Shape Memory Polymers: Fundamentals, Advances and Applications

Author: Jinlian Hu, The Hong Kong Polytechnic University
ISBN 9781909030329

Published: 2014
Pages:308

$205.00

Summary
Table of Contents

Shape-memory polymers (SMP) are a unique branch of the smart materials family which are capable of changing shape on-demand upon exposure to the external stimulus. The discovery of SMP made a significant breakthrough in the developments of novel smart materials for a variety of engineering applications, superseded the traditional materials, and also influenced the current methods of product designing.

This book provides the latest advanced information on on-going research domains of SMP. This will certainly enlighten the reader to the achievements and tremendous potentials of SMP.

The basic fundamentals of SMP, including shape-memory mechanisms and mechanics, are described. This will aid the reader to become more familiar with SMP and the basic concepts, thus guiding them in undergoing independent research in the SMP field.

The book also provides the reader with associated challenges and existing application problems of SMP. This could assist the reader to focus more on these issues and further exploit their knowledge to look for innovative solutions. Future outlooks of SMP research are discussed as well.

This book should prove to be extremely useful for academics, R&D managers, researcher scientists, engineers, and all others related to the SMP research.

1 Shape-memory Polymers
1.1 Introduction
1.2 Shape-memory Effect
1.2.1 Shape-memory Effect in Shape-memory Polymers
1.2.2 Shape-memory Effect in Shape-memory Polymers and Shape-memory Alloys
1.3 Structure of Shape-memory Polymers
1.3.1 Thermally Induced Shape-memory Polymers
1.3.2 Athermal Shape-memory Polymers
1.4 Classification of Shape-memory Polymers
1.5 Conclusions

2 Shape-memory Polymers: Molecular Design, Shape-memory Functionality, and Programming
2.1 Introduction
2.2 Molecular Design of Shape-memory Polymers
2.2.1 Thermally Sensitive Shape-memory Polymers
2.2.1.1 Shape-memory Polymers based on the
Amorphous Phase
2.2.1.2 Shape-memory Polymers based on Semi-crystalline Phase
2.2.1.3 Shape-memory Polymers based on Liquid Crystalline Phase
2.2.2. Photosensitive Shape-memory Polymers
2.2.3. Other Molecular Architectures of Shape-memory Polymers
2.3 Shape-memory Programming
2.3.1 Processing One-way Shape-memory Effects
2.3.1.1 Dual-shape Creation Process for One-way Dual-shape Shape-memory Effects
2.3.1.2 Programming for One-way Triple-shape Shape-memory Effects
2.3.2 Processing One-way Shape-memory Effects
2.3.2.1 Programming for Two-way Dual-shape Shape-memory Effects
2.3.2.2 Programming for Two-way Triple-shape Shape-memory Effects

2.3.3 Multiple Shape-memory Effects Programming

2.4 Shape-memory Functionality

2.4.1 One-way Shape-memory Effects

2.4.2 Two-way Shape-memory Effects

2.4.2.1 Liquid Crystalline Elastomers

2.4.2.2 Shape-memory Polymers having a
Semi-crystalline Phase under Constant Stress
2.4.3 One-way Shape-memory Effects
2.4 Shape-memory Functionality
2.4.2.3 Shape-memory Polymer Laminated Composites
2.4.3 Triple/Multiple Shape-memory Effects
2.4.4 Temperature-memory Effects

2.5 Conclusions

3 Shape-memory Polymer Composites
3.1 Introduction
3.2 Nanowhisker/Shape-memory Polymer Composites
3.2.1 Cellulose Nanowhiskers
3.2.2 Integration of Cellulose Nanowhiskers
3.3 Carbon/Shape-memory Polymer Composites
3.3.1 Carbon Nanotube and Carbon Nanofibre/Shape-memory Polymer Composites
3.3.2 Carbon Black/Shape-memory Polymer Composites
3.3.3 Electrically Sensitive Shape-memory Polymer Nanocomposites
3.3.4 Light-sensitive Shape-memory Polymer Nanocomposites
3.3.5 Enhanced General Shape-memory Effect
3.4 Fibre/Fabric-reinforced Shape-memory Polymer Composites
3.4.1 Microfibre or Fabric/Shape-memory Polymer Composites
3.4.2 Electrospun Nanofibre Shape-memory Polymer Nanocomposites
3.5 Metal and Metal Oxides/Shape-memory Polymer Composites
3.6 Other Shape-memory Polymer Composites
3.6.1 Nanoclay/Shape-memory Polymer Composites
3.6.2 Other Inorganic Filler/Shape-memory Polymer Composites
3.6.3 Organic Filler/Shape-memory Polymer Composites
3.6.4 Shape-memory Polymer Composites with Special Function
3.7 Conclusions

4 Shape-memory Polymer Blends
4.1 Introduction
4.2 Miscible Polymer Blends
4.2.1 Shape-memory Polymer/Polymer Blends
4.2.2 Amorphous Polymer/Crystalline Polymer Blends
4.3 Immiscible Polymer Blends
4.3.1 Elastomer/Polymer Blends
4.3.2 Other Types of Immiscible Blends
4.4 Blending and Post-crosslinking Polymers Networks
4.4.1 Interpenetrating Polymer Networks
4.4.2 Crosslinked Polymer Blends.
4.5 Conclusions

5 Shape-memory Polymers Sensitive to Different Stimuli
5.1 Introduction
5.2 Thermally sensitive Shape-memory Polymers
5.2.1 Shape-memory Effect based on Conventional Glass or Melting Transition
5.2.2 Shape-memory Effect by Indirect Heating
5.2.3 Shape-memory Effect based on a Thermally Reversible Reaction
5.2.4 Shape-memory Effect based on Supermolecular Structure
5.2.5 Two-way Shape-memory Effect based on Change in the Conformation of Anisotropic Chains
5.2.6 Two-way Shape-memory Effect based on Cooling-induced Crystallisation Elongation
5.2.7 Two-way Shape-memory Effect based on Shape-memory Polymer/Carbon Nanotube Composites
5.2.8 Multiple Shape-memory Effect based on Combined Switches
5.2.9 Thermally active and pH-active Polymeric Hydrogels
5.3 Light-sensitive Shape-memory Polymers
5.3.1 Photodeformability Induced by Photoisomerisation
5.3.2 Photodeformability induced by Photoreactive Molecules
5.3.3 Photoactive Effect from the Addition–fragmentation Chain Transfer Reaction
5.3.4 Light-active Polymeric Hydrogels
5.4 Magnetic-sensitive Shape-memory Polymers
5.4.1 Shape-memory Polymer Matrices filled with Magnetic Particles
5.4.2 Magnetic-active polymeric gels
5.5 Water/solvent-sensitive Shape-memory Polymers
5.6 Electric-sensitive Shape-memory Polymers
5.7 Conclusions

6 Modelling of Shape-memory Polymers
6.1 Introduction
6.2 Macroscale Constitutive Modelling
6.2.1 Stress–strain Characteristics
6.2.2 Shape-memory Properties
6.3 Mesoscale Modelling
6.4 Microscale Modelling
6.5 Molecular Dynamics and Monte Carlo Simulations
6.5.1 Reaction Characteristics
6.5.2 Physical Properties
6.5.3 Microstructure
6.5.4 Hydrogen bonding Interactions
6.5.5 Mechanical Properties
6.6 Mathematical Modelling
6.7 Modelling of Device Structures
6.8 Modelling of Light-sensitive Shape-memory Polymers
6.8.1 Three-dimensional Finite Deformation Modelling
6.8.2 Multiple Natural Configurations Modelling
6.8.3 Multi-scale Modelling
6.9 Conclusions

7 Supramolecular Shape-memory Polymers
7.1 Introduction
7.2 Supramolecular Chemistry
7.2.1 Hydrogen Bonding
7.2.2 Relationship between Shape-memory Polymers and Supramolecular Polymer Networks
7.3 Polymers Containing Pyridine Moieties: a Pathway to Achieve Supramolecular Networks
7.3.1 Function of Pyridine Moieties in Supramolecular Chemistry
7.3.2 Supramolecular Pyridine-containing Polymers
7.3.3 Supramolecular Liquid Crystalline Polymer-containing Pyridine Moieties
7.4 Supramolecular Shape-memory Polymers based on Pyridine Moieties
7.4.1 Synthesis
7.4.2 Structure and Morphology
7.4.3 Thermally induced Shape-memory Effect
7.4.4 Moisture-sensitive Shape-memory Effect
7.5 Supramolecular Shape-memory Polymers based on Cyclodextrins
7.5.1 Cyclodextrins
7.5.2 Thermally induced Shape-memory Effect
7.5.3 Non-thermally Induced Shape-memory Effects
7.6 Potential Applications
7.6.1 Reshape Applications
7.6.2 Shape-memory Effect for Hairstyles in Beauty Care
7.6.3 Two-way Shape-memory Polymer Laminates
7.6.4 Medical Application: Antibacterial
7.6.5 Intelligent Windows for Smart Textile Applications
7.7 Conclusions

8 Applications of Shape-memory Polymers
8.1 Introduction
8.2 Applications of Bulk Shape-memory Polymers
8.2.1
8.2.2
Fixation
8.2.1.1 Orthodontic Wires
8.2.1.2 Medical Casts
Actuation
8.2.2.1 Actuation Realised by Combining Shape-memory Polymers with Specific Structures
8.2.2.2 Actuation arising from a Two-way Shape-memory Effect Deployment
8.2.3.1 Cold Hibernated Elastic Memory of Shape- memory Polymer Foams
8.2.3.2 Expandable Stents
8.2.3.3 Deployable Dialysis Needles, Coils, and Neuronal Electrodes
8.2.3
8.2.4
8.3.3 Adaptable Biological Devices for Modulating Cellular– substrate Interactions
8.3.4 Biosensor and Micro-systems
8.3.5 Programmable Surface Pattern
8.3.6 No-programming Reversible Shape-memory Surface Patterns
8.4 Applications in Textiles
8.4.1 Shape-memory Polymer Fibres
8.4.2 Shape-memory Polymer Yarns and Fabrics
8.4.3 Shape-memory Polymer Solutions for Finishing Fabrics
8.4.4 Shape-memory Polymer Nanofibres and their Nonwovens
8.4.5 Shape-memory Polymer Film/Foam and Laminated Textiles
8.5 Engineering Applications
8.5.1 Transportation
8.5.2 Sensors and Actuators
8.5.3 Filtration
Self-healing
8.2.4.1 Confined Shape-recovery Self-healing
8.2.5 Fitting
8.3 Applications in Surface Wrinkling and Patterning
8.3.1 Principe of Surface Wrinkling
8.3.2 Wetting and Spreading

9 Future
Outlook
9.1 Introduction
9.2 New Shape-memory Polymers with Novel Structures and Diversified Functionalities
9.2.1 New Stimulus Switches
9.2.2 Intrinsic Athermal Switches
9.2.3 Multi-responsive and Multi-functional Switches
9.3 Development Trends of Shape-memory Polymer Composites and Blends
9.3.1 Electric-Sensitive Shape-memory Effect
9.3.2 Light-Sensitive Shape-memory Effect
9.3.3 Magnetic-Sensitive Shape-memory Effect
9.3.4 Water/Solvent-Sensitive Shape-memory Effect
9.3.5 Shape-memory Effect based on Non-thermal Phase Transitions
9.4 Versatile Shape-memory Effects by Novel Programming Protocols
9.4.1 Programmability
9.4.2 Imperfection or a New Shape-memory Effect
9.5 Fundamental Understanding
9.6 Comprehensive Study of Structure-property Relationships
9.7 Modelling
9.8 Application in Textiles
9.9 Biomedical Applications
9.10 Applications toward Commercial Success
9.10.1 Maturing and Broadening of Applications.
9.10.1.1 Existing Widely Researched Areas
9.10.1.2 Broadening Areas
9.10.1.3 Untouched Areas
9.10.2 Integrated Approaches
9.10.3 Challenging Issues in Applications
9.11 Supramolecular Shape-memory Polymers
9.12 Conclusions
Abbreviations
Index

Related Products

Additive Migration fro...

$170.00

{"id":11242227908,"title":"Additive Migration from Plastics into Foods","handle":"978-1-84735-055-8","description":"\u003ch5\u003eDescription\u003c\/h5\u003e\nAuthor: T.R. Crompton \u003cbr\u003eISBN 978-1-84735-055-8 \u003cbr\u003e\u003cbr\u003e\u003cb\u003eA Guide for Analytical Chemists\u003cbr\u003e\u003c\/b\u003eSmithers Rapra Technology\u003cbr\u003e\u003cb\u003e\u003cbr\u003e\u003c\/b\u003eSoft-backed, 255 x 190 mm, 325 pages.\u003cb\u003e\u003cbr\u003e\u003c\/b\u003e\n\u003ch5\u003eSummary\u003c\/h5\u003e\nPlastics are now being used on a large scale for the packaging of fatty and aqueous foodstuffs and beverages, both alcoholic and non-alcoholic. This is evident for all to see on the supermarket shelves, margarine is packed in polystyrene tubs, beer is packed in PVC bottles and meats and bacon in shrink-wrap film. Foods are also increasingly being shipped in bulk, in plastic containers. Additionally, there is the area of use of plastics utensils, containers, and processing equipment in the home and during a bulk preparation of food in producing factories, at home and in restaurants and canteens. \u003cbr\u003e\u003cbr\u003eThus it is likely that some transfer of polymer additives will occur - adventitious impurities such as monomers, oligomers, catalyst remnants and residual polymerization solvents and low molecular weight polymer fractions - from the plastic into the packaged material with the consequent risk of a toxic hazard to the consumer. The actual hazard arising to the consumer from any extractable material is a function of two properties, namely, the intrinsic toxicity of the extracted material as evaluated in animal feeding trials (not dealt with in this book) and the amount of material extracted from the polymer which enters the packed commodity under service conditions, i.e., during packaging operations and during the shelf life of the packaged commodity at the time of the consumption. \u003cbr\u003e\u003cbr\u003eThis book covers all aspects of the migration of additives into food and gives detailed information on the analytical determination of the additives in various plastics. It will be of interest to those engaged in the implementation of packaging legislation, including management, analytical chemists and the manufacturers of foods, beverages, pharmaceuticals and cosmetics and also scientific and toxicologists in the packaging industry.\u003cbr\u003e\u003cbr\u003e\n\u003ch5\u003eTable of Contents\u003c\/h5\u003e\n1 Additive Migration from Plastics into Packaged Commodities \u003cbr\u003e2 Types of Polymers Used in Commodity Packaging \u003cbr\u003e3 Non-Polymeric Components of Plastics \u003cbr\u003e4 Determination of Antioxidants \u003cbr\u003e5 Determination of Ultraviolet Stabilisers in Extractants \u003cbr\u003e6 Determination of Plasticisers in Extractants \u003cbr\u003e7 Determination of Organotin Thermal Stabilisers in Extractants \u003cbr\u003e8 Determination of Organic Sulfur Compounds in Extractants \u003cbr\u003e9 Determination of Polydimethyl Siloxanes in Extractants \u003cbr\u003e10 Determination of Lubricants in Extraction Liquids \u003cbr\u003e11 Determination of Monomers and Oligomers in Extractants \u003cbr\u003e12 Analysis of Polymer Extraction Liquids Containing More Than One Migrant \u003cbr\u003e13 Determination of Additives and their Breakdown Products in Extractants \u003cbr\u003e14 Additive Migration Theory \u003cbr\u003e15 Gas Barrier Properties of Food Packaging Plastic Films \u003cbr\u003e16 Legislative Aspects of the Use of Additives in Packaging Plastics \u003cbr\u003e17 Direct Determination of Migrants from Polymers into Foodstuffs\u003cbr\u003e\u003cbr\u003e\n\u003ch5\u003eAbout Author\u003c\/h5\u003e\nRoy Crompton was Head of the polymer analysis research department of a major international polymer producer for some 15 years. In the early fifties, he was heavily engaged in the development of methods of analysis for low-pressure polyolefins produced by the Ziegler-Natta route, including work on high-density polyethylene and polypropylene. He was responsible for the development of methods of analysis of the organoaluminum catalysts used for the synthesis of these polymers. He was also responsible for the development of thin-layer chromatography for the determination of various types of additives in polymers and did pioneering work on the use of TLC to separate polymer additives and to examine the separated additives by infrared and mass spectrometry. He retired in 1988 and has since been engaged as a consultant in the field of analytical chemistry and has written extensively on this subject, with some 20 books published.","published_at":"2017-06-22T21:14:06-04:00","created_at":"2017-06-22T21:14:06-04:00","vendor":"Chemtec Publishing","type":"Book","tags":["2007","additive","antioxidants","book","determination","extractants","lubricants","migration","monomes","non-polymeric","oligomers","p-applications","packaging","plastic","plasticisers","plasticizers","plastics","polymer","polymers","stabilisers","sulfur compounds","ultraviolet"],"price":17000,"price_min":17000,"price_max":17000,"available":true,"price_varies":false,"compare_at_price":null,"compare_at_price_min":0,"compare_at_price_max":0,"compare_at_price_varies":false,"variants":[{"id":43378395844,"title":"Default Title","option1":"Default Title","option2":null,"option3":null,"sku":"","requires_shipping":true,"taxable":true,"featured_image":null,"available":true,"name":"Additive Migration from Plastics into Foods","public_title":null,"options":["Default Title"],"price":17000,"weight":1000,"compare_at_price":null,"inventory_quantity":0,"inventory_management":null,"inventory_policy":"continue","barcode":"978-1-84735-055-8","requires_selling_plan":false,"selling_plan_allocations":[]}],"images":["\/\/chemtec.org\/cdn\/shop\/products\/978-1-84735-055-8.jpg?v=1498185547"],"featured_image":"\/\/chemtec.org\/cdn\/shop\/products\/978-1-84735-055-8.jpg?v=1498185547","options":["Title"],"media":[{"alt":null,"id":350138663005,"position":1,"preview_image":{"aspect_ratio":0.767,"height":450,"width":345,"src":"\/\/chemtec.org\/cdn\/shop\/products\/978-1-84735-055-8.jpg?v=1498185547"},"aspect_ratio":0.767,"height":450,"media_type":"image","src":"\/\/chemtec.org\/cdn\/shop\/products\/978-1-84735-055-8.jpg?v=1498185547","width":345}],"requires_selling_plan":false,"selling_plan_groups":[],"content":"\u003ch5\u003eDescription\u003c\/h5\u003e\nAuthor: T.R. Crompton \u003cbr\u003eISBN 978-1-84735-055-8 \u003cbr\u003e\u003cbr\u003e\u003cb\u003eA Guide for Analytical Chemists\u003cbr\u003e\u003c\/b\u003eSmithers Rapra Technology\u003cbr\u003e\u003cb\u003e\u003cbr\u003e\u003c\/b\u003eSoft-backed, 255 x 190 mm, 325 pages.\u003cb\u003e\u003cbr\u003e\u003c\/b\u003e\n\u003ch5\u003eSummary\u003c\/h5\u003e\nPlastics are now being used on a large scale for the packaging of fatty and aqueous foodstuffs and beverages, both alcoholic and non-alcoholic. This is evident for all to see on the supermarket shelves, margarine is packed in polystyrene tubs, beer is packed in PVC bottles and meats and bacon in shrink-wrap film. Foods are also increasingly being shipped in bulk, in plastic containers. Additionally, there is the area of use of plastics utensils, containers, and processing equipment in the home and during a bulk preparation of food in producing factories, at home and in restaurants and canteens. \u003cbr\u003e\u003cbr\u003eThus it is likely that some transfer of polymer additives will occur - adventitious impurities such as monomers, oligomers, catalyst remnants and residual polymerization solvents and low molecular weight polymer fractions - from the plastic into the packaged material with the consequent risk of a toxic hazard to the consumer. The actual hazard arising to the consumer from any extractable material is a function of two properties, namely, the intrinsic toxicity of the extracted material as evaluated in animal feeding trials (not dealt with in this book) and the amount of material extracted from the polymer which enters the packed commodity under service conditions, i.e., during packaging operations and during the shelf life of the packaged commodity at the time of the consumption. \u003cbr\u003e\u003cbr\u003eThis book covers all aspects of the migration of additives into food and gives detailed information on the analytical determination of the additives in various plastics. It will be of interest to those engaged in the implementation of packaging legislation, including management, analytical chemists and the manufacturers of foods, beverages, pharmaceuticals and cosmetics and also scientific and toxicologists in the packaging industry.\u003cbr\u003e\u003cbr\u003e\n\u003ch5\u003eTable of Contents\u003c\/h5\u003e\n1 Additive Migration from Plastics into Packaged Commodities \u003cbr\u003e2 Types of Polymers Used in Commodity Packaging \u003cbr\u003e3 Non-Polymeric Components of Plastics \u003cbr\u003e4 Determination of Antioxidants \u003cbr\u003e5 Determination of Ultraviolet Stabilisers in Extractants \u003cbr\u003e6 Determination of Plasticisers in Extractants \u003cbr\u003e7 Determination of Organotin Thermal Stabilisers in Extractants \u003cbr\u003e8 Determination of Organic Sulfur Compounds in Extractants \u003cbr\u003e9 Determination of Polydimethyl Siloxanes in Extractants \u003cbr\u003e10 Determination of Lubricants in Extraction Liquids \u003cbr\u003e11 Determination of Monomers and Oligomers in Extractants \u003cbr\u003e12 Analysis of Polymer Extraction Liquids Containing More Than One Migrant \u003cbr\u003e13 Determination of Additives and their Breakdown Products in Extractants \u003cbr\u003e14 Additive Migration Theory \u003cbr\u003e15 Gas Barrier Properties of Food Packaging Plastic Films \u003cbr\u003e16 Legislative Aspects of the Use of Additives in Packaging Plastics \u003cbr\u003e17 Direct Determination of Migrants from Polymers into Foodstuffs\u003cbr\u003e\u003cbr\u003e\n\u003ch5\u003eAbout Author\u003c\/h5\u003e\nRoy Crompton was Head of the polymer analysis research department of a major international polymer producer for some 15 years. In the early fifties, he was heavily engaged in the development of methods of analysis for low-pressure polyolefins produced by the Ziegler-Natta route, including work on high-density polyethylene and polypropylene. He was responsible for the development of methods of analysis of the organoaluminum catalysts used for the synthesis of these polymers. He was also responsible for the development of thin-layer chromatography for the determination of various types of additives in polymers and did pioneering work on the use of TLC to separate polymer additives and to examine the separated additives by infrared and mass spectrometry. He retired in 1988 and has since been engaged as a consultant in the field of analytical chemistry and has written extensively on this subject, with some 20 books published."}

Additives for waterbor...

$235.00

{"id":11242230340,"title":"Additives for waterborne Coatings","handle":"978-3-86630-850-3","description":"\u003ch5\u003eDescription\u003c\/h5\u003e\nAuthor: Wernfried Heilein, Director of Technical Marketing, Evonik Tego Chemical GmbH, Essen, Germany \u003cbr\u003eISBN 978-3-86630-850-3 \u003cbr\u003e\u003cbr\u003eHardbound, 240 Pages\n\u003ch5\u003eSummary\u003c\/h5\u003e\n\u003cp\u003eThis book offers an overview of the most important aspects and applications of additives for waterborne systems in diverse market segments. Wernfried Heilein helps to understand how additives work and elucidates all kinds of mechanisms in great detail. Furthermore, he dispels a lot of myths surrounding paint additives with an excellent combination of theory and practice. This enables a deep insight into all the different application areas for additives in waterborne paint systems.\u003c\/p\u003e\n\u003cp\u003e\u003cb\u003eAudience: \u003c\/b\u003e\u003cbr\u003eFormulators involved in developing, producing, and testing of waterborne coatings and paints for different applications and substrates including can and coil coatings, heavy-duty protective coatings, plastics coatings, wood coatings and architectural coatings.\u003cbr\u003e\u003cbr\u003e\u003c\/p\u003e\n\u003ch5\u003eTable of Contents\u003c\/h5\u003e\n\u003cb\u003e1 Introduction\u003c\/b\u003e\u003cbr\u003e\u003cbr\u003e\u003cb\u003e2 Wetting- and dispersing additives\u003c\/b\u003e\u003cbr\u003e2.1 Modes of action\u003cbr\u003e2.1.1 Pigment wetting\u003cbr\u003e2.1.2 Grinding\u003cbr\u003e2.1.3 Stabilisation\u003cbr\u003e2.1.3.1 Electrostatic stabilisation\u003cbr\u003e2.1.3.2 Steric stabilisation\u003cbr\u003e2.1.3.3 Electrosteric stabilisation\u003cbr\u003e2.1.4 Influences on formulation\u003cbr\u003e2.1.4.1 Viscosity\u003cbr\u003e2.1.4.2 Colour strength\u003cbr\u003e2.1.4.3 Compatibility\u003cbr\u003e2.1.4.4 Stability\u003cbr\u003e2.2 Chemical structures\u003cbr\u003e2.2.1 Polyacrylate salts\u003cbr\u003e2.2.2 Fatty acid and fatty alcohol derivatives\u003cbr\u003e2.2.3 Acrylic-copolymers\u003cbr\u003e2.2.4 Maleic anhydride copolymers\u003cbr\u003e2.2.5 Alkyl phenol ethoxylates\u003cbr\u003e2.2.6 Alkyl phenol ethoxylate replacements\u003cbr\u003e2.3 Wetting and dispersing additives in different market segments\u003cbr\u003e2.3.1 Architectural coatings\u003cbr\u003e2.3.1.1 Direct-grind\u003cbr\u003e2.3.1.2 Pigment concentrates\u003cbr\u003e2.3.2 Wood and furniture coatings\u003cbr\u003e2.3.2.1 Direct grind\u003cbr\u003e2.3.2.2 Pigment concentrates\u003cbr\u003e2.3.3 Industrial coatings\u003cbr\u003e2.3.3.1 Direct grind\u003cbr\u003e2.3.3.2 Pigment concentrates\u003cbr\u003e2.3.4 Printing inks\u003cbr\u003e2.3.4.1 Direct grind\u003cbr\u003e2.3.4.2 Pigment concentrates\u003cbr\u003e2.4 Tips and Tricks\u003cbr\u003e2.5 Test methods\u003cbr\u003e2.5.1 Particle size\u003cbr\u003e2.5.2 Colour strength\u003cbr\u003e2.5.3 Rub-out\u003cbr\u003e2.5.4 Viscosity\u003cbr\u003e2.5.5 Zeta potential\u003cbr\u003e2.6 Summary\u003cbr\u003e2.7 Literature\u003cbr\u003e\u003cbr\u003e\u003cb\u003e3 Defoaming of coating systems\u003c\/b\u003e\u003cbr\u003e3.1 Defoaming mechanisms\u003cbr\u003e3.1.1 Foam\u003cbr\u003e3.1.1.1 Causes of foam\u003cbr\u003e3.1.1.2 Types of foam\u003cbr\u003e3.2 Defoamers\u003cbr\u003e3.2.1 Composition of defoamers\u003cbr\u003e3.2.2 Defoaming mechanisms\u003cbr\u003e3.2.2.1 Defoaming by drainage\/slow defoaming\u003cbr\u003e3.2.2.2 Entry barrier\/entry coefficient\u003cbr\u003e3.2.2.3 Bridging mechanism\u003cbr\u003e3.2.2.4 Spreading mechanism\u003cbr\u003e3.2.2.5 Bridging stretching mechanism\u003cbr\u003e3.2.2.6 Bridging dewetting mechanism\u003cbr\u003e3.2.2.7 Spreading fluid mechanism\u003cbr\u003e3.2.2.8 Spreading wave mechanism\u003cbr\u003e3.2.2.9 Effect of fillers on the performance of defoamers\u003cbr\u003e3.3 Chemistry and formulation of defoamers\u003cbr\u003e3.3.1 Active ingredients in defoamers\u003cbr\u003e3.3.1.1 Silicone oils (polysiloxanes)\u003cbr\u003e3.3.1.2 Mineral oils\u003cbr\u003e3.3.1.3 Vegetable oils\u003cbr\u003e3.3.1.4 Polar oils\u003cbr\u003e3.3.1.5 Molecular defoamers (gemini surfactants)\u003cbr\u003e3.3.1.6 Hydrophobic particles\u003cbr\u003e3.3.1.7 Emulsifiers\u003cbr\u003e3.3.1.8 Solvents\u003cbr\u003e3.3.2 Defoamer formulations\u003cbr\u003e3.3.3 Suppliers of defoamers\u003cbr\u003e3.4 Product recommendations for different binders\u003cbr\u003e3.4.1 Acrylic emulsions\u003cbr\u003e3.4.2 Styrene acrylic emulsions\u003cbr\u003e3.4.3 Vinyl acetate based emulsions\u003cbr\u003e3.4.4 Polyurethane dispersions\u003cbr\u003e3.5 Product choice according to field of application\u003cbr\u003e3.5.1 Influence of the pigment volume concentration (PVC)\u003cbr\u003e3.5.2 Method of incorporating the defoamer\u003cbr\u003e3.5.3 Application of shear forces during application\u003cbr\u003e3.5.4 Surfactant content of the formulation\u003cbr\u003e3.6 Tips and tricks\u003cbr\u003e3.7 Summary\u003cbr\u003e3.8 Literature\u003cbr\u003e\u003cbr\u003e\u003cb\u003e4 Rheology modifiers\u003c\/b\u003e\u003cbr\u003e4.1 General assessment of rheology modifiers\u003cbr\u003e4.1.1 Market overview\u003cbr\u003e4.1.2 Basic characteristics of the different rheological additives\u003cbr\u003e4.2 Requirements for rheology modifiers\u003cbr\u003e4.2.1 Rheology\u003cbr\u003e4.2.2 Example of application\u003cbr\u003e4.3 Ethoxylated and hydrophobically modified urethanes\u003cbr\u003e4.3.1 Synthesis of HEUR\u003cbr\u003e4.3.2 Associative properties of HEUR additives\u003cbr\u003e4.3.3 From self-association to associative behaviour\u003cbr\u003e4.3.4 Hydrophobic\/hydrophilic equilibrium of waterborne coatings\u003cbr\u003e4.3.5 Improved colour acceptance with HEUR\u003cbr\u003e4.4 Alkali swellable emulsions: ASE and HASE\u003cbr\u003e4.4.1 Synthesis\u003cbr\u003e4.4.1.1 ASE\u003cbr\u003e4.4.1.2 HASE\u003cbr\u003e4.4.1.3 Interaction between binders\u003cbr\u003e4.4.2 Thixotropy and HASE\u003cbr\u003e4.5 Outlook\u003cbr\u003e4.6 Literature\u003cbr\u003e\u003cbr\u003e\u003cb\u003e5 Substrate wetting additives\u003c\/b\u003e\u003cbr\u003e5.1 Mechanism of action\u003cbr\u003e5.1.1 Water as a solvent\u003cbr\u003e5.1.2 Surface tension\u003cbr\u003e5.1.3 Reason of the surface tension\u003cbr\u003e5.1.4 Effect of the high surface tension of water\u003cbr\u003e5.1.5 Substrate wetting additives are surfactants\u003cbr\u003e5.1.6 Mode of action of substrate wetting additives\u003cbr\u003e5.1.7 Further general properties of substrate wetting additives\/side effects\u003cbr\u003e5.2 Chemical structure of substrate wetting additives\u003cbr\u003e5.2.1 Basic properties of substrate wetting additives\u003cbr\u003e5.2.2 Chemical structure of substrate wetting additives important in coatings\u003cbr\u003e5.2.2.1 Polyethersiloxanes\u003cbr\u003e5.2.2.2 Gemini surfactants\u003cbr\u003e5.2.2.3 Fluoro surfactants\u003cbr\u003e5.2.2.4 Acetylenediols and modifications\u003cbr\u003e5.2.2.5 Sulfosuccinate\u003cbr\u003e5.2.2.6 Alkoxylated fatty alcohols\u003cbr\u003e5.2.2.7 Alkylphenol ethoxylates (APEO)\u003cbr\u003e5.3 Application of substrate wetting additives\u003cbr\u003e5.3.1 Basic properties of various chemical classes\u003cbr\u003e5.3.2 Reduction of static surface tension\u003cbr\u003e5.3.3 Possible foam stabilisation\u003cbr\u003e5.3.4 Effective reduction in static surface tension versus flow\u003cbr\u003e5.3.5 Reduction of dynamic surface tension\u003cbr\u003e5.3.6 Which property correlates with which practical application?\u003cbr\u003e5.3.6.1 Craters\u003cbr\u003e5.3.6.2 Wetting and atomisation of spray coatings\u003cbr\u003e5.3.6.3 Rewettability, reprintability, recoatability\u003cbr\u003e5.3.6.4 Flow\u003cbr\u003e5.3.6.5 Spray mist uptake\u003cbr\u003e5.4 Use of substrate wetting additives in different market sectors\u003cbr\u003e5.5 Tips and tricks\u003cbr\u003e5.5.1 Successful use of substrate wetting additives in coatings\u003cbr\u003e5.5.2 Metallic shades\u003cbr\u003e5.6 Test methods for measuring surface tension\u003cbr\u003e5.6.1 Static surface tension\u003cbr\u003e5.6.2 Dynamic surface tension\u003cbr\u003e5.6.3 Dynamic versus static\u003cbr\u003e5.6.4 Further practical test methods\u003cbr\u003e5.6.4.1 Wedge spray application\u003cbr\u003e5.6.4.2 One spray path\u003cbr\u003e5.6.4.3 Crater test\u003cbr\u003e5.6.4.4 Drawdown\u003cbr\u003e5.6.4.5 Spray drop uptake\u003cbr\u003e5.6.5 Analytical test methods\u003cbr\u003e5.7 Literature\u003cbr\u003e\u003cbr\u003e\u003cb\u003e6 Improving performance with co-binders\u003c\/b\u003e\u003cbr\u003e6.1 Preparation of co-binders\u003cbr\u003e6.1.1 Secondary dispersions\u003cbr\u003e6.1.1.1 Polyester dispersions\u003cbr\u003e6.1.1.2 Polyurethane dispersions\u003cbr\u003e6.2 Applications of co-binders\u003cbr\u003e6.2.1 Co-binders for better property profiles\u003cbr\u003e6.2.1.1 Drying time\u003cbr\u003e6.2.1.2 Adhesion\u003cbr\u003e6.2.1.3 Hardness-flexibility balance\u003cbr\u003e6.2.1.4 Gloss\u003cbr\u003e6.2.2 Co-binders for pigment pastes\u003cbr\u003e6.3 Summary\u003cbr\u003e6.4 Literature\u003cbr\u003e\u003cbr\u003e\u003cb\u003e7 Deaerators\u003c\/b\u003e\u003cbr\u003e7.1 Mode of action of deaerators\u003cbr\u003e7.1.1 Dissolution of microfoam\u003cbr\u003e7.1.2 Rise of microfoam bubbles in the coating film\u003cbr\u003e7.1.3 How to prevent microfoam in coating films\u003cbr\u003e7.1.4 How deaerators combat microfoam\u003cbr\u003e7.1.4.1 Deaerators promote the dissolution or formation of small microfoam bubbles\u003cbr\u003e7.1.4.2 How deaerators promote the dissolution of microfoam bubbles\u003cbr\u003e7.2 Chemical composition of deaerators\u003cbr\u003e7.3 Main applications according to binder systems\u003cbr\u003e7.4 Main applications according to market segments\u003cbr\u003e7.5 Tips and tricks\u003cbr\u003e7.6 Evaluating the effectiveness of deaerators\u003cbr\u003e7.6.1 Test method for low to medium viscosity coating formulations\u003cbr\u003e7.6.2 Test method for medium to high viscosity coating formulations\u003cbr\u003e7.6.3 Further test methods for microfoam\u003cbr\u003e7.7 Conclusion\u003cbr\u003e7.7 Literature\u003cbr\u003e\u003cbr\u003e\u003cb\u003e8 Flow additives\u003c\/b\u003e\u003cbr\u003e8.1 Mode of action\u003cbr\u003e8.1.1 Mode of action in waterborne systems without co-solvents\u003cbr\u003e8.1.2 Sagging\u003cbr\u003e8.1.3 Total film flow\u003cbr\u003e8.1.4 Mode of action in waterborne systems with co-solvents\u003cbr\u003e8.1.5 Mode of action in an example of a thermosetting waterborne system with cosolvents\u003cbr\u003e8.1.6 Surface tension gradients\u003cbr\u003e8.1.7 Summary\u003cbr\u003e8.2 Chemistry of active ingredients\u003cbr\u003e8.2.1 Polyether siloxanes\u003cbr\u003e8.2.2 Polyacrylates\u003cbr\u003e8.2.3 Side effects of polyether siloxanes\u003cbr\u003e8.2.4 Slip\u003cbr\u003e8.3 Film formation\u003cbr\u003e8.4 Main applications by market segment\u003cbr\u003e8.4.1 Industrial metal coating\u003cbr\u003e8.4.1.1 Electrophoretic coating\u003cbr\u003e8.4.1.2 Waterborne coatings\u003cbr\u003e8.4.2 Industrial coatings\u003cbr\u003e8.4.3 Architectural coatings\u003cbr\u003e8.4.3.1 Flat and semi-gloss emulsion paints\u003cbr\u003e8.4.3.2 High gloss emulsion paints\u003cbr\u003e8.5 Conclusion\u003cbr\u003e8.6 Test methods\u003cbr\u003e8.6.1 Measurement of flow\u003cbr\u003e8.6.2 Measuring flow and sagging by DMA\u003cbr\u003e8.6.3 Measuring the surface slip properties\u003cbr\u003e8.7 Literature\u003cbr\u003e\u003cbr\u003e\u003cb\u003e9 Wax additives\u003c\/b\u003e\u003cbr\u003e9.1 Raw material wax\u003cbr\u003e9.1.1 Natural waxes\u003cbr\u003e9.1.1.1 Waxes from renewable raw materials\u003cbr\u003e9.1.1.2 Waxes from fossilised sources\u003cbr\u003e9.1.2 Semi-synthetic and synthetic waxes\u003cbr\u003e9.1.2.1 Semi-synthetic waxes\u003cbr\u003e9.1.2.2 Synthetic waxes\u003cbr\u003e9.2 From wax to wax additives\u003cbr\u003e9.2.1 Wax and water\u003cbr\u003e9.2.1.1 Wax emulsions\u003cbr\u003e9.2.1.2 Wax dispersions\u003cbr\u003e9.2.3 Micronized wax additives\u003cbr\u003e9.3 Wax additives for the coating industry\u003cbr\u003e9.3.1 Acting mechanism\u003cbr\u003e9.3.2 Coating properties\u003cbr\u003e9.3.2.1 Surface protection\u003cbr\u003e9.3.2.2 Gloss reduction\u003cbr\u003e9.3.2.3 Texture and structure\u003cbr\u003e9.3.2.4 Rheology control\u003cbr\u003e9.4 Summary\u003cbr\u003e\u003cbr\u003e\u003cb\u003e10 Light stabilizers for waterborne coatings\u003c\/b\u003e\u003cbr\u003e10.1 Introduction\u003cbr\u003e10.2 Light and photo-oxidative degradation\u003cbr\u003e10.3 Stabilization options for polymers\u003cbr\u003e10.3.1 UV absorbers\u003cbr\u003e10.3.2 Radical scavengers\u003cbr\u003e10.3.2.1 Antioxidants\u003cbr\u003e10.3.2.2 Sterically hindered amines\u003cbr\u003e10.4 Light stabilizers for waterborne coatings\u003cbr\u003e10.4.1 Market overview\u003cbr\u003e10.4.2 Application fields and market segments\u003cbr\u003e10.4.2.1 Application specific product selection\u003cbr\u003e10.5 Conclusions\u003cbr\u003e10.6 Test methods and analytical determination\u003cbr\u003e10.6.1 UV absorbers\u003cbr\u003e10.6.2 HALS\u003cbr\u003e10.6.3 Weathering methods and evaluation criteria\u003cbr\u003e10.6.3.1 Accelerated exposure tests\u003cbr\u003e10.6.3.2 Further evaluation criteria\u003cbr\u003e10.7 Literature\u003cbr\u003e\u003cbr\u003e\u003cb\u003e11 In-can and dry film preservation\u003c\/b\u003e\u003cbr\u003e11.1 Sustainable and effective in-can and dry film preservation\u003cbr\u003e11.2 In-can preservation\u003cbr\u003e11.2.1 Types of active ingredients\u003cbr\u003e11.2.2 Selection of active ingredients for the preservation system\u003cbr\u003e11.2.3 Plant hygiene\u003cbr\u003e11.3 Dry film preservation\u003cbr\u003e11.3.1. Conventional dry film preservatives\u003cbr\u003e11.3.2 New, „old” actives\u003cbr\u003e11.3.3 Improvements in the ecotoxicological properties\u003cbr\u003e11.4 External determining factors\u003cbr\u003e11.5 Prospect\u003cbr\u003e11.6 Literature\u003cbr\u003e\u003cbr\u003e\u003cb\u003e12 Hydrophobing agents\u003c\/b\u003e\u003cbr\u003e12.1 Mode of action\u003cbr\u003e12.1.1 Capillary water-absorption\u003cbr\u003e12.1.2 Hydrophobicity\u003cbr\u003e12.1.3 How hydrophobing agents work\u003cbr\u003e12.2 Chemical structures\u003cbr\u003e12.2.1 Linear polysiloxanes and organofunctional polysiloxanes\u003cbr\u003e12.2.2 Silicone resins\/silicone resin emulsions\u003cbr\u003e12.2.3 Other hydrophobing agents\u003cbr\u003e12.2.4 Production of linear polysiloxanes\u003cbr\u003e12.2.5 Production of silicone resin emulsions\u003cbr\u003e12.2.5.1 Secondary emulsification process\u003cbr\u003e12.2.5.2 Primary emulsification process\u003cbr\u003e12.3 Waterborne architectural paints\u003cbr\u003e12.3.1 Synthetic emulsion paints\u003cbr\u003e12.3.2 Silicate emulsion paints\u003cbr\u003e12.3.3 Emulsion paints with silicate character (SIL-paints)\u003cbr\u003e12.3.4 Siloxane architectural paints with strong water-beading effect\u003cbr\u003e12.3.5 Silicone resin emulsion paints\u003cbr\u003e12.4 Conclusions\u003cbr\u003e12.5 Appendix\u003cbr\u003e12.5.1 Facade protection theory according to Künzel\u003cbr\u003e12.5.2 Measurement of capillary water-absorption (w-value)\u003cbr\u003e12.5.3 Water vapour diffusion (sd-value)\u003cbr\u003e12.5.4 Simulated dirt pick-up\u003cbr\u003e12.5.5 Pigment-volume concentration (PVC):\u003cbr\u003e12.6 Literature\u003cbr\u003eAuthors\u003cbr\u003eIndex\u003cbr\u003e\u003cbr\u003e","published_at":"2017-06-22T21:14:14-04:00","created_at":"2017-06-22T21:14:14-04:00","vendor":"Chemtec Publishing","type":"Book","tags":["2009","additives","book","co-binders","coatings","deaerators","dispersing","formulators","hydrophobing agents","p-applications","paints","plastic","polymer","waterborne systems","wetting"],"price":23500,"price_min":23500,"price_max":23500,"available":true,"price_varies":false,"compare_at_price":null,"compare_at_price_min":0,"compare_at_price_max":0,"compare_at_price_varies":false,"variants":[{"id":43378399876,"title":"Default Title","option1":"Default Title","option2":null,"option3":null,"sku":"","requires_shipping":true,"taxable":true,"featured_image":null,"available":true,"name":"Additives for waterborne Coatings","public_title":null,"options":["Default Title"],"price":23500,"weight":1000,"compare_at_price":null,"inventory_quantity":1,"inventory_management":null,"inventory_policy":"continue","barcode":"978-3-86630-850-3","requires_selling_plan":false,"selling_plan_allocations":[]}],"images":["\/\/chemtec.org\/cdn\/shop\/products\/978-3-86630-850-3.jpg?v=1498184602"],"featured_image":"\/\/chemtec.org\/cdn\/shop\/products\/978-3-86630-850-3.jpg?v=1498184602","options":["Title"],"media":[{"alt":null,"id":350139383901,"position":1,"preview_image":{"aspect_ratio":0.767,"height":450,"width":345,"src":"\/\/chemtec.org\/cdn\/shop\/products\/978-3-86630-850-3.jpg?v=1498184602"},"aspect_ratio":0.767,"height":450,"media_type":"image","src":"\/\/chemtec.org\/cdn\/shop\/products\/978-3-86630-850-3.jpg?v=1498184602","width":345}],"requires_selling_plan":false,"selling_plan_groups":[],"content":"\u003ch5\u003eDescription\u003c\/h5\u003e\nAuthor: Wernfried Heilein, Director of Technical Marketing, Evonik Tego Chemical GmbH, Essen, Germany \u003cbr\u003eISBN 978-3-86630-850-3 \u003cbr\u003e\u003cbr\u003eHardbound, 240 Pages\n\u003ch5\u003eSummary\u003c\/h5\u003e\n\u003cp\u003eThis book offers an overview of the most important aspects and applications of additives for waterborne systems in diverse market segments. Wernfried Heilein helps to understand how additives work and elucidates all kinds of mechanisms in great detail. Furthermore, he dispels a lot of myths surrounding paint additives with an excellent combination of theory and practice. This enables a deep insight into all the different application areas for additives in waterborne paint systems.\u003c\/p\u003e\n\u003cp\u003e\u003cb\u003eAudience: \u003c\/b\u003e\u003cbr\u003eFormulators involved in developing, producing, and testing of waterborne coatings and paints for different applications and substrates including can and coil coatings, heavy-duty protective coatings, plastics coatings, wood coatings and architectural coatings.\u003cbr\u003e\u003cbr\u003e\u003c\/p\u003e\n\u003ch5\u003eTable of Contents\u003c\/h5\u003e\n\u003cb\u003e1 Introduction\u003c\/b\u003e\u003cbr\u003e\u003cbr\u003e\u003cb\u003e2 Wetting- and dispersing additives\u003c\/b\u003e\u003cbr\u003e2.1 Modes of action\u003cbr\u003e2.1.1 Pigment wetting\u003cbr\u003e2.1.2 Grinding\u003cbr\u003e2.1.3 Stabilisation\u003cbr\u003e2.1.3.1 Electrostatic stabilisation\u003cbr\u003e2.1.3.2 Steric stabilisation\u003cbr\u003e2.1.3.3 Electrosteric stabilisation\u003cbr\u003e2.1.4 Influences on formulation\u003cbr\u003e2.1.4.1 Viscosity\u003cbr\u003e2.1.4.2 Colour strength\u003cbr\u003e2.1.4.3 Compatibility\u003cbr\u003e2.1.4.4 Stability\u003cbr\u003e2.2 Chemical structures\u003cbr\u003e2.2.1 Polyacrylate salts\u003cbr\u003e2.2.2 Fatty acid and fatty alcohol derivatives\u003cbr\u003e2.2.3 Acrylic-copolymers\u003cbr\u003e2.2.4 Maleic anhydride copolymers\u003cbr\u003e2.2.5 Alkyl phenol ethoxylates\u003cbr\u003e2.2.6 Alkyl phenol ethoxylate replacements\u003cbr\u003e2.3 Wetting and dispersing additives in different market segments\u003cbr\u003e2.3.1 Architectural coatings\u003cbr\u003e2.3.1.1 Direct-grind\u003cbr\u003e2.3.1.2 Pigment concentrates\u003cbr\u003e2.3.2 Wood and furniture coatings\u003cbr\u003e2.3.2.1 Direct grind\u003cbr\u003e2.3.2.2 Pigment concentrates\u003cbr\u003e2.3.3 Industrial coatings\u003cbr\u003e2.3.3.1 Direct grind\u003cbr\u003e2.3.3.2 Pigment concentrates\u003cbr\u003e2.3.4 Printing inks\u003cbr\u003e2.3.4.1 Direct grind\u003cbr\u003e2.3.4.2 Pigment concentrates\u003cbr\u003e2.4 Tips and Tricks\u003cbr\u003e2.5 Test methods\u003cbr\u003e2.5.1 Particle size\u003cbr\u003e2.5.2 Colour strength\u003cbr\u003e2.5.3 Rub-out\u003cbr\u003e2.5.4 Viscosity\u003cbr\u003e2.5.5 Zeta potential\u003cbr\u003e2.6 Summary\u003cbr\u003e2.7 Literature\u003cbr\u003e\u003cbr\u003e\u003cb\u003e3 Defoaming of coating systems\u003c\/b\u003e\u003cbr\u003e3.1 Defoaming mechanisms\u003cbr\u003e3.1.1 Foam\u003cbr\u003e3.1.1.1 Causes of foam\u003cbr\u003e3.1.1.2 Types of foam\u003cbr\u003e3.2 Defoamers\u003cbr\u003e3.2.1 Composition of defoamers\u003cbr\u003e3.2.2 Defoaming mechanisms\u003cbr\u003e3.2.2.1 Defoaming by drainage\/slow defoaming\u003cbr\u003e3.2.2.2 Entry barrier\/entry coefficient\u003cbr\u003e3.2.2.3 Bridging mechanism\u003cbr\u003e3.2.2.4 Spreading mechanism\u003cbr\u003e3.2.2.5 Bridging stretching mechanism\u003cbr\u003e3.2.2.6 Bridging dewetting mechanism\u003cbr\u003e3.2.2.7 Spreading fluid mechanism\u003cbr\u003e3.2.2.8 Spreading wave mechanism\u003cbr\u003e3.2.2.9 Effect of fillers on the performance of defoamers\u003cbr\u003e3.3 Chemistry and formulation of defoamers\u003cbr\u003e3.3.1 Active ingredients in defoamers\u003cbr\u003e3.3.1.1 Silicone oils (polysiloxanes)\u003cbr\u003e3.3.1.2 Mineral oils\u003cbr\u003e3.3.1.3 Vegetable oils\u003cbr\u003e3.3.1.4 Polar oils\u003cbr\u003e3.3.1.5 Molecular defoamers (gemini surfactants)\u003cbr\u003e3.3.1.6 Hydrophobic particles\u003cbr\u003e3.3.1.7 Emulsifiers\u003cbr\u003e3.3.1.8 Solvents\u003cbr\u003e3.3.2 Defoamer formulations\u003cbr\u003e3.3.3 Suppliers of defoamers\u003cbr\u003e3.4 Product recommendations for different binders\u003cbr\u003e3.4.1 Acrylic emulsions\u003cbr\u003e3.4.2 Styrene acrylic emulsions\u003cbr\u003e3.4.3 Vinyl acetate based emulsions\u003cbr\u003e3.4.4 Polyurethane dispersions\u003cbr\u003e3.5 Product choice according to field of application\u003cbr\u003e3.5.1 Influence of the pigment volume concentration (PVC)\u003cbr\u003e3.5.2 Method of incorporating the defoamer\u003cbr\u003e3.5.3 Application of shear forces during application\u003cbr\u003e3.5.4 Surfactant content of the formulation\u003cbr\u003e3.6 Tips and tricks\u003cbr\u003e3.7 Summary\u003cbr\u003e3.8 Literature\u003cbr\u003e\u003cbr\u003e\u003cb\u003e4 Rheology modifiers\u003c\/b\u003e\u003cbr\u003e4.1 General assessment of rheology modifiers\u003cbr\u003e4.1.1 Market overview\u003cbr\u003e4.1.2 Basic characteristics of the different rheological additives\u003cbr\u003e4.2 Requirements for rheology modifiers\u003cbr\u003e4.2.1 Rheology\u003cbr\u003e4.2.2 Example of application\u003cbr\u003e4.3 Ethoxylated and hydrophobically modified urethanes\u003cbr\u003e4.3.1 Synthesis of HEUR\u003cbr\u003e4.3.2 Associative properties of HEUR additives\u003cbr\u003e4.3.3 From self-association to associative behaviour\u003cbr\u003e4.3.4 Hydrophobic\/hydrophilic equilibrium of waterborne coatings\u003cbr\u003e4.3.5 Improved colour acceptance with HEUR\u003cbr\u003e4.4 Alkali swellable emulsions: ASE and HASE\u003cbr\u003e4.4.1 Synthesis\u003cbr\u003e4.4.1.1 ASE\u003cbr\u003e4.4.1.2 HASE\u003cbr\u003e4.4.1.3 Interaction between binders\u003cbr\u003e4.4.2 Thixotropy and HASE\u003cbr\u003e4.5 Outlook\u003cbr\u003e4.6 Literature\u003cbr\u003e\u003cbr\u003e\u003cb\u003e5 Substrate wetting additives\u003c\/b\u003e\u003cbr\u003e5.1 Mechanism of action\u003cbr\u003e5.1.1 Water as a solvent\u003cbr\u003e5.1.2 Surface tension\u003cbr\u003e5.1.3 Reason of the surface tension\u003cbr\u003e5.1.4 Effect of the high surface tension of water\u003cbr\u003e5.1.5 Substrate wetting additives are surfactants\u003cbr\u003e5.1.6 Mode of action of substrate wetting additives\u003cbr\u003e5.1.7 Further general properties of substrate wetting additives\/side effects\u003cbr\u003e5.2 Chemical structure of substrate wetting additives\u003cbr\u003e5.2.1 Basic properties of substrate wetting additives\u003cbr\u003e5.2.2 Chemical structure of substrate wetting additives important in coatings\u003cbr\u003e5.2.2.1 Polyethersiloxanes\u003cbr\u003e5.2.2.2 Gemini surfactants\u003cbr\u003e5.2.2.3 Fluoro surfactants\u003cbr\u003e5.2.2.4 Acetylenediols and modifications\u003cbr\u003e5.2.2.5 Sulfosuccinate\u003cbr\u003e5.2.2.6 Alkoxylated fatty alcohols\u003cbr\u003e5.2.2.7 Alkylphenol ethoxylates (APEO)\u003cbr\u003e5.3 Application of substrate wetting additives\u003cbr\u003e5.3.1 Basic properties of various chemical classes\u003cbr\u003e5.3.2 Reduction of static surface tension\u003cbr\u003e5.3.3 Possible foam stabilisation\u003cbr\u003e5.3.4 Effective reduction in static surface tension versus flow\u003cbr\u003e5.3.5 Reduction of dynamic surface tension\u003cbr\u003e5.3.6 Which property correlates with which practical application?\u003cbr\u003e5.3.6.1 Craters\u003cbr\u003e5.3.6.2 Wetting and atomisation of spray coatings\u003cbr\u003e5.3.6.3 Rewettability, reprintability, recoatability\u003cbr\u003e5.3.6.4 Flow\u003cbr\u003e5.3.6.5 Spray mist uptake\u003cbr\u003e5.4 Use of substrate wetting additives in different market sectors\u003cbr\u003e5.5 Tips and tricks\u003cbr\u003e5.5.1 Successful use of substrate wetting additives in coatings\u003cbr\u003e5.5.2 Metallic shades\u003cbr\u003e5.6 Test methods for measuring surface tension\u003cbr\u003e5.6.1 Static surface tension\u003cbr\u003e5.6.2 Dynamic surface tension\u003cbr\u003e5.6.3 Dynamic versus static\u003cbr\u003e5.6.4 Further practical test methods\u003cbr\u003e5.6.4.1 Wedge spray application\u003cbr\u003e5.6.4.2 One spray path\u003cbr\u003e5.6.4.3 Crater test\u003cbr\u003e5.6.4.4 Drawdown\u003cbr\u003e5.6.4.5 Spray drop uptake\u003cbr\u003e5.6.5 Analytical test methods\u003cbr\u003e5.7 Literature\u003cbr\u003e\u003cbr\u003e\u003cb\u003e6 Improving performance with co-binders\u003c\/b\u003e\u003cbr\u003e6.1 Preparation of co-binders\u003cbr\u003e6.1.1 Secondary dispersions\u003cbr\u003e6.1.1.1 Polyester dispersions\u003cbr\u003e6.1.1.2 Polyurethane dispersions\u003cbr\u003e6.2 Applications of co-binders\u003cbr\u003e6.2.1 Co-binders for better property profiles\u003cbr\u003e6.2.1.1 Drying time\u003cbr\u003e6.2.1.2 Adhesion\u003cbr\u003e6.2.1.3 Hardness-flexibility balance\u003cbr\u003e6.2.1.4 Gloss\u003cbr\u003e6.2.2 Co-binders for pigment pastes\u003cbr\u003e6.3 Summary\u003cbr\u003e6.4 Literature\u003cbr\u003e\u003cbr\u003e\u003cb\u003e7 Deaerators\u003c\/b\u003e\u003cbr\u003e7.1 Mode of action of deaerators\u003cbr\u003e7.1.1 Dissolution of microfoam\u003cbr\u003e7.1.2 Rise of microfoam bubbles in the coating film\u003cbr\u003e7.1.3 How to prevent microfoam in coating films\u003cbr\u003e7.1.4 How deaerators combat microfoam\u003cbr\u003e7.1.4.1 Deaerators promote the dissolution or formation of small microfoam bubbles\u003cbr\u003e7.1.4.2 How deaerators promote the dissolution of microfoam bubbles\u003cbr\u003e7.2 Chemical composition of deaerators\u003cbr\u003e7.3 Main applications according to binder systems\u003cbr\u003e7.4 Main applications according to market segments\u003cbr\u003e7.5 Tips and tricks\u003cbr\u003e7.6 Evaluating the effectiveness of deaerators\u003cbr\u003e7.6.1 Test method for low to medium viscosity coating formulations\u003cbr\u003e7.6.2 Test method for medium to high viscosity coating formulations\u003cbr\u003e7.6.3 Further test methods for microfoam\u003cbr\u003e7.7 Conclusion\u003cbr\u003e7.7 Literature\u003cbr\u003e\u003cbr\u003e\u003cb\u003e8 Flow additives\u003c\/b\u003e\u003cbr\u003e8.1 Mode of action\u003cbr\u003e8.1.1 Mode of action in waterborne systems without co-solvents\u003cbr\u003e8.1.2 Sagging\u003cbr\u003e8.1.3 Total film flow\u003cbr\u003e8.1.4 Mode of action in waterborne systems with co-solvents\u003cbr\u003e8.1.5 Mode of action in an example of a thermosetting waterborne system with cosolvents\u003cbr\u003e8.1.6 Surface tension gradients\u003cbr\u003e8.1.7 Summary\u003cbr\u003e8.2 Chemistry of active ingredients\u003cbr\u003e8.2.1 Polyether siloxanes\u003cbr\u003e8.2.2 Polyacrylates\u003cbr\u003e8.2.3 Side effects of polyether siloxanes\u003cbr\u003e8.2.4 Slip\u003cbr\u003e8.3 Film formation\u003cbr\u003e8.4 Main applications by market segment\u003cbr\u003e8.4.1 Industrial metal coating\u003cbr\u003e8.4.1.1 Electrophoretic coating\u003cbr\u003e8.4.1.2 Waterborne coatings\u003cbr\u003e8.4.2 Industrial coatings\u003cbr\u003e8.4.3 Architectural coatings\u003cbr\u003e8.4.3.1 Flat and semi-gloss emulsion paints\u003cbr\u003e8.4.3.2 High gloss emulsion paints\u003cbr\u003e8.5 Conclusion\u003cbr\u003e8.6 Test methods\u003cbr\u003e8.6.1 Measurement of flow\u003cbr\u003e8.6.2 Measuring flow and sagging by DMA\u003cbr\u003e8.6.3 Measuring the surface slip properties\u003cbr\u003e8.7 Literature\u003cbr\u003e\u003cbr\u003e\u003cb\u003e9 Wax additives\u003c\/b\u003e\u003cbr\u003e9.1 Raw material wax\u003cbr\u003e9.1.1 Natural waxes\u003cbr\u003e9.1.1.1 Waxes from renewable raw materials\u003cbr\u003e9.1.1.2 Waxes from fossilised sources\u003cbr\u003e9.1.2 Semi-synthetic and synthetic waxes\u003cbr\u003e9.1.2.1 Semi-synthetic waxes\u003cbr\u003e9.1.2.2 Synthetic waxes\u003cbr\u003e9.2 From wax to wax additives\u003cbr\u003e9.2.1 Wax and water\u003cbr\u003e9.2.1.1 Wax emulsions\u003cbr\u003e9.2.1.2 Wax dispersions\u003cbr\u003e9.2.3 Micronized wax additives\u003cbr\u003e9.3 Wax additives for the coating industry\u003cbr\u003e9.3.1 Acting mechanism\u003cbr\u003e9.3.2 Coating properties\u003cbr\u003e9.3.2.1 Surface protection\u003cbr\u003e9.3.2.2 Gloss reduction\u003cbr\u003e9.3.2.3 Texture and structure\u003cbr\u003e9.3.2.4 Rheology control\u003cbr\u003e9.4 Summary\u003cbr\u003e\u003cbr\u003e\u003cb\u003e10 Light stabilizers for waterborne coatings\u003c\/b\u003e\u003cbr\u003e10.1 Introduction\u003cbr\u003e10.2 Light and photo-oxidative degradation\u003cbr\u003e10.3 Stabilization options for polymers\u003cbr\u003e10.3.1 UV absorbers\u003cbr\u003e10.3.2 Radical scavengers\u003cbr\u003e10.3.2.1 Antioxidants\u003cbr\u003e10.3.2.2 Sterically hindered amines\u003cbr\u003e10.4 Light stabilizers for waterborne coatings\u003cbr\u003e10.4.1 Market overview\u003cbr\u003e10.4.2 Application fields and market segments\u003cbr\u003e10.4.2.1 Application specific product selection\u003cbr\u003e10.5 Conclusions\u003cbr\u003e10.6 Test methods and analytical determination\u003cbr\u003e10.6.1 UV absorbers\u003cbr\u003e10.6.2 HALS\u003cbr\u003e10.6.3 Weathering methods and evaluation criteria\u003cbr\u003e10.6.3.1 Accelerated exposure tests\u003cbr\u003e10.6.3.2 Further evaluation criteria\u003cbr\u003e10.7 Literature\u003cbr\u003e\u003cbr\u003e\u003cb\u003e11 In-can and dry film preservation\u003c\/b\u003e\u003cbr\u003e11.1 Sustainable and effective in-can and dry film preservation\u003cbr\u003e11.2 In-can preservation\u003cbr\u003e11.2.1 Types of active ingredients\u003cbr\u003e11.2.2 Selection of active ingredients for the preservation system\u003cbr\u003e11.2.3 Plant hygiene\u003cbr\u003e11.3 Dry film preservation\u003cbr\u003e11.3.1. Conventional dry film preservatives\u003cbr\u003e11.3.2 New, „old” actives\u003cbr\u003e11.3.3 Improvements in the ecotoxicological properties\u003cbr\u003e11.4 External determining factors\u003cbr\u003e11.5 Prospect\u003cbr\u003e11.6 Literature\u003cbr\u003e\u003cbr\u003e\u003cb\u003e12 Hydrophobing agents\u003c\/b\u003e\u003cbr\u003e12.1 Mode of action\u003cbr\u003e12.1.1 Capillary water-absorption\u003cbr\u003e12.1.2 Hydrophobicity\u003cbr\u003e12.1.3 How hydrophobing agents work\u003cbr\u003e12.2 Chemical structures\u003cbr\u003e12.2.1 Linear polysiloxanes and organofunctional polysiloxanes\u003cbr\u003e12.2.2 Silicone resins\/silicone resin emulsions\u003cbr\u003e12.2.3 Other hydrophobing agents\u003cbr\u003e12.2.4 Production of linear polysiloxanes\u003cbr\u003e12.2.5 Production of silicone resin emulsions\u003cbr\u003e12.2.5.1 Secondary emulsification process\u003cbr\u003e12.2.5.2 Primary emulsification process\u003cbr\u003e12.3 Waterborne architectural paints\u003cbr\u003e12.3.1 Synthetic emulsion paints\u003cbr\u003e12.3.2 Silicate emulsion paints\u003cbr\u003e12.3.3 Emulsion paints with silicate character (SIL-paints)\u003cbr\u003e12.3.4 Siloxane architectural paints with strong water-beading effect\u003cbr\u003e12.3.5 Silicone resin emulsion paints\u003cbr\u003e12.4 Conclusions\u003cbr\u003e12.5 Appendix\u003cbr\u003e12.5.1 Facade protection theory according to Künzel\u003cbr\u003e12.5.2 Measurement of capillary water-absorption (w-value)\u003cbr\u003e12.5.3 Water vapour diffusion (sd-value)\u003cbr\u003e12.5.4 Simulated dirt pick-up\u003cbr\u003e12.5.5 Pigment-volume concentration (PVC):\u003cbr\u003e12.6 Literature\u003cbr\u003eAuthors\u003cbr\u003eIndex\u003cbr\u003e\u003cbr\u003e"}

Adhesives Technology f...

$169.00

{"id":11242202180,"title":"Adhesives Technology for Electronic Applications, 2nd Edition - Materials, Processing, Reliability","handle":"978-1-4377-7889-2","description":"\u003ch5\u003eDescription\u003c\/h5\u003e\nAuthor: James J. Licari \u0026amp; Dale W. Swanson \u003cbr\u003eISBN 978-1-4377-7889-2 \u003cbr\u003e\u003cbr\u003e512 pages\n\u003ch5\u003eSummary\u003c\/h5\u003e\n\u003cb\u003eKey Features\u003c\/b\u003e\n\u003cli\u003eA complete guide for the electronics industry to adhesive types, their properties, and applications - this book is an essential reference for a wide range of specialists including electrical engineers, adhesion chemists, and other engineering professionals.\u003c\/li\u003e\n\u003cli\u003eProvides specifications of adhesives for particular uses and outlines the processes for application and curing - coverage that is of particular benefit to design engineers, who are charged with creating the interface between the adhesive material and the microelectronic device.\u003c\/li\u003e\n\u003cli\u003eDiscusses the respective advantages and limitations of different adhesives for varying applications, thereby addressing reliability issues before they occur and offering useful information to both design engineers and Quality Assurance personnel.\u003c\/li\u003e\n\u003cp\u003e\u003cb\u003eDescription\u003c\/b\u003e\u003cbr\u003e\u003cbr\u003e\u003cbr\u003eAdhesives are widely used in the manufacture and assembly of electronic circuits and products. Generally, electronics design engineers and manufacturing engineers are not well versed in adhesives, while adhesion chemists have a limited knowledge of electronics. This book bridges these knowledge gaps and is useful to both groups.\u003cbr\u003e\u003cbr\u003e\u003cbr\u003eThe book includes chapters covering types of adhesive, the chemistry on which they are based, and their properties, applications, processes, specifications, and reliability. Coverage of toxicity, environmental impacts, and the regulatory framework make this book particularly important for engineers and managers alike.\u003cbr\u003e\u003cbr\u003e\u003cbr\u003eThe third edition has been updated throughout and includes new sections on nanomaterials, environmental impacts and new environmentally friendly ‘green’ adhesives. Information about regulations and compliance has been brought fully up-to-date.\u003cbr\u003e\u003cbr\u003eAs well as providing full coverage of standard adhesive types, Licari explores the most recent developments in fields such as:\u003cbr\u003e\u003cbr\u003e• Tamper-proof adhesives for electronic security devices.\u003cbr\u003e\u003cbr\u003e• Bio-compatible adhesives for implantable medical devices.\u003cbr\u003e\u003cbr\u003e• Electrically conductive adhesives to replace toxic tin-lead solders in printed circuit assembly - as required by regulatory regimes, e.g. the EU’s Restriction of Hazardous Substances Directive or RoHS (compliance is required for all products placed on the European market).\u003cbr\u003e\u003cbr\u003e• Nano-fillers in adhesives used to increase the thermal conductivity of current adhesives for cooling electronic devices.\u003cbr\u003e\u003cbr\u003e\u003cb\u003eReadership\u003c\/b\u003e\u003cbr\u003e\u003cbr\u003eElectronics and materials engineers in the automotive, medical, semiconductors, space, plastics, and military industries.\u003cbr\u003e\u003cbr\u003e\u003cb\u003eQuotes\u003c\/b\u003e\u003cbr\u003e\u003cbr\u003e\"I recommend this book without reservation to everyone in electronics who must understand adhesives, or make decisions about adhesives, or both.\" - George Riley\u003c\/p\u003e\n\u003ch5\u003eTable of Contents\u003c\/h5\u003e\n1. Introduction\u003cbr\u003e1.1 Adhesives Types and Definitions\u003cbr\u003e1.2 Summary of Packaging Technologies\u003cbr\u003e1.3 History of Adhesives in Electronic Applications\u003cbr\u003e1.4 Comparison of Polymer Adhesives with Metallurgical and Vitreous Attachment Materials\u003cbr\u003e1.5 Specifications\u003cbr\u003e1.6 The Market \u003cbr\u003e2. Functions and Theory of Adhesives\u003cbr\u003e2.1 Mechanical Attachment\u003cbr\u003e2.2 Electrical Connections\u003cbr\u003e2.3 Thermal Dissipation\u003cbr\u003e2.4 Stress Dissipation \u003cbr\u003e3. Chemistry, Formulation, and Properties of Adhesives\u003cbr\u003e3.1 Chemistry\u003cbr\u003e3.2 Formulation of Adhesives\u003cbr\u003e3.3 Properties \u003cbr\u003e4. Adhesive Bonding Properties\u003cbr\u003e4.1 Cleaning\u003cbr\u003e4.2 Surface Treatments\u003cbr\u003e4.3 Adhesive Dispensing\u003cbr\u003e4.4 Placement of Devices and Components\u003cbr\u003e4.5 Curing\u003cbr\u003e4.6 Rework \u003cbr\u003e5. Applications\u003cbr\u003e5.1 General Applications\u003cbr\u003e5.2 Specific Applications \u003cbr\u003e6. Reliability\u003cbr\u003e6.1 Failure Modes and Mechanisms\u003cbr\u003e6.2 Specifications \u003cbr\u003e7. Test and Inspection Methods\u003cbr\u003e7.1 Physical Tests\u003cbr\u003e7.2 Electrical Tests\u003cbr\u003e7.3 Environmental Tests\u003cbr\u003e7.4 Thermal Tests\u003cbr\u003e7.5 Mechanical and Thermomechanical Tests\u003cbr\u003e7.6 Chemical Analysis\u003cbr\u003eAppendix\u003cbr\u003eConversion Factors\u003cbr\u003eAbbreviations and Acronyms\u003cbr\u003eIndex\n\u003ch5\u003eAbout Author\u003c\/h5\u003e\n\u003cdiv\u003e\u003cb\u003eJames J. Licari\u003c\/b\u003e\u003c\/div\u003e\n\u003cdiv\u003e\u003c\/div\u003e\n\u003cdiv\u003eAvanTeco, Whittier, CA, USA\u003c\/div\u003e\n\u003cdiv\u003ehas his own consulting firm, AvanTeco, specializing in materials and processes for electronics. He holds a BS in Chemistry from Fordham University and a Ph.D. in Chemistry from Princeton University, where he was a DuPont Senior Fellow. His areas of expertise include materials and processes for electronic applications, primarily for high-reliability systems, hybrid microcircuits, printed wiring circuits, and other interconnect packaging technologies. He is an expert on polymeric materials including adhesives, coatings, encapsulants, insulation, reliability based on failure modes and mechanisms. Dr. Licari has had a forty-year career dedicated to the study and advancement of microelectronic materials and processes. Notable achievements throughout this career include conducting the first studies on the reliability and use of die-attach adhesives for microcircuits, which he did in the mid-1970s through the early 1980s, making industry and the government aware of the degrading effects of trace amounts of ionic contaminants in epoxy resins. He conducted early exploratory development on the use of non-noble metal (Cu) thick-film conductor pastes for thick-film ceramic circuits. He carried out the first studies on the use of Parylene as a dielectric and passivation coating for MOS devices and as a particle immobilizer for hybrid microcircuits. He developed the first photo-definable thick-film conductor and resistor pastes that were the forerunners of DuPont’s Fodel process, for which he received a patent was granted in England. And he developed the first photocurable epoxy coating using cationic photoinitiation by employing a diazonium salt as the catalytic agent (U.S. 3205157). The work was referenced as pioneering work in a review article by J.V. Crivello “The Discovery and Development of Onium Salt Cationic Photoinitiators,” J. Polymer Chemistry (1999)\u003c\/div\u003e\n\u003cdiv\u003e\u003c\/div\u003e\n\u003cdiv\u003e\n\u003cb\u003eDale W. Swanson \u003c\/b\u003ehas over 29 years experience in Materials and process engineering\u003c\/div\u003e\n\u003cdiv\u003e\u003c\/div\u003e\n\u003cdiv\u003e\u003c\/div\u003e","published_at":"2017-06-22T21:12:44-04:00","created_at":"2017-06-22T21:12:44-04:00","vendor":"Chemtec Publishing","type":"Book","tags":["2011","adhesives","book","electronic","mechanical testing","p-applications","physical testing","plastic","polymer","surface","thermal testing"],"price":16900,"price_min":16900,"price_max":16900,"available":true,"price_varies":false,"compare_at_price":null,"compare_at_price_min":0,"compare_at_price_max":0,"compare_at_price_varies":false,"variants":[{"id":43378310404,"title":"Default Title","option1":"Default Title","option2":null,"option3":null,"sku":"","requires_shipping":true,"taxable":true,"featured_image":null,"available":true,"name":"Adhesives Technology for Electronic Applications, 2nd Edition - Materials, Processing, Reliability","public_title":null,"options":["Default Title"],"price":16900,"weight":1000,"compare_at_price":null,"inventory_quantity":1,"inventory_management":null,"inventory_policy":"continue","barcode":"978-1-4377-7889-2","requires_selling_plan":false,"selling_plan_allocations":[]}],"images":["\/\/chemtec.org\/cdn\/shop\/products\/978-1-4377-7889-2_cc1a9f07-b661-41cc-bfb1-5ab1ffa1d865.jpg?v=1498185491"],"featured_image":"\/\/chemtec.org\/cdn\/shop\/products\/978-1-4377-7889-2_cc1a9f07-b661-41cc-bfb1-5ab1ffa1d865.jpg?v=1498185491","options":["Title"],"media":[{"alt":null,"id":350140825693,"position":1,"preview_image":{"aspect_ratio":0.767,"height":450,"width":345,"src":"\/\/chemtec.org\/cdn\/shop\/products\/978-1-4377-7889-2_cc1a9f07-b661-41cc-bfb1-5ab1ffa1d865.jpg?v=1498185491"},"aspect_ratio":0.767,"height":450,"media_type":"image","src":"\/\/chemtec.org\/cdn\/shop\/products\/978-1-4377-7889-2_cc1a9f07-b661-41cc-bfb1-5ab1ffa1d865.jpg?v=1498185491","width":345}],"requires_selling_plan":false,"selling_plan_groups":[],"content":"\u003ch5\u003eDescription\u003c\/h5\u003e\nAuthor: James J. Licari \u0026amp; Dale W. Swanson \u003cbr\u003eISBN 978-1-4377-7889-2 \u003cbr\u003e\u003cbr\u003e512 pages\n\u003ch5\u003eSummary\u003c\/h5\u003e\n\u003cb\u003eKey Features\u003c\/b\u003e\n\u003cli\u003eA complete guide for the electronics industry to adhesive types, their properties, and applications - this book is an essential reference for a wide range of specialists including electrical engineers, adhesion chemists, and other engineering professionals.\u003c\/li\u003e\n\u003cli\u003eProvides specifications of adhesives for particular uses and outlines the processes for application and curing - coverage that is of particular benefit to design engineers, who are charged with creating the interface between the adhesive material and the microelectronic device.\u003c\/li\u003e\n\u003cli\u003eDiscusses the respective advantages and limitations of different adhesives for varying applications, thereby addressing reliability issues before they occur and offering useful information to both design engineers and Quality Assurance personnel.\u003c\/li\u003e\n\u003cp\u003e\u003cb\u003eDescription\u003c\/b\u003e\u003cbr\u003e\u003cbr\u003e\u003cbr\u003eAdhesives are widely used in the manufacture and assembly of electronic circuits and products. Generally, electronics design engineers and manufacturing engineers are not well versed in adhesives, while adhesion chemists have a limited knowledge of electronics. This book bridges these knowledge gaps and is useful to both groups.\u003cbr\u003e\u003cbr\u003e\u003cbr\u003eThe book includes chapters covering types of adhesive, the chemistry on which they are based, and their properties, applications, processes, specifications, and reliability. Coverage of toxicity, environmental impacts, and the regulatory framework make this book particularly important for engineers and managers alike.\u003cbr\u003e\u003cbr\u003e\u003cbr\u003eThe third edition has been updated throughout and includes new sections on nanomaterials, environmental impacts and new environmentally friendly ‘green’ adhesives. Information about regulations and compliance has been brought fully up-to-date.\u003cbr\u003e\u003cbr\u003eAs well as providing full coverage of standard adhesive types, Licari explores the most recent developments in fields such as:\u003cbr\u003e\u003cbr\u003e• Tamper-proof adhesives for electronic security devices.\u003cbr\u003e\u003cbr\u003e• Bio-compatible adhesives for implantable medical devices.\u003cbr\u003e\u003cbr\u003e• Electrically conductive adhesives to replace toxic tin-lead solders in printed circuit assembly - as required by regulatory regimes, e.g. the EU’s Restriction of Hazardous Substances Directive or RoHS (compliance is required for all products placed on the European market).\u003cbr\u003e\u003cbr\u003e• Nano-fillers in adhesives used to increase the thermal conductivity of current adhesives for cooling electronic devices.\u003cbr\u003e\u003cbr\u003e\u003cb\u003eReadership\u003c\/b\u003e\u003cbr\u003e\u003cbr\u003eElectronics and materials engineers in the automotive, medical, semiconductors, space, plastics, and military industries.\u003cbr\u003e\u003cbr\u003e\u003cb\u003eQuotes\u003c\/b\u003e\u003cbr\u003e\u003cbr\u003e\"I recommend this book without reservation to everyone in electronics who must understand adhesives, or make decisions about adhesives, or both.\" - George Riley\u003c\/p\u003e\n\u003ch5\u003eTable of Contents\u003c\/h5\u003e\n1. Introduction\u003cbr\u003e1.1 Adhesives Types and Definitions\u003cbr\u003e1.2 Summary of Packaging Technologies\u003cbr\u003e1.3 History of Adhesives in Electronic Applications\u003cbr\u003e1.4 Comparison of Polymer Adhesives with Metallurgical and Vitreous Attachment Materials\u003cbr\u003e1.5 Specifications\u003cbr\u003e1.6 The Market \u003cbr\u003e2. Functions and Theory of Adhesives\u003cbr\u003e2.1 Mechanical Attachment\u003cbr\u003e2.2 Electrical Connections\u003cbr\u003e2.3 Thermal Dissipation\u003cbr\u003e2.4 Stress Dissipation \u003cbr\u003e3. Chemistry, Formulation, and Properties of Adhesives\u003cbr\u003e3.1 Chemistry\u003cbr\u003e3.2 Formulation of Adhesives\u003cbr\u003e3.3 Properties \u003cbr\u003e4. Adhesive Bonding Properties\u003cbr\u003e4.1 Cleaning\u003cbr\u003e4.2 Surface Treatments\u003cbr\u003e4.3 Adhesive Dispensing\u003cbr\u003e4.4 Placement of Devices and Components\u003cbr\u003e4.5 Curing\u003cbr\u003e4.6 Rework \u003cbr\u003e5. Applications\u003cbr\u003e5.1 General Applications\u003cbr\u003e5.2 Specific Applications \u003cbr\u003e6. Reliability\u003cbr\u003e6.1 Failure Modes and Mechanisms\u003cbr\u003e6.2 Specifications \u003cbr\u003e7. Test and Inspection Methods\u003cbr\u003e7.1 Physical Tests\u003cbr\u003e7.2 Electrical Tests\u003cbr\u003e7.3 Environmental Tests\u003cbr\u003e7.4 Thermal Tests\u003cbr\u003e7.5 Mechanical and Thermomechanical Tests\u003cbr\u003e7.6 Chemical Analysis\u003cbr\u003eAppendix\u003cbr\u003eConversion Factors\u003cbr\u003eAbbreviations and Acronyms\u003cbr\u003eIndex\n\u003ch5\u003eAbout Author\u003c\/h5\u003e\n\u003cdiv\u003e\u003cb\u003eJames J. Licari\u003c\/b\u003e\u003c\/div\u003e\n\u003cdiv\u003e\u003c\/div\u003e\n\u003cdiv\u003eAvanTeco, Whittier, CA, USA\u003c\/div\u003e\n\u003cdiv\u003ehas his own consulting firm, AvanTeco, specializing in materials and processes for electronics. He holds a BS in Chemistry from Fordham University and a Ph.D. in Chemistry from Princeton University, where he was a DuPont Senior Fellow. His areas of expertise include materials and processes for electronic applications, primarily for high-reliability systems, hybrid microcircuits, printed wiring circuits, and other interconnect packaging technologies. He is an expert on polymeric materials including adhesives, coatings, encapsulants, insulation, reliability based on failure modes and mechanisms. Dr. Licari has had a forty-year career dedicated to the study and advancement of microelectronic materials and processes. Notable achievements throughout this career include conducting the first studies on the reliability and use of die-attach adhesives for microcircuits, which he did in the mid-1970s through the early 1980s, making industry and the government aware of the degrading effects of trace amounts of ionic contaminants in epoxy resins. He conducted early exploratory development on the use of non-noble metal (Cu) thick-film conductor pastes for thick-film ceramic circuits. He carried out the first studies on the use of Parylene as a dielectric and passivation coating for MOS devices and as a particle immobilizer for hybrid microcircuits. He developed the first photo-definable thick-film conductor and resistor pastes that were the forerunners of DuPont’s Fodel process, for which he received a patent was granted in England. And he developed the first photocurable epoxy coating using cationic photoinitiation by employing a diazonium salt as the catalytic agent (U.S. 3205157). The work was referenced as pioneering work in a review article by J.V. Crivello “The Discovery and Development of Onium Salt Cationic Photoinitiators,” J. Polymer Chemistry (1999)\u003c\/div\u003e\n\u003cdiv\u003e\u003c\/div\u003e\n\u003cdiv\u003e\n\u003cb\u003eDale W. Swanson \u003c\/b\u003ehas over 29 years experience in Materials and process engineering\u003c\/div\u003e\n\u003cdiv\u003e\u003c\/div\u003e\n\u003cdiv\u003e\u003c\/div\u003e"}