plasticizers on product properties \u003cbr\u003e13.5 Cementitious materials \u003cbr\u003e13.5.1 Plasticizer types \u003cbr\u003e13.5.2 Plasticizer concentration \u003cbr\u003e13.5.3 Reasons for plasticizer use \u003cbr\u003e13.5.4 Advantages and disadvantages of plasticizers use \u003cbr\u003e13.5.5 Effect of plasticizers on product properties \u003cbr\u003e13.5.6 Examples of formulations \u003cbr\u003e13.6 Coated fabrics \u003cbr\u003e13.6.1 Plasticizer types \u003cbr\u003e13.6.2 Plasticizer concentration \u003cbr\u003e13.6.3 Reasons for plasticizer use \u003cbr\u003e13.6.4 Advantages and disadvantages of plasticizers use \u003cbr\u003e13.6.5 Effect of plasticizers on product properties \u003cbr\u003e13.6.6 Examples of formulations \u003cbr\u003e13.7 Composites \u003cbr\u003e13.7.1 Plasticizer types \u003cbr\u003e13.7.2 Plasticizer concentrations \u003cbr\u003e13.7.3 Reasons for addition \u003cbr\u003e13.7.4 Effect of plasticizers on product properties \u003cbr\u003e13.8 Cosmetics \u003cbr\u003e13.8.1 Plasticizer types \u003cbr\u003e13.8.2 Plasticizer concentration \u003cbr\u003e13.8.3 Reasons for plasticizer use \u003cbr\u003e13.8.4 Advantages and disadvantages of plasticizers use \u003cbr\u003e13.8.5 Effect of plasticizers on product properties \u003cbr\u003e13.8.6 Examples of formulations \u003cbr\u003e13.9 Cultural heritage \u003cbr\u003e13.10 Dental materials \u003cbr\u003e13.10.1 Plasticizer types \u003cbr\u003e13.10.2 Plasticizer concentration \u003cbr\u003e13.10.3 Reasons for plasticizer use \u003cbr\u003e13.10.4 Advantages and disadvantages of plasticizers use \u003cbr\u003e13.11 Electrical and electronics \u003cbr\u003e13.11.1 Plasticizer types \u003cbr\u003e13.11.2 Plasticizer concentration \u003cbr\u003e13.11.3 Reasons for plasticizer use \u003cbr\u003e13.11.4 Advantages and disadvantages of plasticizers use \u003cbr\u003e13.11.5 Effect of plasticizers on product properties \u003cbr\u003e13.12 Fibers \u003cbr\u003e13.12.1 Plasticizer types \u003cbr\u003e13.12.2 Plasticizer concentration \u003cbr\u003e13.12.3 Reasons for plasticizer use \u003cbr\u003e13.12.4 Effect of plasticizers on product properties \u003cbr\u003e13.13 Film \u003cbr\u003e13.13.1 Plasticizer types \u003cbr\u003e13.13.2 Plasticizer concentration \u003cbr\u003e13.13.3 Reasons for plasticizer use \u003cbr\u003e13.13.4 Advantages and disadvantages of plasticizers use \u003cbr\u003e13.13.5 Effect of plasticizers on product properties \u003cbr\u003e13.14 Food \u003cbr\u003e13.14.1 Plasticizer types \u003cbr\u003e13.14.2 Plasticizer concentration \u003cbr\u003e13.14.3 Reasons for plasticizer use \u003cbr\u003e13.14.4 Advantages and disadvantages of plasticizers use \u003cbr\u003e13.14.5 Effect of plasticizers on product properties \u003cbr\u003e13.15 Flooring \u003cbr\u003e13.15.1 Plasticizer types \u003cbr\u003e13.15.2 Plasticizer concentration \u003cbr\u003e13.15.3 Reasons for plasticizer use \u003cbr\u003e13.15.4 Advantages and disadvantages of plasticizers use \u003cbr\u003e13.15.5 Effect of plasticizers on product properties \u003cbr\u003e13.15.6 Examples of formulations \u003cbr\u003e13.16 Foams \u003cbr\u003e13.16.1 Plasticizer types \u003cbr\u003e13.16.2 Plasticizer concentration \u003cbr\u003e13.16.3 Reasons for plasticizer use \u003cbr\u003e13.16.4 Advantages and disadvantages of plasticizers use \u003cbr\u003e13.16.5 Effect of plasticizers on product properties \u003cbr\u003e13.16.6 Examples of formulations \u003cbr\u003e13.17 Footwear \u003cbr\u003e13.17.1 Plasticizer types \u003cbr\u003e13.17.2 Plasticizer concentration \u003cbr\u003e13.17.3 Reasons for plasticizer use \u003cbr\u003e13.17.4 Advantages and disadvantages of plasticizers use \u003cbr\u003e13.17.5 Example of formulation \u003cbr\u003e13.18 Fuel cells \u003cbr\u003e13.18.1 Plasticizer types \u003cbr\u003e13.18.2 Plasticizer concentration \u003cbr\u003e13.18.3 Reasons for plasticizer use \u003cbr\u003e13.19 Gaskets \u003cbr\u003e13.19.1 Plasticizer types \u003cbr\u003e13.19.2 Plasticizer concentration \u003cbr\u003e13.19.3 Reasons for plasticizer use \u003cbr\u003e13.19.4 Advantages and disadvantages of plasticizers use \u003cbr\u003e13.19.5 Examples of formulations \u003cbr\u003e13.20 Household products \u003cbr\u003e13.21 Inks, varnishes, and lacquers \u003cbr\u003e13.21.1 Plasticizer types \u003cbr\u003e13.21.2 Plasticizer concentration \u003cbr\u003e13.21.3 Reasons for plasticizer use \u003cbr\u003e13.21.4 Advantages and disadvantages of plasticizers use \u003cbr\u003e13.21.5 Effect of plasticizers on product properties \u003cbr\u003e13.21.6 Examples of formulations \u003cbr\u003e13.22 Medical applications \u003cbr\u003e13.22.1 Plasticizer types \u003cbr\u003e13.22.2 Plasticizer concentration \u003cbr\u003e13.22.3 Reasons for plasticizer use \u003cbr\u003e13.22.4 Advantages and disadvantages of plasticizers use \u003cbr\u003e13.22.5 Effect of plasticizers on product properties \u003cbr\u003e13.22.6 Examples of formulations \u003cbr\u003e13.23 Membranes \u003cbr\u003e13.23.1 Plasticizer types \u003cbr\u003e13.23.2 Plasticizer concentration \u003cbr\u003e13.23.3 Reasons for plasticizer use \u003cbr\u003e13.23.4 Advantages and disadvantages of plasticizers use \u003cbr\u003e13.24 Microspheres \u003cbr\u003e13.24.1 Plasticizer types \u003cbr\u003e13.24.2 Plasticizer concentration \u003cbr\u003e13.24.3 Reasons for plasticizer use \u003cbr\u003e13.25 Paints and coatings \u003cbr\u003e13.25.1 Plasticizer types \u003cbr\u003e13.25.2 Plasticizer concentration \u003cbr\u003e13.25.3 Reasons for plasticizer use \u003cbr\u003e13.25.4 Advantages and disadvantages of plasticizers use \u003cbr\u003e13.25.5 Effect of plasticizers on product properties \u003cbr\u003e13.25.6 Examples of formulations \u003cbr\u003e13.26 Pharmaceutical products \u003cbr\u003e13.26.1 Plasticizer types \u003cbr\u003e13.26.2 Plasticizer concentration \u003cbr\u003e13.26.3 Reasons for plasticizer use \u003cbr\u003e13.26.4 Advantages and disadvantages of plasticizers use \u003cbr\u003e13.26.5 Effect of plasticizers on product properties \u003cbr\u003e13.26.6 Examples of formulations \u003cbr\u003e13.27 Photographic materials \u003cbr\u003e13.27.1 Plasticizer types \u003cbr\u003e13.27.2 Plasticizer concentration \u003cbr\u003e13.27.3 Reasons for plasticizer use \u003cbr\u003e13.27.4 Effect of plasticizers on product properties \u003cbr\u003e13.28 Pipes \u003cbr\u003e13.28.1 Plasticizer types \u003cbr\u003e13.28.2 Plasticizer concentration \u003cbr\u003e13.28.3 Reasons for plasticizer use \u003cbr\u003e13.28.4 Advantages and disadvantages of plasticizers use \u003cbr\u003e13.28.5 Effect of plasticizers on product properties \u003cbr\u003e13.28.6 Examples of formulations \u003cbr\u003e13.29 Roofing materials \u003cbr\u003e13.29.1 Plasticizer types \u003cbr\u003e13.29.2 Plasticizer concentration \u003cbr\u003e13.29.3 Reasons for plasticizer use \u003cbr\u003e13.29.4 Advantages and disadvantages of plasticizers use \u003cbr\u003e13.29.5 Effect of plasticizers on product properties \u003cbr\u003e13.29.6 Examples of formulations \u003cbr\u003e13.30 Tires \u003cbr\u003e13.30.1 Plasticizer types \u003cbr\u003e13.30.2 Plasticizer concentration \u003cbr\u003e13.30.3 Reasons for plasticizer use \u003cbr\u003e13.30.4 Advantages and disadvantages of plasticizers use \u003cbr\u003e13.30.5 Effect of plasticizers on product properties \u003cbr\u003e13.30.6 Examples of formulations \u003cbr\u003e13.31 Toys \u003cbr\u003e13.31.1 Plasticizer types \u003cbr\u003e13.31.2 Plasticizer concentration \u003cbr\u003e13.31.3 Reasons for plasticizer use \u003cbr\u003e13.31.4 Effect of plasticizers on product properties \u003cbr\u003e13.32 Tubing \u003cbr\u003e13.32.1 Plasticizer types \u003cbr\u003e13.32.2 Plasticizer concentration \u003cbr\u003e13.32.3 Reasons for plasticizer use \u003cbr\u003e13.32.4 Advantages and disadvantages of plasticizers use \u003cbr\u003e13.32.5 Effect of plasticizers on product properties \u003cbr\u003e13.32.6 Examples of formulations \u003cbr\u003e13.33 Wire and cable \u003cbr\u003e13.33.1 Plasticizer types \u003cbr\u003e13.33.2 Plasticizer concentration \u003cbr\u003e13.33.3 Reasons for plasticizer use \u003cbr\u003e13.33.4 Advantages and disadvantages of plasticizers use \u003cbr\u003e13.33.5 Effect of plasticizers on product properties \u003cbr\u003e13.33.6 Examples of formulations \u003cbr\u003e\u003cbr\u003e\u003cstrong\u003e14 PLASTICIZERS IN VARIOUS PROCESSING METHODS\u003c\/strong\u003e \u003cbr\u003e George Wypych\u003cbr\u003e14.1 Blow molding \u003cbr\u003e14.2 Calendering \u003cbr\u003e14.3 Coil coating \u003cbr\u003e14.4 Compression molding \u003cbr\u003e14.5 Compounding (mixing) \u003cbr\u003e14.6 Dip coating \u003cbr\u003e14.7 Dry blending \u003cbr\u003e14.8 Extrusion \u003cbr\u003e14.9 Injection molding \u003cbr\u003e14.10 Polymer synthesis \u003cbr\u003e14.11 Rotational molding \u003cbr\u003e14.12 Rubber processing \u003cbr\u003e14.13 Thermoforming \u003cbr\u003e14.14 Web coating \u003cbr\u003e14.15 Wire coating \u003cbr\u003e\u003cbr\u003e\u003cstrong\u003e15 SPECIALIZED ANALYTICAL METHODS IN PLASTICIZER TESTING\u003c\/strong\u003e \u003cbr\u003e George Wypych\u003cbr\u003e15.1 Plasticizer identification \u003cbr\u003e15.2 Methods of determination of plasticizer concentration \u003cbr\u003e15.3 Determination of volatility, molecular motion, diffusion, and migration \u003cbr\u003e15.4 Methods of study of plasticized materials \u003cbr\u003e\u003cbr\u003e\u003cstrong\u003e16 MATHEMATICAL MODELING IN APPLICATION TO PLASTICIZERS\u003c\/strong\u003e \u003cbr\u003e George Wypych\u003cbr\u003e16.1 PVC-plasticizer interaction model \u003cbr\u003e16.2 Gas permeation \u003cbr\u003e16.3 Migration \u003cbr\u003e16.4 Dry-blending time \u003cbr\u003e16.5 Gelation and fusion \u003cbr\u003e16.6 Thermal decomposition \u003cbr\u003e16.7 Potential health risk of exposure to DEHP from glove \u003cbr\u003e\u003cbr\u003e\u003cstrong\u003e17 HEALTH AND SAFETY ISSUES WITH PLASTICIZERS AND PLASTICIZED\u003c\/strong\u003e\u003cbr\u003e\u003cstrong\u003e MATERIALS\u003c\/strong\u003e \u003cbr\u003e17.1 Adjuvant effect of plasticizers \u003cbr\u003e Søren Thor Larsen \u003cbr\u003e17.1.1 Introduction \u003cbr\u003e17.1.2 Airway allergy \u003cbr\u003e17.1.3 Adjuvant effect \u003cbr\u003e17.1.4 Adjuvant effect of phthalate plasticizers \u003cbr\u003e 17.1.4.1 Epidemiological studies \u003cbr\u003e17.1.4.2 In vivo (animal) studies \u003cbr\u003e17.1.5 Conclusions \u003cbr\u003e17.2 The rodent hepatocarcinogenic response to phthalate plasticizers\u003cbr\u003e : basic biology and human extrapolation \u003cbr\u003e Abigail L Walker and Ruth A Roberts\u003cbr\u003e17.2.1 Introduction \u003cbr\u003e17.2.2 Gene expression and cancer toxicology \u003cbr\u003e17.2.2.1 Gene expression \u003cbr\u003e17.2.2.2 Cancer biology: some basic considerations \u003cbr\u003e17.2.2.3 Developing areas of interest in hepatocarcinogenesis \u003cbr\u003e17.2.2.4 Chemical carcinogenesis \u003cbr\u003e17.2.3 Peroxisome proliferators and rodent nongenotoxic\u003cbr\u003e hepatocarcinogenesis \u003cbr\u003e17.2.3.1 The peroxisome proliferators \u003cbr\u003e17.2.3.2 PPAR \u003cbr\u003e17.2.4 Species differences in response to peroxisome proliferators \u003cbr\u003e17.2.5 Chemical regulation \u003cbr\u003e17.2.5.1 Challenges in alternative models \u003cbr\u003e17.2.6 Summary \u003cbr\u003e17.3 The influence of maternal nutrition on phthalate teratogenicity \u003cbr\u003e Janet Y. Uriu-Adams1 and Carl L. Keen\u003cbr\u003e17.3.1 Introduction \u003cbr\u003e17.3.2 Reproductive toxicity of BBP and DEHP \u003cbr\u003e17.3.3 Acute phase response-induced alterations in maternal \u003cbr\u003e17.3.4 Concluding comments \u003cbr\u003e17.3.5 Recent findings \u003cbr\u003e17.3.6 Acknowledgments \u003cbr\u003e17.4 Public health implications of phthalates: A review of U.S. actions\u003cbr\u003e to protect those most vulnerable \u003cbr\u003e Stephanie R. Miles-Richardson and Dhara Richardson\u003cbr\u003e17.4.1 Introduction \u003cbr\u003e17.4.2 Implications of the COVID-19 pandemic on phthalate exposure \u003cbr\u003e17.4.3 The U.S. response to phthalate exposure \u003cbr\u003e17.4.3 Some U.S. State-level actions \u003cbr\u003e17.4.4 2008 Consumer Product Safety Improvement Act \u003cbr\u003e17.4.5 Food and Drug Administration (FDA) petition, lawsuit, and final ruling \u003cbr\u003e17.4.6 Preventing Harmful Exposure to Phthalates Act 117th Congress\u003cbr\u003e (2021-2022) \u003cbr\u003e17.4.7 Other U.S. Federal Agencies \u003cbr\u003e17.4.8 Conclusion \u003cbr\u003e17.5 Plasticizers in the indoor environment \u003cbr\u003e Werner Butte\u003cbr\u003e17.5.1 Introduction \u003cbr\u003e17.5.2 Sources of indoor plasticizers \u003cbr\u003e17.5.3 Occurrence of plasticizers indoors \u003cbr\u003e17.5.3.1 Indoor air \u003cbr\u003e17.5.3.2 House dust \u003cbr\u003e17.5.4 Impact of plasticizers in the indoor environment \u003cbr\u003e17.5.4.1 Indoor plasticizers and health \u003cbr\u003e17.5.4.2 Human exposure assessment for plasticizers in the indoor\u003cbr\u003e environment \u003cbr\u003e17.5.4.3 Reference and guideline values of plasticizers to assess indoor\u003cbr\u003e quality \u003cbr\u003e17.5.5 Summary \u003cbr\u003e\u003cbr\u003e\u003cstrong\u003e18 THE ENVIRONMENTAL FATE OF PLASTICIZERS\u003c\/strong\u003e \u003cbr\u003e William R. Roy\u003cbr\u003e18.1 Introduction \u003cbr\u003e18.1.1 Releases to the environment \u003cbr\u003e18.1.2 Levels in the environment \u003cbr\u003e18.2 Plasticizers in water \u003cbr\u003e18.2.1 Solubility \u003cbr\u003e18.2.2 Volatilization from water. \u003cbr\u003e18.2.3 Abiotic degradation in water \u003cbr\u003e18.2.4 Biodegradation in water \u003cbr\u003e18.2.5 Adsorption from water \u003cbr\u003e18.3 Soil and sediment \u003cbr\u003e18.3.1 Volatilization \u003cbr\u003e18.3.2 Biodegradation in soil \u003cbr\u003e18.4 Organisms \u003cbr\u003e18.5 Air \u003cbr\u003e Summary and concluding remarks \u003cbr\u003e\u003cbr\u003e\u003cstrong\u003e19 REGULATIONS AND DATA\u003c\/strong\u003e \u003cbr\u003e George Wypych\u003cbr\u003e19.1 Toxic substance control \u003cbr\u003e19.2. Carcinogenic effect \u003cbr\u003e19.3 Teratogenic and mutagenic effect \u003cbr\u003e19.4 Workplace exposure limits \u003cbr\u003e19.5 Exposure from consumer products \u003cbr\u003e19.6 Plasticizers in drinking water \u003cbr\u003e19.7 Food regulatory acts \u003cbr\u003e19.8 Medical and other applications \u003cbr\u003e\u003cbr\u003e\u003cbr\u003e\u003cstrong\u003e20 PERSONAL PROTECTION\u003c\/strong\u003e \u003cbr\u003e George Wypych\u003cbr\u003e20.1 Clothing \u003cbr\u003e20.2 Gloves \u003cbr\u003e20.3 Eye protection \u003cbr\u003e20.4 Respiratory protection \u003cbr\u003e\u003cbr\u003e\u003cstrong\u003e21 PLASTICIZER RECOVERY \u0026amp; RECYCLING\u003c\/strong\u003e \u003cbr\u003e George Wypych\u003cbr\u003e\u003cbr\u003e \u003cstrong\u003eINDEX\u003c\/strong\u003e\u003cbr\u003e\u003c\/p\u003e\n\u003cp\u003e \u003c\/p\u003e\n\u003ch5\u003eAbout Author\u003c\/h5\u003e\nGeorge Wypych has PhD Eng. The professional expertise includes university teaching (full professor) and research \u0026amp; development (university and corporate). He has published 48 books (PVC Plastisols, Wroclaw University Press; Polyvinylchloride Degradation, Elsevier; Polyvinylchloride Stabilization, Elsevier; Polymer Modified Textile Materials, Wiley \u0026amp; Sons; Handbook of Material Weathering, 1st, 2nd, 3rd, 4th, 5th, 6th Edition, ChemTec Publishing; Handbook of Fillers, 1st, 2nd, 3rd, 4th, and 5th Edition, ChemTec Publishing; Recycling of PVC, ChemTec Publishing; Weathering of Plastics. Testing to Mirror Real Life Performance, Plastics Design Library, Handbook of Solvents, Vol. 1. Properties 1st, 2nd, and 3rd Edition, ChemTec Publishing, Handbook of Solvents, Vol. 2. Health \u0026amp; Environment 1st, 2nd, and 3rd Edition, ChemTec Publishing, Handbook of Plasticizers, 1st, 2nd, 3rd, 4th Edition, ChemTec Publishing, Handbook of Antistatics, 1st and 2nd Edition, ChemTec Publishing, Databook of Antistatics, 1st and 2nd Edition, ChemTec Publishing, Handbook of Antiblocking, Release and Slip Additives, 1st , 2nd and 3rd Edition, ChemTec Publishing, Industrial Solvents in Kirk-Othmer Encyclopedia of Chemical Technology (two editions), John Wiley \u0026amp; Sons, PVC Degradation \u0026amp; Stabilization, 1st, 2nd, 3rd, and 4th Editions, ChemTec Publishing, The PVC Formulary, 1st, 2nd, and 3rd Editions, ChemTec Publishing, Handbook of Material Biodegradation, Biodeterioration, and Biostabilization, 1st and 2nd Editions, ChemTec Publishing, Handbook of UV Degradation and Stabilization, 1st, 2nd, and 3rd Editions, ChemTec Publishing, Handbook of Polymers, 1st, 2nd, and 3rd Editions, ChemTec Publishing, Atlas of Material Damage, 1st, 2nd, and 3rd Editions, ChemTec Publishing, Handbook of Odors in Plastic Materials, 1st, 2nd, and 3rd Editions, ChemTec Publishing, Databook of Solvents (two editions), ChemTec Publishing, Databook of Blowing and Auxiliary Agents, ChemTec Publishing, Handbook of Foaming and Blowing Agents (two editions), ChemTec Publishing, Databook of Green Solvents, ChemTec Publishing (two editions), Self-healing Products (two editions), ChemTec Publishing, Handbook of Adhesion Promoters (two editions), ChemTec Publishing, Databook of Surface Modification Additives (two editions), ChemTec Publishing, Handbook of Surface Improvement and Modification (two editions), ChemTec Publishing, Graphene – Important Results and Applications, ChemTec Publishing, Handbook of Curatives and Crosslinkers, ChemTec Publishing, Chain Mobility and Progress in Medicine, Pharmaceutical, Polymer Science and Technology, Impact of Award, ChemTec Publishing, Databook of Antioxidants, ChemTec Publishing, Handbook of Antioxidants, ChemTec Publishing, Databook of UV Stabilizers (two Editions), ChemTec Publishing, Databook of Flame Retardants, ChemTec Publishing, Databook of Nucleating Agents, ChemTec Publishing, Handbook of Flame Retardants, ChemTec Publishing, Handbook of Nucleating Agents, ChemTec Publishing, Handbook of Polymers in Electronics, ChemTec Publishing, Databook of Impact Modifiers, ChemTec Publishing, Databook of Rheological Additives, ChemTec Publishing, Handbook of Impact Modifiers, ChemTec Publishing, Handbook of Rheological Additives, ChemTec Publishing, Databook of Polymer Processing Additives, ChemTec Publishing, Handbook of Polymer Processing Additives, ChemTec Publishing, Functional Fillers (two editions), 2 databases (Solvents Database, 1st, 2nd, 3rd Edition and Database of Antistatics 1st and 2nd Edition, both by ChemTec Publishing), and 42 scientific papers and obtained 16 patents. He specializes in PVC, polymer additives, material durability, and the development of sealants and coatings. He was included in the Dictionary of International Biography, Who's Who in Plastics and Polymers, and Who's Who in Engineering, and was selected International Man of the Year 1996-1997 in recognition of services to education."}